Chinese Journal of Lasers, Volume. 50, Issue 24, 2402205(2023)

Laser Cladding High‑Entropy Alloy Coating Reinforced by Carbon Nanotubes and Its Corrosion Resistance

Bing Han1,2、*, Xi Chen3, Meng Jiang3, Wenlong Chen4, Dongdong Zhang5, Lichao Cao2, Junshuang Zhang1, Xianbin Teng1, and Yanbin Chen3
Author Affiliations
  • 1School of Marine Engineering, Guangzhou Maritime University, Guangzhou 510725, Guangdong, China
  • 2Institute of Intelligent Manufacturing, Guangdong Academy of Science, Guangzhou 510070, Guangdong, China
  • 3State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001, Heilongjiang, China
  • 4Center for Industrial Analysis and Testing, Guangdong Academy of Science, Guangzhou 510650, Guangdong, China
  • 5School of Vanadium and Titanium, Panzhihua University, Panzhihua 617000, Sichuan, China
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    Figures & Tables(11)
    Micromorphologies of CoCrFeNi powder and CNTs before and after mechanical mixing. (a) CoCrFeNi raw powder; (b) CNT raw powder; (c) CoCrFeNi-CNTs powder; (d) local magnification of Fig. 1 (c)
    Laser cladding diagram for preparing CoCrFeNi-CNTs composite coating and physical image
    XRD patterns of CoCrFeNi raw powder and CoCrFeNi-CNTs composite coating
    Sectional metallographic morphologies of CoCrFeNi-CNTs composite coating. (a) Low magnification of metallographic morphology of coating cross section; (b) micro-morphology of region A; (c) micro-morphology of region B; (d) micro-morphology of C region
    TEM microstructure of CoCrFeNi-CNTs composite coating. (a) Intergranular carbide morphology; (b) enlarged morphology of D region
    SEM microstructure of unknown substances in CoCrFeNi-CNTs composite coating
    Comparison of microhardness distributions in CoCrFeNi-CNTs and CoCrFeNi coatings
    SEM microstructures of CoCrFeNi-CNTs composite coating under different salt spray corrosion time. (a) 36 h; (b) 168 h; (c) 269 h (imaging in secondary electron mode); (d) 269 h (imaging in backscatter mode); (e) distribution of C element in area E; (f) distribution of Si element in area E
    • Table 1. Measured components of high-entropy alloy powder

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      Table 1. Measured components of high-entropy alloy powder

      Raw powderMass fraction /%
      CoCrFeNi
      CoCrFeNi26.2323.3625.28Bal.
    • Table 2. Optimized process parameters of laser cladding CoCrFeNi high-entropy alloy composite coating

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      Table 2. Optimized process parameters of laser cladding CoCrFeNi high-entropy alloy composite coating

      Parameter

      Laser

      power /W

      Laser scanning velocity /(mm·s-1

      Overlap

      rate /%

      Powder feeding rate /(g·min-1

      Layer

      thickness /mm

      Argon flow

      rate /(L·min-1

      Value87012.5508.70.520
    • Table 3. EDS results measured at microscopic areas of CoCrFeNi-CNTs composite coating

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      Table 3. EDS results measured at microscopic areas of CoCrFeNi-CNTs composite coating

      AreaAtomic number fraction /%
      CoCrFeNiCOSi
      I3.9949.236.631.2238.93
      II23.1423.2525.0223.593.371.63
      III27.7372.27
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    Bing Han, Xi Chen, Meng Jiang, Wenlong Chen, Dongdong Zhang, Lichao Cao, Junshuang Zhang, Xianbin Teng, Yanbin Chen. Laser Cladding High‑Entropy Alloy Coating Reinforced by Carbon Nanotubes and Its Corrosion Resistance[J]. Chinese Journal of Lasers, 2023, 50(24): 2402205

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    Paper Information

    Category: Laser Surface Machining

    Received: Apr. 17, 2023

    Accepted: May. 30, 2023

    Published Online: Nov. 1, 2023

    The Author Email: Han Bing (dabingzhenniu@163.com)

    DOI:10.3788/CJL230737

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