Opto-Electronic Advances, Volume. 6, Issue 9, 220154(2023)

ITO-free silicon-integrated perovskite electrochemical cell for light-emission and light-detection

Maria Baeva1,2,3, Dmitry Gets2, Artem Polushkin2, Aleksandr Vorobyov1, Aleksandr Goltaev1, Vladimir Neplokh1,4, Alexey Mozharov1, Dmitry V. Krasnikov5, Albert G. Nasibulin5, Ivan Mukhin1,4、*, and Sergey Makarov2,6、**
Author Affiliations
  • 1Alferov University, Khlopina 8/3, St. Petersburg 194021, Russia
  • 2Department of Physics and Engineering, ITMO University, Lomonosova 9, St. Petersburg 197101, Russia
  • 3Institute of Automation and Control Processes (IACP), Far Eastern Branch of Russian Academy of Sciences, Ulitsa Radio 5, Vladivostok 690041, Primorsky Krai, Russia
  • 4Peter the Great St. Petersburg Polytechnic University, Polytechnicheskaya 29, St. Petersburg 195251, Russia
  • 5Skolkovo Institute of Science and Technology, Nobel 3, Moscow 121205, Russia
  • 6Qingdao Innovation and Development Center, Harbin Engineering University, Qingdao 266000, China
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    Figures & Tables(8)
    Schematic diagrams of (a) the typical PeLED device structure, where CTL - charge transfer layer, QD - quantum dots and (b) our PeLEC device structure, where SWCNT - single-walled carbon nanotubes.
    (a) Dual-function device processing scheme. (b) Device cross-section 3D illustration and SEM images, scale bars - 200 nm. (c) Final device photos: left panel- without applied bias, right panel- with applied positive bias to one of the pixels, scale bars - 5 mm.
    Composite perovskite PeLEC key figures-of-merit. (a) The device EL spectra on applied bias offset relative to each other, inset – CIE 1931 RGB color space with triangular NTSC color-gamut standard, “star” marker - the device’s color coordinates. (b) Measured device’s J-V curve plot in one axis with L-V curve. (c, d) The device’s band diagram at 0 V bias (left panel) and 4 V bias (right panel), where Ec and Ev are the perovskite material conduction band bottom and valence band top, respectively, EFn and EFp– quasi-Fermi levels for electrons and holes, respectively. (e) The device’s EL efficiency curve and PeLEC EQE characteristic on applied voltage. (f) The device’s power efficiency curve.
    (a) The PeLEC J-V curves at positive applied bias for charge carrier lifetimes: τ = 10 ns (left panel) and τ = 120 ns (right panel). (b) The PeLECs IQE at different charge carriers’ lifetimes versus applied bias. (c) Combined IQE curve versus charge carrier lifetime at 4 V.
    (a) Left panel – PeLECs J and L tracking over 8 minutes at 3.7 V, right panel – zoomed in maximum current density point in the J curve. (b) Comparison of the J-V curves before and after soaking. (c) Schematic simplified PeLEC’ energy level diagram combined with underlying ionic movement scenario.
    The dual-function PeLEC devices indicator display images. (a) The entire indicator displays frame PCB and addressing pixels PCB (left panel) with zoomed-in image of the mounted onto the indicator display frame devices (right panel). (b) Day-light indicator display image. (c) Low ambient light all-pixels-in-operation indicator display image. (d-m) Numbers from 0 to 9 images displayed with our indicator display. Scale bars in all images – 1 cm.
    Optical images of our n++-Si(100)/CsPbBr3:PEO:LiTFSI/SWCNT mat devices in shape of. (a) Alferov University (Saint-Petersburg, Russia) emblem. (b) ITMO University (Saint-Petersburg, Russia) emblem. (c) Inverted composite perovskite cat. Scale bars in all images are 500 μm.
    Composite perovskite photodiode key figures-of-merit. (a) J-V curves at different laser incident radiant power densities, insert – Uch values on incident radiant power density. (b) Photodetector EQE on the electrical bias, insert – the device’s EQE at U = 0 V in linear axis. (c) Schematic simplified PeLEC’ energy level diagram in light-detecting operation regime. (d) The device’s responsivity for different laser incident radiant power densities, insert – zoomed-in section of the graph from U = 0 V to Uch . (e) The device’s LDR curves for three different biases, insert – LDR region for three biases in linear axis. (f) The device’s specific detectivity curves for different laser incident radiant power densities, insert – zoomed-in section of the graph for maximal D* in linear axis.
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    Maria Baeva, Dmitry Gets, Artem Polushkin, Aleksandr Vorobyov, Aleksandr Goltaev, Vladimir Neplokh, Alexey Mozharov, Dmitry V. Krasnikov, Albert G. Nasibulin, Ivan Mukhin, Sergey Makarov. ITO-free silicon-integrated perovskite electrochemical cell for light-emission and light-detection[J]. Opto-Electronic Advances, 2023, 6(9): 220154

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    Paper Information

    Category: Research Articles

    Received: Sep. 20, 2022

    Accepted: Feb. 27, 2023

    Published Online: Nov. 15, 2023

    The Author Email:

    DOI:10.29026/oea.2023.220154

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