Journal of Radiation Research and Radiation Processing, Volume. 43, Issue 2, 020201(2025)

Preparation and properties of fluorine-containing antimicrobial UV-curing coatings

Shupeng WU, Xiwen CUI, Yue ZHANG, Bingbin ZHANG, Zhengtao WU, Xuehua ZHU, and Yan YUAN*
Author Affiliations
  • Suzhou University of Science and Technology, Suzhou 215009, China
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    Figures & Tables(13)
    Synthesis of organosilicon quaternary ammonium salt
    Synthesis of fluorinated UV-curing monomer
    1H NMR spectrum (a) and FTIR spectrum of UV-F (b)
    1H NMR spectrum of QAC
    Coating morphology of cross-section: (a, b) coating with 15% (mass percent) 3UV-F∶7QAC; (c, d) coating with 15% (mass percent) 5UV-F∶5QAC
    Double bond conversion rate with 15% additives of different mix ratio (color online)
    Double bond conversion rate with different mass percent of 3UV-F∶7QAC (color online)
    Thermogravimetric analysis (TGA) with 15% additives of different mix ratio (color online)
    Inhibition circle diameter of additives with different content and mix ratio
    Experiment of inhibition circle
    Water contact angle photos of coating with 15% additives of different mix ratios: (a) 9UV-F∶1QAC;(b) 7UV-F∶3QAC; (c) 5UV-F∶5QAC; (d) 3UV-F∶7QAC; (e) 1UV-F∶9QAC; (f) coating of 0% additives;(g) water contact angle of different coatings
    • Table 1. The ratio and content of additives in the coating formulation

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      Table 1. The ratio and content of additives in the coating formulation

      添加剂 / %

      Additives

      051015202530
      9UV-F∶1QAC051015202530
      7UV-F∶3QAC051015202530
      5UV-F∶5QAC051015202530
      3UV-F∶7QAC051015202530
      1UV-F∶9QAC051015202530
    • Table 2. Mechanical properties test of coating

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      Table 2. Mechanical properties test of coating

      添加剂 / % Additives051015202530

      铅笔硬度

      Pencil hardness

      9UV-F∶1QACHBBBB2B2B2B
      7UV-F∶3QACHB3B6B6B<6B<6B
      5UV-F∶5QAC5B6B<6B<6B<6B6B
      3UV-F∶7QACHB2B2B<6B<6B<6B
      1UV-F∶9QAC5B<6B<6B<6B<6B<6B

      摆杆硬度 / s

      Pendulum

      hardness

      9UV-F∶1QAC115±5210±5162±2205±5180±3110±4174±4
      7UV-F∶3QAC309±4251±5180±2226±3250±1180±1
      5UV-F∶5QAC260±5170±378±4140±5167±4122±2
      3UV-F∶7QAC340±5380±3240±2155±392±187±1
      1UV-F∶9QAC300±1352±595±5180±5100±2140±5

      抗拉强度 / MPa

      Tensile strength

      9UV-F∶1QAC4.933.884.563.553.273.954.63
      7UV-F∶3QAC4.684.213.473.872.484.76
      5UV-F∶5QAC5.214.104.083.324.073.37
      3UV-F∶7QAC2.942.573.062.552.202.17
      1UV-F∶9QAC2.992.661.691.231.691.29

      断裂伸长率 / %

      Elongation at break

      9UV-F∶1QAC41.334.640.526.031.828.039.2
      7UV-F∶3QAC47.025.336.236.926.627.2
      5UV-F∶5QAC34.033.339.133.647.931.7
      3UV-F∶7QAC31.234.744.026.734.741.6
      1UV-F∶9QAC28.923.262.725.430.324.8
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    Shupeng WU, Xiwen CUI, Yue ZHANG, Bingbin ZHANG, Zhengtao WU, Xuehua ZHU, Yan YUAN. Preparation and properties of fluorine-containing antimicrobial UV-curing coatings[J]. Journal of Radiation Research and Radiation Processing, 2025, 43(2): 020201

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    Paper Information

    Category: RADIATION CHEMISTRY

    Received: Sep. 23, 2024

    Accepted: Nov. 15, 2024

    Published Online: May. 16, 2025

    The Author Email: Yan YUAN (袁妍)

    DOI:10.11889/j.1000-3436.2024-0078

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