Journal of Inorganic Materials, Volume. 34, Issue 1, 49(2019)

Synthesis, Optimization of Cu Nanowires and Application of Its Transparent Electrodes

Xiao WANG, Ran-Ran WANG, Liang-Jing SHI, Jing SUN, [in Chinese], [in Chinese], [in Chinese], and [in Chinese]
Author Affiliations
  • Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
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    Figures & Tables(8)
    Formation of Cu nanowires directed by liquid-crystalline structure of the medium[14]
    SEM images and diameter distribution of Cu nanowires synthesized by using different halide ions[16] (a, e) 2.6 mmol Cl-; (b,f) 2.0 mmol Cl-; (c,g) 1.6 mmol Cl-; (d,h) 1.6 mmol Br-
    (A) SEM image of Cu-Ni NWs with inset showing high resolution SEM image of Cu-Ni NWs; (B) Dark field optical microscopy images of Cu-Ni NWs; (C-H) The distribution of Cu and Ni elements of Cu-Ni NWs with different contents of nickel[23]
    Schematic diagram of the vaccum transfer method (a)[35], the spray-coating method (b)[36], the meyer rod coating method (c)[37], and the roll-to-roll coating method (d)[37]
    (a-c) Schematic diagram of the experimental setup of a typical plasma treatment process; (d) SEM image of the nanowire junction after plasma treatment; (e) Current-voltage measurement of LED lamps connected by stretchable Cu NW conductors at various strains. Insets are digital photos of the whole setup at 0 and 250% strain[48]
    Schematic diagram (a) of the preparation procedure of Cu NWs/PA electrode. SEM (b), TEM (c), HRTEM (d) and EELS spetra (e) of the Cu NWs film after TiO2 nanopartical sol treatment. Raman spectra (f) of Cu NWs before post-treating, after H2 plasma treatment and TiO2 nanopartical sol treatment. Plot of the transmittance (at a wavelength of 550 nm) with respect to the sheet resistance (g) for films of Cu NWs with H2 annealing, H2 plasma treatment and TiO2 nanopartical sol treatment. Sheet resistance variation (h) of the commercial ITO/PET and Cu NWs/PA electrodes during the bending test of 104 cycles[53]
    (a) Time-dependent temperature curves of Cu NW-1000 on PET films at input voltages of 1.5-5 V under ambient conditions; (b) PET/ITO transparent heaters during 104 cycles of bending tests; (c) Infrared photograph and (d) application examples of Cu NW-based stretchable heater[61]
    • Table 1. Summary of representitive synthetic methods of Cu nanowires

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      Table 1. Summary of representitive synthetic methods of Cu nanowires

      SolventReducing agentCapping agentCu precursorAverage
      diameter/nm
      Average lengthRef.
      DI waterH3PO3Sodium dodecyl
      benzene sulfonate (SDBS)
      CuSO4·5H2O,~85Tens of
      micrometers
      [17]
      DI waterHydrazine hydrateEthylenediamineCu(NO3)235-7020-80 μm[11-13, 18]
      DI waterAscorbic AcidPVPCu(NO3)2~50>10 μm[19]
      DI waterGlucoseHDACuCl2·2H2O24±4Tens to hundreds
      micrometers
      [20]
      DI waterGlucoseOleic acid, OleylamineCuCl2~4560-90 μm[9]
      1-hexadecylamine
      (HDA)
      1-Hexadecylamine (HDA)Hexadecyl trimethyl
      ammonium bromide (CTAB)
      Cu(acac)2~78Tens to hundreds
      micrometers
      [14]
      OleylamineOleylamineOleylamineCuCl~6310-30 μm[10]
      OleylamineOleylamineOleylamineCuBr2/CuCl216.2-90.020-40 μm[15-16]
      OleylamineTris(trimethylsilyl)
      silane
      OleylamineCuCl2~16.1~17 μm[21]
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    Xiao WANG, Ran-Ran WANG, Liang-Jing SHI, Jing SUN, [in Chinese], [in Chinese], [in Chinese], [in Chinese]. Synthesis, Optimization of Cu Nanowires and Application of Its Transparent Electrodes[J]. Journal of Inorganic Materials, 2019, 34(1): 49

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    Paper Information

    Category: Research Articles

    Received: May. 25, 2018

    Accepted: --

    Published Online: Feb. 4, 2021

    The Author Email:

    DOI:10.15541/jim20180243

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