Chinese Journal of Lasers, Volume. 52, Issue 20, 2002202(2025)

Effects of Laser Shock Peening on Corrosion Resistance of TA15 Titanium Alloy with Different Microstructures

Qianqian Wang1, Lingfeng Zhang1,2、*, Hua Yu1,3, Tao Jiang1,3, Yi Xiong1,2, Huai Yao1,2, and Jing Zhang1
Author Affiliations
  • 1School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang 471023, Henan , China
  • 2Provincial and Ministerial Co-Construction of Collaborative Innovation Center for Non-Ferrous Metal New Materials and Advanced Processing Technology, Luoyang 471023, Henan , China
  • 3National Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials, Luoyang 471003, Henan , China
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    Figures & Tables(19)
    Microstructures of TA15 titanium alloy. (a) Equiaxed microstructure; (b) basketweave microstructure
    XRD patterns of TA15 titanium alloy surface before and after LSP. (a) Equiaxed microstructure; (b) basketweave microstructure
    Cross-sectional microstructural morphology of TA15 titanium alloy after LSP. (a) Equiaxed microstructure; (b) basketweave microstructure
    TEM images of TA15 titanium alloy after LSP. (a)(b) Equiaxed microstructures; (c)(d) basketweave microstructures
    TEM images of the surface layer of TA15 titanium alloy after LSP. (a) Brightfield image and SAED pattern of equiaxed microstructure; (b) darkfield image and grain size distribution of equiaxed microstructure; (c) brightfield image and SAED pattern of basketweave microstructure; (d) darkfield image and grain size distribution of basketweave microstructure
    Three-dimensional surface morphology of TA15 titanium alloy. (a) Untreated equiaxed microstructure; (b) untreated basketweave microstructure; (c) LSP-treated equiaxed microstructure; (d) LSP-treated basketweave microstructure
    Microhardness at different depths of TA15 titanium alloy. (a) Equiaxed microstructure; (b) basketweave microstructure
    Residual stress at different depths of TA15 titanium alloy after LSP
    Potentiodynamic polarization (PDP) curves of TA15 titanium alloy
    EIS of TA15 titanium alloy. (a) Nyquist plot; (b) Bode plot
    Equivalent circuit used for EIS fitting
    Weight loss of TA15 titanium alloy
    Corrosion rate of TA15 titanium alloy
    SEM images and EDS spectra of TA15 titanium alloy after immersion in 5 mol/L HCl solution for 10 days. (a) Untreated equiaxed microstructure; (b) LSP-treated equiaxed microstructure; (c) untreated basketweave microstructure; (d) LSP-treated basketweave microstructure
    SEM images of TA15 titanium alloy after being immersed in 5 mol/L HCl solution for 10 days and removing corrosion products. (a) Untreated equiaxed microstructure; (b) LSP-treated equiaxed microstructure; (c) untreated basketweave microstructure; (d) LSP-treated basketweave microstructure
    • Table 1. Chemical composition of TA15 titanium alloy

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      Table 1. Chemical composition of TA15 titanium alloy

      ElementMass fraction /%
      Al6.6
      Zr2.2
      Mo1.7
      V2.2
      TiBal.
    • Table 2. LSP processing parameter

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      Table 2. LSP processing parameter

      Parameter of LSPValue
      Laser wavelength /nm1064
      Pulse width /ns20
      Pulse energy /J6
      Spot diameter /mm3
      Overlapping rate /%50
      Power density /(GW/cm24.25
    • Table 3. PDP curve parameters of TA15 titanium alloy in different states

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      Table 3. PDP curve parameters of TA15 titanium alloy in different states

      MicrostructureSpecimenCorrosion potential /mV

      Corrosion current

      density /(nA/cm2

      Passivation current

      density /(μA/cm2

      EquiaxedUntreated-403.9929.052.28
      LSP-393.2710.641.29
      BasketweaveUntreated-398.7399.589.87
      LSP-331.0213.531.53
    • Table 4. Equivalent circuit parameters

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      Table 4. Equivalent circuit parameters

      MicrostructureSpecimenRs /(Ω·cm2CPEf /(10-6 S·cm-2·s-nn1Rf /(kΩ·cm2
      EquiaxedUntreated27.519.230.887922.06
      LSP13.736.6790.900135.43
      BasketweaveUntreated12.0534.180.852917.92
      LSP23.249.6080.926215.99
      MicrostructureSpecimenCPEdl /(10-6 S·cm-2·s-nn2Rct /(MΩ·cm2χ2 /10-4
      EquiaxedUntreated4.1440.91035.6135.241
      LSP2.4230.881677.463.718
      BasketweaveUntreated3.8130.98830.63679.923
      LSP3.0180.86519.9112.945
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    Qianqian Wang, Lingfeng Zhang, Hua Yu, Tao Jiang, Yi Xiong, Huai Yao, Jing Zhang. Effects of Laser Shock Peening on Corrosion Resistance of TA15 Titanium Alloy with Different Microstructures[J]. Chinese Journal of Lasers, 2025, 52(20): 2002202

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    Paper Information

    Category: Laser Surface Machining

    Received: Feb. 25, 2025

    Accepted: Apr. 10, 2025

    Published Online: Jun. 16, 2025

    The Author Email: Lingfeng Zhang (zh_lingfeng@163.com)

    DOI:10.3788/CJL250557

    CSTR:32183.14.CJL250557

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