Journal of Inorganic Materials, Volume. 34, Issue 4, 349(2019)

Silicon-based Anode Materials Applied in High Specific Energy Lithium-ion Batteries: a Review

Yi TAN1,2 and Kai WANG1,2
Author Affiliations
  • 1School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China
  • 2Key Laboratory for Solar Energy Photovoltaic System of Liaoning Province, Dalian 116024, China
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    Figures & Tables(14)
    Performance comparison of common anode materials
    Illustration of Si volume expansion during charge and discharge[9]
    Schematic of the failure mechanism of silicon[13]
    The composite map of synthesis of CNT@mp-Si and meso-porous Si nanotube [20]
    Schematic of the pomegranate-inspired design[25](a) Three dimensional view and (b) simplified two-dimensional cross-section view
    (a) Schematic diagram of the novel core-shell Si@C@void@C, TEM images of (b) raw Si, (c) Si@SiO2@C, (d) Si@void@C, (e) Si@C, (f) Si@C@SiO2@C, and (g) Si@C@void@C[26]
    Scanning diagrams of (a) Ag-deposited on Si and (b, c) metal induced etching Si[28]
    Schematic illustration of the preparation process from Al-Si alloy to the Si/C composite[30]
    Schematic diagram of the basic electrochemical mechanism of SiOx-based materials[46]
    Schematic diagram of short-circuit prelithiation treatment of metal foil circuit of batteries[50]
    Schematic diagram of preparation of the SiOx/Si/C[54]
    SEM images of (a) initial SiO@C, surface ((b) secondary electron phase, (c) back scattered) and (d) cross-section of hollow SiO@void@C material[59]
    Performance comparisons of common Si-based anode materials[25, 30, 35-39, 47, 53-54, 59-62]
    • Table 1. Electrochemical performance of some silicon/carbon composite anodes for lithium-ion batteries

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      Table 1. Electrochemical performance of some silicon/carbon composite anodes for lithium-ion batteries

      Composite typeSi sourceCarbon sourceElectrochemical performanceMethodRef.
      Si/Porous-CNano-silicon powderPitch723.8 mAh/g (1st)600 mAh/g (100 mA/g, 100 )aSpray drying + High-temperature pyrolysis[35]
      Si@C@RGOSilicon powder (80 nm)Sucrose1599 mAh/g (1st)1517 mAh/g (100 mA/g, 100 )Spray drying + High-temperature pyrolysis[36]
      Si/C/GSilicon powder (325 mesh)Phenol-formaldehyde resin (PFR)700 mAh/g (1st)550 mAh/g (100 mA/g, 40 )High-temperature pyrolysis[37]
      Silicon-spongeSi wafer (>20 μm)Acetylene790 mAh/g (1st)726 mAh/g (100 mA/g, 300 )Electrochemical etching+ High-temperature pyrolysis[38]
      PS@CSi powder(5 μm)Propylene1980 mAh/g (1st)1287 mAh/g (100 mA/g, 100)Chemical etching + CVD[39]
      Si/CAl-Si alloy(2-10 μm)Polyacrylonitrile (PAN)952 mAh/g (1st)826.3 mAh/g (200 mA/g, 300)Chemical etching + High-temperature pyrolysis[30]
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    Yi TAN, Kai WANG. Silicon-based Anode Materials Applied in High Specific Energy Lithium-ion Batteries: a Review[J]. Journal of Inorganic Materials, 2019, 34(4): 349

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    Paper Information

    Category: REVIEW

    Received: Jul. 25, 2018

    Accepted: --

    Published Online: Sep. 24, 2021

    The Author Email:

    DOI:10.15541/jim20180347

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