Chinese Optics, Volume. 15, Issue 4, 625(2022)
The principle, performance characterization and research progress of nonlinear optical limiting materials
![Nonlinear refraction schematic diagrams[2]. (a) Typical self-defocusing optical structure; (b) typical self-focusing optical structure](/Images/icon/loading.gif){kind=icon}
Fig. 4. Nonlinear refraction schematic diagrams[2]. (a) Typical self-defocusing optical structure; (b) typical self-focusing optical structure
Fig. 7. (a) Open hole Z-scan curve and (b) close hole Z-scan curve
Table 1. The mechanism, characteristics and the technical indicators of the five types of optical limiting materials
View tableView in ArticleTable 1. The mechanism, characteristics and the technical indicators of the five types of optical limiting materials
材料类别 光限幅机理 性能特点 代表材料 光限幅技术指标 参考文献 无机半导体材料 双光子吸收 载流子吸收 非线性折射 制备简单、成本低廉、 物化性质稳定，限幅波段单一、 线性吸收大 CuS 限幅阈值：0.88 J/cm2@532 nm [ 15 ]ZnO 限幅阈值：~6 mW@633 nm [ 16 ]TiS2 限幅阈值：0.57 J/cm2 [ 17 ]共轭有机高分子 反饱和吸收 适用于脉宽纳秒 量级以上的脉冲激光、 限幅阈值低 J-dimers 限幅阈值：0.03 J/cm2@532 nm [ 18 ](NiNc(COONa)4/TiO2)n 限幅波段：600 nm@18 ps [ 19 ]MnPcCl 限幅波段：633 nm，533 nm [ 20 ]无机金属团簇 非线性折射 反饱和吸收 结构多样、线性吸收小、 非线性性能强 MoS4Cu2 限幅阈值：0.35 J/cm2@532 nm [ 21 ]碳基纳米材料 反饱和吸收 非线性折射 非线性散射 限幅阈值低、限幅波段宽， 损伤阈值高、适用于纳秒、 皮秒脉冲激光，固态化技术成熟 C60(Toluene) 限幅阈值：0.2 J/cm2@532 nm [ 22 ]MWNTS 限幅阈值：1 J/cm2@532 nm [ 23 ]GO-Pt-2 限幅阈值：0.85 J/cm2@532 nm [ 24 ]二维材料 反饱和吸收 非线性折射 非线性散射 限幅波段宽， 可用于飞秒脉冲激光， 物化性质优异 Si−antimonene 限幅波段：532~2000 nm 限幅阈值：0.3~2 J/cm2@532 nm [ 25 ]F16PcGa-BP 限幅波段：415~590 nm 限幅阈值：2.64 J/cm2@532 nm [ 26 ]
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Ze LV, You FANG, Tiao FENG, Nan ZONG, Yun-fei LI, Shen-jin ZHANG, Zheng XIE, Qin-jun PENG. The principle, performance characterization and research progress of nonlinear optical limiting materials[J]. Chinese Optics, 2022, 15(4): 625
Category: Review
Received: Nov. 8, 2021
Accepted: Jan. 24, 2022
Published Online: Sep. 6, 2022
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