Spectroscopy and Spectral Analysis, Volume. 41, Issue 2, 448(2021)

Species Identification of NaCl, NaOH and β-Phenylethylamine Based on Ultraviolet Spectrophotometry and Supervised Pattern Recognition Technology

Ang-xin TONG*, Xiao-jun TANG, Feng ZHANG, and Bin WANG
Author Affiliations
  • State Key Laboratory of Electrical Insulation and Power Equipment, Xi’an Jiaotong University, Xi’an 710049, China
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    Figures & Tables(9)
    Structure diagram of sample dilution
    Structure diagram of the equipment
    UV absorption spectra of NaCl, NaOH and PEA at 0.001 49 mol·L-1
    UV absorption spectra of the mixtures at seven different concentrations
    Distribution of score vector values in the space of the first three PCs
    Sample distribution of NaCl, NaOH and PEA in the plane of the discriminant functions
    Classification results of the mixture obtained by three supervised classification method(a): RBF-SVM; (b): BP ANN; (c): ABC BP ANN; (a): RBF-SVM; (b): BP ANN; (c): ABC BP ANN; 1: 0%mol·L-1; 2: 10%mol·L-1; 3: 20%mol·L-1; 4: 30%mol·L-1; 5: 40%mol·L-1, 6: 50%mol·L-1; 7: 60%mol·L-1
    • Table 1. The sensitivity and specificity of NaCl, NaOH and PEA for test sets obtained by supervised classification methods/%

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      Table 1. The sensitivity and specificity of NaCl, NaOH and PEA for test sets obtained by supervised classification methods/%

      ModelNaClNaOHPEAOverall
      SENSSPECSENSSPECSENSSPECSENSSPEC
      LDA10083.386.710010010095.694.4
      Sigmoid SVM97.887.389.198.110097.895.694.4
      RBF SVM98.387.989.499.110098.495.995.1
      RBF ANN98.787.689.199.599.598.995.895.3
      BP ANN10090.590.810010010096.996.8
      ABC BP-ANN10097.898.710010010099.699.3
    • Table 2. The sensitivity and specificity of the mixture for test sets obtained by three supervised classification methods

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      Table 2. The sensitivity and specificity of the mixture for test sets obtained by three supervised classification methods

      SpeciesSENS/%SPEC/%
      RBF SVMBP ANNABC BP-ANNRBF SVMBP ANNABC BP-ANN
      0%10010010091.291.291.2
      10%74.481.787.577.183.486.9
      20%73.782.492.681.686.990.2
      30%10010010094.694.694.6
      40%79.181.587.280.484.387.6
      50%10010010082.182.785.2
      60%82.890.494.387.289.794.8
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    Ang-xin TONG, Xiao-jun TANG, Feng ZHANG, Bin WANG. Species Identification of NaCl, NaOH and β-Phenylethylamine Based on Ultraviolet Spectrophotometry and Supervised Pattern Recognition Technology[J]. Spectroscopy and Spectral Analysis, 2021, 41(2): 448

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    Paper Information

    Category: Research Articles

    Received: Dec. 9, 2019

    Accepted: Apr. 4, 2020

    Published Online: Apr. 8, 2021

    The Author Email: TONG Ang-xin (tongangxin@stu.xjtu.edu.cn)

    DOI:10.3964/j.issn.1000-0593(2021)02-0448-06

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