Chinese Journal of Lasers, Volume. 50, Issue 1, 0113006(2023)
Recent Developments of Organic Optoelectronic Functional Materials and Devices Based on Biphenyl Derivatives
Fig. 2. Molecular structure of biphenyl derivatives linked by carbon-carbon single bonds
Fig. 3. Molecular structure of biphenyl derivatives linked by carbon-carbon double bonds
Fig. 4. Novel nonheterostructure OLED based on BSBCz[32-34]. (a) Energy level diagrams for OLEDs with a single emitter layer of BSBCz, OLEDs with a hole-blocking BCP layer, and OLEDs with electron-blocking mCP and hole-blocking BCP layers from top to bottom; (b) current density-voltage characteristic curves of devices A, B, and C; (c) exciton density (ηexciton)-current density characteristic curves of devices A, B, and C
Fig. 5. Characteristics of OLET devices based on DBTVB[55]. (a) Energy-level alignment of OLET device; (b) schematic diagram of OLET device; (c) summary map of single-component high-performance OLET devices reported so far; (d)-(e) transfer and output curves under P-type operation mode; (f)-(g) transfer and output curves under N-type operation mode
Fig. 6. Organic micro/nao-crystal lasers based on biphenyl derivatives. (a) High-resolution PL spectrum and image of laser emissions at 475 nm of BPVT; (b) high-resolution PL spectrum and image of laser emissions at 541 nm of BBTVB; (c) high-resolution PL spectrum and image of laser emissions at 588 nm of BTTVB; (d)-(e) schematic illustration and lasing spectra of dual-wavelength switchable vibronic laser; (f) normalized lasing spectra and PL images of BP3T doped BP1T microcrystals
Fig. 7. CW pumped lasers[65]. (a) Schematic representation of mixed-order DFB grating structure; (b) streak camera images showing laser oscillations from a representative BSBCz:CBP encapsulated mixed-order DFB device at repetition frequency from 0.01 to 80 MHz; (c) streak camera images showing laser emission integrated over 100 pulses from an encapsulated mixed-order DFB device using a BSBCz:CBP (20%∶80%) film as gain medium and optically pumped by pulses of 30 ms and 2.0 kW/cm2 (top) or 800 ms and 200 W/cm2 (bottom); (d) photograph of DFB device operating in long-pulse regime (excitation, 30 ms)
Fig. 8. Polariton lasers based on DSA derivatives[75-76]. (a) Polariton emission of DPAVBi microcavity when laser energy is less than threshold[75]; (b) polariton emission of DPAVBi microcavity when laser energy is more than thrshold[75]; (c) polaritons start to occupy high-energy discrete levels at large angles[75]; (d) polariton emission BSBCz-EH microcavities when laser energy is less than threshold and more than threshold[76]
Fig. 9. Indication of current-injection lasing[36,44]. (a) Schematic representation of organic semiconductor laser diodes (OSLD)[36]; (b) SEM images of DFB grating and cross-section SEM image of OSLD[36]; (c) emission spectra and threshold of BSBCz OSLDs[36]; (d) DFB- and FRP-el-OSCL devices in electrically driven mode operation and laser emission based on BP3T microcrystals[44]; (e) intensity of emission as a function of current density or light fluence[44]; (f) comparison of relationship of intensity of emission versus light fluence between ASE and laser in optically driven mode[44]
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Fan Yin, Jianbo De, Qing Liao, Hongbing Fu. Recent Developments of Organic Optoelectronic Functional Materials and Devices Based on Biphenyl Derivatives[J]. Chinese Journal of Lasers, 2023, 50(1): 0113006
Category: micro and nano optics
Received: Aug. 24, 2022
Accepted: Oct. 21, 2022
Published Online: Jan. 6, 2023
The Author Email: Liao Qing (liaoqing@cnu.edu.cn)