Chinese Journal of Lasers, Volume. 48, Issue 15, 1502002(2021)
Ultrafast Laser Fabricating of Controllable Micro-Nano Dual-Scale Metallic Surface Structures and Their Functionalization
Fig. 1. Evolution of micro-nanostructures on Cu surfaces with different scanning speeds[6]. (a1)--(a3) Low speed scanning; (b1)--(b3) medium speed scanning; (c1)--(c3) high speed scanning
Fig. 2. Water contact angles and sliding angles of samples with different scanning speeds[6]
Fig. 3. Micro-nanostructures of triple-scale superhydrophobic surfaces[19]. (a) Schematic of fabrication processes; (b1)--(b3) characteristics of surface topography
Fig. 4. Cassie stability and anti/deicing performance of the triple-scale superhydrophobic surfaces[19]. (a)(b) Evolution of water contact angle and three phase contact line as Laplace pressure increasing during the evaporation process; (c) jumping number of impacting droplets on different surfaces; (d) dropwise condensation; (e) hierarchical condensation; (f) schematic of primary condensed droplets (PCDs) and the secondary condensed droplets (SCDs); (g) ice adhesion strength of MNGF and other superhydrophobic surfaces
Fig. 5. Superhydrophilic/superhydrophobic venation network for water collection[24]
Fig. 6. Water collection process of superhydrophilic/superhydrophobic venation network[24]. (a) (b) Water self-transporting by first and second order channels; (c) water collection process of venation network; (d) water collecting by third and fourth order channels; (e) cross sections of water droplets collected by venation network
Fig. 7. Micro-nanostructures and wettability of the oil-triggered surface (OTS)[31]. (a) Micro-nanostructures of superamphiphobic (SAB, purple) and superhydrophobic-superoleophilic (SHB-SOL, orange) areas; (b) XPS spectrum of the surface of superamphiphobic (purple) and superhydrophobic-superoleophilic (orange) areas; (c)(d) micro-nanostructures of superamphiphobic areas; (e)(f) micro-nanostructures of superhydrophobic-superoleophilic areas; (g) liquid contact angles of superamphiphobic or superhydrophobic-superoleophilic areas
Fig. 8. Oil-triggered wettability transition of OTS[31]. (a) Schematic of oil-triggered wettability transition; (b) surface shows isotropic superhydrophocity before adding oil; (c) oil spreads on the SHB-SOL area; (d) surface shows anisotropic superhydrophocity after adding oil; (e) water droplet rolls freely on the oil-free track; (f) water droplet rolls along the oily track; (g)(h) energy state of the droplet on SLIS or SAB areas
Fig. 9. Schematic illustrations of pulse injection controlled ultrafast laser direct writing strategy[39]
Fig. 10. Micro-nanostructures prepared by pulse injection controlled ultrafast laser processing strategy and their reflectance[39]. (a) Micro-nanostructures; (b) reflectance
Fig. 12. SEM images of micro-nanostructures prepared by laser-thermal-oxidation fabrication strategy and its performance of antireflection[40]. (a) Structure; (b) antireflection
Fig. 13. Macroscopic and microscopic morphologies of the surfaces with different micro and nano structures.[41] (a)--(d) Optical photos; (e)--(h) SEM photos; (i)--(l) laser confocal 3D images; (a)(e)(i) structure 1; (b)(f)(j) structure 2; (c)(g)(k) structure 3; (d)(h)(l) structure 4, cauliflower-shaped micro-nano hierarchical structure
Fig. 14. Broadband omnidirectional light absorption performance, photo-thermal conversion efficiencies and the average absorptance of the surface[41]. (a)(b) Broadband omnidirectional light absorption performance; (c) photo-thermal conversion efficiency; (d) average absorptance
Fig. 15. Laser-assisted doping Fe3O4 nanoparticles[46]. (a) SEM images of Fe3O4 nanoparticles and Auger electron spectra at different points; (b) polarization curves of Ni-Fe-O clusters and commercial RuO2; (c)(d) overpotentials at different current densities and stability testing of Ni-Fe-O clusters
Fig. 16. Three-dimensional stainless steel nanoparticles[48]. (a)--(c) Digital photograph and SEM images of stainless steel catalytic electrode; (d)--(e) OER polarization curves and Tafel slopes of different stainless steel-based samples and commercial RuO2; (f) amperometric measurement of stainless steel catalytic electrode for long-term stability
Fig. 17. Hierarchical three-dimensional self-supporting micro-nano structure. (a1)--(a3)SEM images of hierarchical porous WO3 nanoparticle aggregates[49]; (b1)--(b3)SEM images at different magnifications for L-W
Fig. 18. Ag SERS substrates fabricated by femtosecond laser[68]. (a) SEM image of S-Ag-Ar substrate; (b) Raman spectra of R6G solutions on S-Ag-Ar substrates with different concentrations; (c) Raman spectra of eleven random points on the S-Ag-Ar SERS substrates with the concentration of R6G being 10-7 mol/L; (d) relationship between Raman signal intensity and analyte concentration; (e) variation tendency of Raman signal intensity of R6G with the storage time of S-Ag-Ar SERS substrates
Fig. 19. Superhydrophobic PTFE SERS substrates fabricated by femtosecond laser[72]. (a) SEM images of the laser-processed superhydrophobic PTFE; (b) Raman spectra of 10-6 mol/L R6G aqueous solution mixed with gold sol deposited PTFE sample
Fig. 20. Patterned superhydrophilic-superhydrophobic SERS substrate fabricated by femtosecond laser[75]. (a) SEM images of the R6G and AuNSs aggregating on the central area after evaporation concentration; (b) Raman spectra of R6G@AuNSs with different concentrations; (c) Raman signals of seven random points on substrate surface with 10-12 mol/L and 10-14 mol/L R6G solutions
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Xiao Luo, Weijian Liu, Hongjun Zhang, Minlin Zhong. Ultrafast Laser Fabricating of Controllable Micro-Nano Dual-Scale Metallic Surface Structures and Their Functionalization[J]. Chinese Journal of Lasers, 2021, 48(15): 1502002
Category: laser manufacturing
Received: Mar. 22, 2021
Accepted: Apr. 27, 2021
Published Online: Aug. 5, 2021
The Author Email: Minlin Zhong (zhml@mail.tsinghua.edu.cn)