Electronics and Packaging, Volume. 25, Issue 7, 70107(2025)
Recent Progress in Electroless Plating Process for Metallization of Through Glass Via
[5] [5] OKORO C, JAYARAMAN S, POLLARD S. Understanding and eliminating thermo-mechanically induced radial cracks in fully metallized through-glass via (TGV) substrates[J]. Microelectronics Reliability, 2021, 120: 114092.
[8] [8] YU T, CHEN X, WANG M Y, et al. On-chip single/dual-notch-band half-mode substrate integrated plasmonic waveguide filters based on through glass via technology[J]. IEEE Transactions on Components, Packaging and Manufacturing Technology, 2025, 15(4): 880-883.
[9] [9] YU T, YU D Q. Electrical performance characterization of glass substrate for millimeter-wave applications[J]. Journal of Materials Science: Materials in Electronics, 2023, 34(2): 126.
[10] [10] LAI Y Y, PAN K, PARK S. Thermo-mechanical reliability of glass substrate and through glass vias (TGV): a comprehensive review[J]. Microelectronics Reliability, 2024, 161: 115477.
[11] [11] NIU X B, STAGON S P, HUANG H C, et al. Smallest metallic nanorods using physical vapor deposition[J]. Physical Review Letters, 2013, 110(13): 136102.
[12] [12] OPIEKUN Z A, OROWICZ W A. Physical vapour deposition coatings on elements of pressure casting dies[J]. Surface Engineering, 2006, 22(1): 69-72.
[13] [13] LAXANE R B, BHIDE R S, PATIL A S, et al. Characterisation of chromium nitride physical vapour deposition coating on diesel engine pistons[J]. Surface Engineering, 2006, 22(1): 78-80.
[14] [14] TIAN W, DAI J Y, ZHANG L J, et al. Microstructure and properties of nanocrystalline Cu-Ta thin films prepared by direct current magnetron sputtering[J]. Surface Engineering, 2021, 37(2): 160-168.
[15] [15] SHARKO S A, SEROKUROVA A I, NOVITSKII N N, et al. A new approach to the formation of nanosized gold and beryllium films by ion-beam sputtering deposition[J]. Nanomaterials, 2022, 12(3): 470.
[16] [16] CHO S, FUKE I, PRABHU V. Motion planning for coating process optimisation in electron beam physical vapour deposition[J]. Surface Engineering, 2005, 21(4): 279-289.
[17] [17] RAHMANI H, CABANAS I L. Development of alloy coatings by electron beam physical vapour deposition method[J]. Surface Engineering, 2021, 37(3): 325-333.
[18] [18] JEON N L, NUZZO R G. Physical and spectroscopic studies of the nucleation and growth of copper thin films on polyimide surfaces by chemical vapor deposition[J]. Langmuir, 1995, 11(1): 341-355.
[19] [19] ALI M, RGEN M, KAWASHIMA A. High purity diamond films synthesised by chemical vapour deposition[J]. Surface Engineering, 2012, 28(10): 791-795.
[20] [20] TRIPATHI T S, WILKEN M, HOPPE C, et al. Atomic layer deposition of copper metal films from Cu(acac)2 and hydroquinone reductant[J]. Advanced Engineering Materials, 2021, 23(10): 2100446.
[21] [21] GUPTA B, HOSSAIN M A, RIAZ A, et al. Recent advances in materials design using atomic layer deposition for energy applications[J]. Advanced Functional Materials, 2022, 32(3): 2109105.
[22] [22] SUN P, SHEN X X, XU P, et al. Conductive polyaniline film synthesized through in situ polymerization as a conductive seed layer for hole metallization of printed circuit boards[J]. Applied Surface Science, 2024, 655: 159649.
[24] [24] TOUIR R, LARHZIL H, EBNTOUHAMI M, et al. Electroless deposition of copper in acidic solutions using hypophosphite reducing agent[J]. Journal of Applied Electrochemistry, 2006, 36(1): 69-75.
[25] [25] ANIK T, EL HALOUI A, EBN TOUHAMI M, et al. Influence of N-N dimethyl formamide on electroless copper plating using hypophosphite as reducing agent[J]. Surface and Coatings Technology, 2014, 245: 22-27.
[26] [26] HUNG A. Electroless Copper deposition with hypophosphite as reducing agent[J]. Plating and Surface Finishing, 1988, 75(1): 62-65.
[27] [27] HUANG G Y, XU S M, XU G, et al. Preparation of fine nickel powders via reduction of nickel hydrazine complex precursors[J]. Transactions of Nonferrous Metals Society of China, 2009, 19(2): 389-393.
[28] [28] KARTHIKEYAN S, VASUDEVAN T, SRINIVASAN K N, Studies on formaldehyde-free electroless copper deposition[J]. Plating and Surface Finishing, 2002, 89(7): 54-56.
[29] [29] ZHANG Y, ZONG B Y, JIN J, et al. Electroless copper plating on particulate reinforcements and effects on mechanical properties of SiCp/Fe composite[J]. Surface Engineering, 2015, 31(3): 232-239.
[30] [30] PAUNOVIC M. Fundamentals of electrochemical deposition[M]. New Jersey: Wiley, 2006.
[31] [31] GHOSH S. Electroless copper deposition: a critical review[J]. Thin Solid Films, 2019, 669: 641-658.
[32] [32] NOBARI N, BEHBOUDNIA M, MALEKI R. Palladium-free electroless deposition of pure copper film on glass substrate using hydrazine as reducing agent[J]. Applied Surface Science, 2016, 385: 9-17.
[33] [33] CHEN Y Z, ZHANG J H, GAO L B, et al. An optimized NiP seed layer coating method for through glass via (TGV)[J]. Microelectronic Engineering, 2022, 257: 111735.
[34] [34] KOBETS A V, VOROBYOVA T N. Palladium catalyst synthesis through sol-gel processing for electroless nickel deposition on glass[J]. Thin Solid Films, 2016, 616: 793-799.
[35] [35] KAEWVILAI A, TANATHAKORN R, LAOBUTHEE A, et al. Electroless copper plating on nano-silver activated glass substrate: a single-step activation[J]. Surface and Coatings Technology, 2017, 319: 260-266.
[36] [36] ONITAKE S, ONISHI T. Direct copper metallization on glass technology x-substrate[C]//2017 IMAPS Nordic Conference on Microelectronics Packaging (NordPac), Gothenburg, 2017: 35-37.
[37] [37] OKABE K, KAGAMI T, HORIUCHI Y, et al. Copper plating on glass using a solution processed copper-titanium oxide catalytic adhesion layer[J]. Journal of the Electrochemical Society, 2016, 163(5): D201-D205.
[38] [38] CHENG C W, CHAN P-F, DOW W P. Direct copper pattern plating on glass and ceramic substrates using an Al-doped ZnO as an adhesive and conducting layer[J]. Journal of the Electrochemical Society, 2017, 164(12): D687-D693.
[39] [39] XU L, LIU G L, ZHANG H W, et al. Nano-silver doped zinc oxides adhesion layer for wet copper metallization of glass substrates[J]. Journal of the Electrochemical Society, 2025, 172(1): 012507.
[40] [40] CHANG Y H, WANG W Y, TSENG P L, et al. All-solution-processed metallization of high aspect ratio through glass vias (HAR-TGVs) with a high adhesion promoting layer (APL)[C]//2023 18th International Microsystems, Packaging, Assembly and Circuits Technology Conference (IMPACT), Taipei, China, 2023: 251-254.
[41] [41] LIU Z C, HE Q G, TANG J X, et al. A new approach on the active treatment for electroless copper plating on glass[J]. Chinese Journal of Chemistry, 2003, 21(1): 1-3.
[42] [42] LIU Z C, HE Q G, HOU P, et al. Electroless plating of copper through successive pretreatment with silane and colloidal silver[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2005, 257: 283-286.
[43] [43] KAWASE T, FUJ T, MINAGAWA M, et al. Surface modification of glass by end-capped fluoroalkyl-functional silanes[J]. Journal of Adhesion Science and Technology, 1996, 10(10): 1031-1046.
[44] [44] HU J D, LI W, CHEN J, et al. Novel plating solution for electroless deposition of gold film onto glass surface[J]. Surface and Coatings Technology, 2008, 202(13): 2922-2926.
[45] [45] BAJPAI V K, PANDEY H, SINGH T, et al. Ultrasonic-assisted surface roughening of glass substrate to improve adhesion of electroless nickel seed layer in microsystems packaging[J]. Materials Letters, 2022, 316: 132033.
[46] [46] MGICA-VIDAL R, ALBA-ELAS F, SAINZ-GARCA E, et al. Atmospheric pressure air plasma treatment of glass substrates for improved silver/glass adhesion in solar mirrors[J]. Solar Energy Materials and Solar Cells, 2017, 169: 287-296.
[47] [47] YANG L Q, YANG X L, GAO F, et al. Enhanced adhesion of copper films on fused silica glass substrate by plasma pre-treatment[J]. Materials, 2023, 16(14): 5152.
[48] [48] JEONG E, ZHAO G Q, LEE S G, et al. Exploring SiOxas an effective adhesion promoter for Ag on glass and polymer substrates[J]. Applied Surface Science, 2025, 688: 162342.
[49] [49] BAKAR A A, HASHIM N H, TAJUDDIN H A, et al. Eliminating adhesive layers in silver metallization: a comparative study of glass cleaning methods for enhanced hydroxylation and adhesion[J]. Current Applied Physics, 2025, 71: 138-143.
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SUN Peng, ZHONG Yi, YU Daquan. Recent Progress in Electroless Plating Process for Metallization of Through Glass Via[J]. Electronics and Packaging, 2025, 25(7): 70107
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Received: May. 2, 2025
Accepted: Aug. 26, 2025
Published Online: Aug. 26, 2025
The Author Email: ZHONG Yi (zhongyi@xmu.edu.cn)