Acta Optica Sinica, Volume. 42, Issue 22, 2230001(2022)

Fluorescence Background Subtraction Algorithm of UV Raman Based on Morphology and Polynomial Fitting

Ganshang Si1,2, Jiaxiang Liu1, Zhengang Li1,2, Zhiqiang Ning1,2, and Yonghua Fang1,2、*
Author Affiliations
  • 1Key Laboratory of Environmental Optics and Technology, Anhui Institute of Optics and Fine Mechanics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, Anhui , China
  • 2University of Science and Technology of China, Hefei 230026, Anhui , China
  • show less
    Figures & Tables(11)
    Raman and fluorescence spectral ranges (excitation light wavelength is 266 nm)
    Baseline correction. (a) Morphological algorithm; (b) polynomial fitting algorithm
    Baseline correction based on morphology and polynomial joint
    Comparison of correction effects for different baselines using different methods. (a) Sine function; (b) Gaussian function;(c) Sigmoid function; (d) logarithmic function
    Influence of parameter setting on baseline correction effect
    Sample preparation and experimental device. (a) Sample preparation; (b) UV Raman spectroscopy setup
    Original spectra of potassium nitrate samples on different substrates
    Results of baseline correction of potassium nitrate powder on different substrates obtained by Mor+poly and airPLS algorithms. (a) Paper; (b) transparent acrylic sheet; (c) blue acrylic sheet; (d) metal aluminum
    • Table 1. Parameters of Gaussian function

      View table

      Table 1. Parameters of Gaussian function

      Numberabc
      11401205
      21035010
      3405506
      410750120
      51508808
    • Table 2. Comparison of baseline correction effects of different methods

      View table

      Table 2. Comparison of baseline correction effects of different methods

      Baseline typeParameterImorModpolyairPLSMor+poly
      SineOptimal parametersw=25n=6w=25, n=6
      RMSE0.3051.1150.2040.134
      GaussianOptimal parametersw=25n=8w=25, n=8
      RMSE1.0682.5371.0411.032
      SigmoidOptimal parametersw=25n=8w=25, n=8
      RMSE1.0651.3890.2810.256
      LogarithmOptimal parametersw=25n=7w=25, n=7
      RMSE0.3941.0710.3720.322
    • Table 3. Comparison of Stdev after baseline correction by different methods

      View table

      Table 3. Comparison of Stdev after baseline correction by different methods

      Raman spectrum of different substratesStdev of airPLS algorithmStdev of Mod+poly algorithm
      Paper10.409.37
      Acrylic-transparent32.0723.17
      Acrylic-blue22.0713.12
      Metal aluminum13.7511.65
    Tools

    Get Citation

    Copy Citation Text

    Ganshang Si, Jiaxiang Liu, Zhengang Li, Zhiqiang Ning, Yonghua Fang. Fluorescence Background Subtraction Algorithm of UV Raman Based on Morphology and Polynomial Fitting[J]. Acta Optica Sinica, 2022, 42(22): 2230001

    Download Citation

    EndNote(RIS)BibTexPlain Text
    Save article for my favorites
    Paper Information

    Category: Spectroscopy

    Received: Apr. 15, 2022

    Accepted: May. 25, 2022

    Published Online: Nov. 7, 2022

    The Author Email: Fang Yonghua (yhfang@aiofm.ac.cn)

    DOI:10.3788/AOS202242.2230001

    Topics