Journal of Inorganic Materials, Volume. 39, Issue 6, 697(2024)

Effect of B4C Content on Mechanical Properties and Oxidation Resistance of (Ti0.25Zr0.25Hf0.25Ta0.25)B2-B4C Ceramics

Guoang LIU, Hailong WANG*, Cheng FANG*, Feilong HUANG, and Huan YANG
Author Affiliations
  • School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
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    Figures & Tables(14)
    XRD patterns of different ceramic samples
    Surface morphologies and EDS analysis of different ceramic samples
    Surface morphology and EPMA analysis of HBC-1 sample
    Fracture morphologies of different ceramic samples
    SEM images of crack propagation of HBC-2 sample
    XRD patterns of different ceramic samples after static oxidation for 1 h
    Cross-sectional morphologies of different ceramic samples after static oxidation at different temperatures for 1 h
    Surface morphologies of different ceramic samples after static oxidation at 800 ℃
    Surface morphology and EDS mappings of HBC-1 sample after static oxidation at 800 ℃
    Surface morphologies of different ceramic samples after static oxidation at 1100 ℃
    Surface morphologies of different ceramic samples after static oxidation at 1400 ℃
    • Table 1. FWHM and crystallinity of the corresponding diffraction peaks of different ceramic samples

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      Table 1. FWHM and crystallinity of the corresponding diffraction peaks of different ceramic samples

      CrystallineHBC-0HBC-1HBC-2HBC-3
      FWHM (2θ)/(°)(101)0.187±0.0020.186±0.0020.194±0.0020.199±0.002
      (100)0.119±0.0010.118±0.0020.131±0.0020.126±0.002
      (001)0.153±0.0020.151±0.0030.163±0.0040.184±0.003
      Crystallinity/%(101)68.51±0.5570.30±0.8070.75±0.8568.93±0.81
      (100)81.77±0.8581.85±1.2682.78±1.3181.92±1.14
      (001)88.85±1.0489.39±1.6789.34±1.8690.85±1.61
    • Table 2. Relative density and porosity of different ceramic samples

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      Table 2. Relative density and porosity of different ceramic samples

      SampleTheoretical density/(g·cm-3) Bulk density/(g·cm-3) Relative density/%Porosity/%
      HBC-08.598.0794.06.0
      HBC-18.037.6695.44.6
      HBC-27.787.5096.43.6
      HBC-37.547.4098.11.9
    • Table 3. Flexural strength, fracture toughness and hardness of different ceramic samples

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      Table 3. Flexural strength, fracture toughness and hardness of different ceramic samples

      SampleFlexural strength/MPa Fracture toughness/(MPa·m1/2) Vickers hardness/GPa
      HBC-0409.0±37.43.22±0.1321.5±0.5
      HBC-1273.0±11.24.85±0.1622.2±0.3
      HBC-2570.0±27.65.58±0.3624.6±1.1
      HBC-3418.0±8.35.14±0.4523.3±0.8
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    Guoang LIU, Hailong WANG, Cheng FANG, Feilong HUANG, Huan YANG. Effect of B4C Content on Mechanical Properties and Oxidation Resistance of (Ti0.25Zr0.25Hf0.25Ta0.25)B2-B4C Ceramics [J]. Journal of Inorganic Materials, 2024, 39(6): 697

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    Paper Information

    Category:

    Received: Nov. 28, 2023

    Accepted: --

    Published Online: Jul. 31, 2024

    The Author Email: Hailong WANG (119whl@zzu.edu.cn), Cheng FANG (fangcheng@zzu.edu.cn)

    DOI:10.15541/jim20230544

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