Journal of Inorganic Materials, Volume. 39, Issue 5, 457(2024)
Recently, organic-inorganic hybrid perovskite solar cells have demonstrated a broad commercial prospect due to their high photoelectric conversion efficiency (PCE) and low fabricating costs. During the past decades, the highest reported PCE of small-area (<1 cm2) perovskite solar cells (PSCs) rose to 26.10%, and those of large-area (1-10 cm2), mini-module level (10-800 cm2) and module level (>800 cm2) PSCs increased to 24.35%, 22.40% and 18.60%, respectively. The performance of PSCs decreases dramatically with the area increasing due to limitation of the deposition method and the poor quality of large-area perovskite films. Spin-coating method is not suitable for actual industrial production, while the scalable deposition methods including blade-coating and slot-die coating still face the difficulty of precisely controlling nucleation and crystallization of the perovskite films with large area. This review summarized preparation methods of large-area perovskite films, and discussed the film-forming mechanism and strategies for high-quality perovskite films. Finally, relevant outlooks on technologies and applications for large-area PSCs with high performances and stabilities were analyzed. This review is expected to provide insights on the research of large-area PSCs with high performance.
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Hui ZHANG, Zhipeng XU, Congtan ZHU, Xueyi GUO, Ying YANG.
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Received: Sep. 28, 2023
Accepted: --
Published Online: Jul. 8, 2024
The Author Email: Ying YANG (muyicaoyang@csu.edu.cn)