Chinese Journal of Lasers, Volume. 49, Issue 14, 1402806(2022)

Electrochemical Corrosion Characteristics of Ti-6Al-4V Repaired Using Underwater Directed Energy Deposition Technique

Zhandong Wang, Shibin Wang, Erke Wu, Kedong Bi, Zhonghua Ni, and Guifang Sun*
Author Affiliations
  • School of Mechanical Engineering and Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments, Southeast University, Nanjing 211189, Jiangsu, China
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    Figures & Tables(12)
    Dimension of preprepared trapezoidal groove on Ti-6Al-4V substrate
    Underwater and in-air directed energy deposition and photos of as-repaired samples. (a) Schematic of underwater directed energy deposition (UDED); (b) actual manufacturing process of UDED; (c) as-repaired sample by UDED; (d) schematic of in-air directed energy deposition (in-air DED); (e) actual manufacturing process of in-air DED; (f) as-repaired sample by in-air DED
    Microstructures of repaired zone of Ti-6Al-4V repaired by UDED and in-air DED. (a)-(c) Microstructures repaired by UDED; (d)-(f) microstructures repaired by in-air DED
    Electron back scatter diffraction (EBSD) maps showing the microstructures. (a) Microstructure repaired by UDED; (b) microstructure repaired by in-air DED; (c) inverse pole figure of microstructure repaired by UDED; (d) inverse pole figure of microstructure repaired by in-air DED
    Transmission electron microscopy (TEM) analysis. (a) TEM image of the top region of UDED microstructure; (b) bright field image showing α′ lath martensite in the middle region of UDED microstructure; (c) selected area electron diffraction (SAED) pattern of UDED microstructure; (d) TEM image of the top region of in-air DED microstructure; (e) bright field image showing α lath in the middle region of in-air DED sample; (f) SAED pattern of in-air DED microstructure
    Microhardness analysis of three samples. (a) Microhardness distribution of repaired zone; (b) average microhardness
    Polarization curves of UDED specimen, in-air DED specimen and substrate in 3.5% NaCl solution. (a) Potentiodynamic polarization curves; (b) Tafel polarization curves
    Electrochemical impedance spectroscopy (EIS) of UDED Ti-6Al-4V, in-air DED Ti-6Al-4V, and substrate. (a) Nyquist plot; (b)(c) Bode plots; (d) equivalent simulated circuit used for EIS analysis
    SEM images and energy dispersive spectroscopy (EDS) analysis of the surfaces before and after corrosion tests. (a) Surface of UDED Ti-6Al-4V before corrosion test; (b)-(d) surface of UDED Ti-6Al-4V after corrosion test and EDS analysis of lumps in corrosion pits; (e) surface of in-air DED Ti-6Al-4V before corrosion test; (f)-(h) surface of in-air DED Ti-6Al-4V after corrosion test and EDS analysis of lumps in corrosion pits; (i) surface of the substrate after corrosion test
    • Table 1. Technological parameters for Ti-6Al-4V repaired by UDED and in-air DED

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      Table 1. Technological parameters for Ti-6Al-4V repaired by UDED and in-air DED

      ParameterValue
      UDEDIn-air DED
      Laser power /W13001300
      Scanning speed /(mm·min-1)10001000
      Powder feed rate /(g·min-1)55
      Hatch spacing /mm11
      Layer height /mm0.650.65
      Powder gas flow /(L·min-1)1210
      Coaxial gas flow /(L·min-1)83
      Carrier gas flow /(L·min-1)83
      Gas curtain gas flow /(L·min-1)200-
      Water depth /mm60-
    • Table 2. Corrosion parameters obtained from polarization curves

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      Table 2. Corrosion parameters obtained from polarization curves

      SpecimenEcorr/Vicorr/(μA·cm-2)Ep/Vip/(μA·cm-2)
      UDED-0.23540.09171.4041.628
      In-air DED-0.29780.09951.4552.474
      Substrate-0.24300.0861 2.072
    • Table 3. Electrical parameters of equivalent simulated circuit

      View table

      Table 3. Electrical parameters of equivalent simulated circuit

      SpecimenRs/(Ω·cm2)CPEf/(10-5F·cm-2)n1Rf/(Ω·cm2)Rct/(kΩ·cm2)CPEdl/(10-6F·cm-2)n2
      UDED14.082.1640.8502996.90.84376.1930.8821
      In-air DED20.285.4800.6951290.40.68289.5550.7243
      Substrate13.541.1530.8931135400.66069.7960.7445
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    Zhandong Wang, Shibin Wang, Erke Wu, Kedong Bi, Zhonghua Ni, Guifang Sun. Electrochemical Corrosion Characteristics of Ti-6Al-4V Repaired Using Underwater Directed Energy Deposition Technique[J]. Chinese Journal of Lasers, 2022, 49(14): 1402806

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    Paper Information

    Received: Oct. 8, 2021

    Accepted: Dec. 23, 2021

    Published Online: Jun. 14, 2022

    The Author Email: Sun Guifang (gfsun@seu.edu.cn)

    DOI:10.3788/CJL202249.1402806

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