Journal of Inorganic Materials, Volume. 39, Issue 8, 920(2024)

Oxidation Behavior and Meso-macro Model of Tubular C/SiC Composites in High-temperature Environment

Wenxin QUAN, Yiping YU, Bing FANG, Wei LI, and Song WANG*
Author Affiliations
  • Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, College of Aerospace Science and Engineering, National University of Defense Technology, Changsha 410073, China
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    Figures & Tables(16)
    Tubular specimen of C/SiC composite
    Ring tensile experiment of C/SiC composite
    Crack healed through thermal expansion and oxidation of SiC matrix
    Diffusion of oxygen in SiC cracks (a) and oxidation channel of carbon fibers (b)
    Equivalent oxidation depth of tubular C/SiC composite
    Mass retention rate (a), function fitting of $ \left(1-\eta_{\mathrm{m}}\right)^{2}$ with t (b), strength retention rate (c), and function fitting of $ \left(1-\eta_{\mathrm{R}}\right)^{2}$ with t (d) for tubular C/SiC composites after high-temperature air oxidation
    Morphology and distributions of elements on the surface of tubular C/SiC composite
    Microstructures at fractures of tubular C/SiC composites after high-temperature air oxidation
    Microstructures at fractures of carbon fibers in tubular C/SiC composites after high-temperature air oxidation
    Microstructures of cross-sections of tubular C/SiC composites after high-temperature air oxidation
    EDS distributions of oxygen contents at cross sections of tubular C/SiC composites after 1100 ℃-1 h (a), 1300 ℃-0.5 h (b) and 1300 ℃-1 h (c) high-temperature air oxidation
    Distributions of mole fraction of oxygen (a), gradient of mole fraction (b) and mole fraction with diffusion progress (c) in microcracks of SiC matrix
    Predicted results of strength retention rate (a) and mass retention rate (b)
    • Table 1. Parabolic rate constant of SiC in air oxidation

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      Table 1. Parabolic rate constant of SiC in air oxidation

      Parameter900 ℃1000 ℃1100 ℃1200 ℃1300 ℃
      B/(nm2∙min-1)1.0510.2939.4884.84163.17
    • Table 2. Parameters of oxidation for 10 h

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      Table 2. Parameters of oxidation for 10 h

      Parameter900 ℃1100 ℃1300 ℃
      $ D_{\mathrm{O}_{2}}^{z} $/(m2∙s–1)3.18×10-53.53×10-53.86×10-5
      B/(nm2∙s-1)0.01750.6582.720
      Z/μm0.02510.15390.3129
      e/μm1.9801.8351.658
      $ R_{\mathrm{O}_{2}}^{z} $/(mol∙m–3∙s–1)1.937×10-21.128×10-22.880×10-1
    • Table 3. Modifying factor of equivalent oxidation depth

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      Table 3. Modifying factor of equivalent oxidation depth

      Modifying factor900 ℃1100 ℃1300 ℃
      $ \beta $1.2×10-53.1×10-56.0×10-5
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    Wenxin QUAN, Yiping YU, Bing FANG, Wei LI, Song WANG. Oxidation Behavior and Meso-macro Model of Tubular C/SiC Composites in High-temperature Environment[J]. Journal of Inorganic Materials, 2024, 39(8): 920

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    Paper Information

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    Received: Jan. 2, 2024

    Accepted: --

    Published Online: Dec. 12, 2024

    The Author Email: Song WANG (wangs0731@163.com)

    DOI:10.15541/jim20240002

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