Detection of Heavy Metals in Aqueous Solution via Surface‐Enhanced Laser‑Induced Breakdown Spectroscopy Using Microstructures Fabricated by Microchip Laser

Huanming Shan; Zenghui Wang; Runhua Li; Yuqi Chen

doi:10.3788/CJL240918

Chinese Journal of Lasers, Volume. 52, Issue 2, 0211001(2025)

Detection of Heavy Metals in Aqueous Solution via Surface‐Enhanced Laser‑Induced Breakdown Spectroscopy Using Microstructures Fabricated by Microchip Laser

Huanming Shan, Zenghui Wang, Runhua Li, and Yuqi Chen^*

Author Affiliations

School of Physics and Optoelectronics, South China University of Technology, Guangzhou 510641, Guangdong , China

show less

Abstract Get PDF(in Chinese)

References(27)

[1] Ge T, Wang Q Y, Chen A M et al. Effect of metal substrate temperature on the determination of trace metal elements in water by combined LIBS with electro-deposition[J]. Journal of Analytical Atomic Spectrometry, 37, 2510-2516(2022).

[2] Ren J, Yang Z H, Zhao Y R et al. Collinear double-pulse laser-induced breakdown spectroscopy based Cd profiling in the soil[J]. Optics Express, 30, 37711-37726(2022).

[3] Wang Y T, Li H L, Yin X L et al. Research on water heavy metal element detection using surface-enhanced LIBS based on coffee ring enrichment[J]. Measurement, 224, 113869(2024).

[4] Li W P, Zhou W D. Comparative study of underwater single pulse and orthogonal double pulse laser-induced breakdown spectroscopy of Barium element in solution[J]. Chinese Journal of Lasers, 46, 0911003(2019).

[5] Li X Y, Liu K, Zhou R et al. Laser-induced breakdown spectroscopy and its application[J]. Chinese Journal of Lasers, 49, 1202003(2022).

[6] Álvarez J, Velásquez M, Sandoval-Muñoz C et al. Improved mineralogical analysis in copper ores by laser-induced breakdown spectroscopy[J]. Journal of Analytical Atomic Spectrometry, 37, 1994-2004(2022).

[7] Wang J M, Lu J S, Zheng P C et al. Study on alkalinity measurement of sinter based on LIBS technology combined with internal standard method[J]. Chinese Journal of Lasers, 50, 2211001(2023).

[8] Gao Y, Sun L X, Li X Y et al. On-line analysis of sinter mixture composition and correction of moisture influence based on laser-induced breakdown spectroscopy[J]. Chinese Journal of Lasers, 50, 1911001(2023).

[9] Chen P, Qi C, Liu R W et al. Quantitative analysis of carbon content in fly ash using LIBS based on support vector machine regression[J]. Acta Optica Sinica, 42, 0930003(2022).

[10] Al-Salihi M, Yi R X, Wang S Q et al. Quantitative laser-induced breakdown spectroscopy for discriminating neoplastic tissues from non-neoplastic ones[J]. Optics Express, 29, 4159-4173(2021).

[11] Chen Z P, Ren X, Liu J J et al. Probabilistic multivariable calibration for major elements analysis of MarSCoDe Martian laser-induced breakdown spectroscopy instrument on Zhurong rover[J]. Spectrochimica Acta Part B: Atomic Spectroscopy, 197, 106529(2022).

[12] Díaz Pace D M, D’Angelo C A, Bertuccelli D et al. Analysis of heavy metals in liquids using Laser Induced Breakdown Spectroscopy by liquid-to-solid matrix conversion[J]. Spectrochimica Acta Part B: Atomic Spectroscopy, 61, 929-933(2006).

[13] Shimazu Y, Matsumoto A, Nakano H et al. Sensitive quantitative analysis of strontium in microdroplet by surface-enhanced laser-induced breakdown spectroscopy using porous silicon[J]. Analytical Sciences, 37, 1839-1841(2021).

[14] Yang X Y, Hao Z Q, shen M et al. Simultaneous determination of La, Ce, Pr, and Nd elements in aqueous solution using surface-enhanced laser-induced breakdown spectroscopy[J]. Talanta, 163, 127-131(2017).

[15] Chen Z J, Li H K, Liu M et al. Fast and sensitive trace metal analysis in aqueous solutions by laser-induced breakdown spectroscopy using wood slice substrates[J]. Spectrochimica Acta Part B: Atomic Spectroscopy, 63, 64-68(2008).

[16] Bae D, Nam S H, Han S H et al. Spreading a water droplet on the laser-patterned silicon wafer substrate for surface-enhanced laser-induced breakdown spectroscopy[J]. Spectrochimica Acta Part B: Atomic Spectroscopy, 113, 70-78(2015).

[17] Kaplan D, Aras N, Yalçın Ş. Design, fabrication, and application of micro-structured surfaces for laser-induced breakdown spectroscopic analysis of liquids: a sample-loading target development studies[J]. Microchemical Journal, 196, 109568(2024).

[18] Wang Q Y, Liu Y T, Jiang L Y et al. Metal micro/nanostructure enhanced laser-induced breakdown spectroscopy[J]. Analytica Chimica Acta, 1241, 340802(2023).

[19] Yao Y Q, He F, Lin Q Y et al. Synchronous detection of heavy metal ions in aqueous solution by gold nanoparticle surface-enhanced laser-induced breakdown spectroscopy[J]. Journal of Analytical Atomic Spectrometry, 36, 2639-2648(2021).

[20] Niu S, Zheng L J, Khan A Q et al. Laser-induced breakdown spectroscopic detection of trace level heavy metal in solutions on a laser-pretreated metallic target[J]. Talanta, 179, 312-317(2018).

[21] Bonse J, Gräf S. Maxwell meets Marangoni: a review of theories on laser-induced periodic surface structures[J]. Laser & Photonics Reviews, 14, 2000215(2020).

[22] Ji S, Park J, Lim H. Improved antireflection properties of moth eye mimicking nanopillars on transparent glass: flat antireflection and color tuning[J]. Nanoscale, 4, 4603-4610(2012).

[23] Abere M J, Zhong M L, Krüger J et al. Ultrafast laser-induced morphological transformations[J]. MRS Bulletin, 41, 969-974(2016).

[24] Li S S, Li R H, Chen Y Q et al. One-point calibration quantitative elemental analysis of Cu-Zn-Ag alloys with microchip laser-based SD-LIBS[J]. Optik, 270, 169946(2022).

[25] Hanif M, Salik M, Baig M A. Quantitative studies of copper plasma using laser induced breakdown spectroscopy[J]. Optics and Lasers in Engineering, 49, 1456-1461(2011).

[26] Zmerli B, Ben Nessib N, Dimitrijević M S et al. Stark broadening calculations of neutral copper spectral lines and temperature dependence[J]. Physica Scripta, 82, 055301(2010).

[27] Cui Y X, Fung K H, Xu J et al. Ultrabroadband light absorption by a sawtooth anisotropic metamaterial slab[J]. Nano Letters, 12, 1443-1447(2012).

Tools

Get Citation

Copy Citation Text

Huanming Shan, Zenghui Wang, Runhua Li, Yuqi Chen. Detection of Heavy Metals in Aqueous Solution via Surface‐Enhanced Laser‑Induced Breakdown Spectroscopy Using Microstructures Fabricated by Microchip Laser[J]. Chinese Journal of Lasers, 2025, 52(2): 0211001

Download Citation

EndNote(RIS)BibTex Plain Text

Set citation alerts for article

Save article for my favorites

Paper Information

Category: spectroscopy

Received: May. 29, 2024

Accepted: Jun. 28, 2024

Published Online: Jan. 20, 2025

The Author Email: Chen Yuqi (chenyuqi@scut.edu.cn)

DOI:10.3788/CJL240918

CSTR:32183.14.CJL240918

Topics

laser devices and laser physics

Lasers and Laser Optics

Laser physics

laser manufacturing

Instrumentation, Measurement and Metrology