Chinese Journal of Lasers, Volume. 51, Issue 7, 0701010(2024)

Research Progress of Beyond Extreme Ultraviolet Multilayers at 6.X nm

Xiaoran Li1,2, Hetao Tang1,2, Jiaoling Zhao2、*, and Fenghua Li2
Author Affiliations
  • 1School of Microelectronics, Shanghai University, Shanghai 200072, China
  • 2Laboratory of Thin Film Optics, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China
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    Figures & Tables(11)
    Trend for the development of lithographic light sources regarding wavelength
    Schematic of the main optical components in an EUV lithography system[30]
    Schematic view of Bragg diffraction for PMMs
    Real and imaginary parts of the refractive index at 6.7 nm for typical elements (original data obtained from Lawrence Berkeley National Laboratory)[38]
    Calculated results of La/B4C multilayers. (a) Reflectivity curve; (b) curve of reflectivity changing with number of periods; (c) curve of reflectivity variation with substrate roughness
    Calculated results of La/B4C multilayers. (a) Variation of central wavelength of multilayers with different periodic thicknesses; (b) variation of peak reflectivity of multilayers with different interface widths
    Schematic of La/B4C multilayers with barrier layer of carbon[55]. (a) Structures of La/B4C with carbon barrier layer inserted on different interfaces; (b) zoomed-in depth profiles of La+ measured by using TOF-SIMS (reprinted and adapted from Ref. [55] with permission from Elsevier)
    Experiments on the nitridation of La/B interface[7]. (a) Schematic of La/B-based multilayer prepared by using the delayed nitridation method; (b) calculated peak reflectivity for LaN/B multilayers, with BN and LaB6 as interlayers on the LaN-on-B interface (adapted with permission from Ref. [7] © The Optical Society)
    Annealing experiments for La/B4C and LaN/B4C multilayers[65]. (a) Period thicknesses of the La/B4C and LaN/B4C multilayer, for annealing temperatures up to 800 ℃; (b) EUV reflectance curves of the La/B4C multilayer right after deposition, and after annealing to 400 ℃ and 800 ℃, respectively; (c) EUV reflectance curves of the LaN/B4C multilayer right after deposition, and after annealing to 400 ℃ and 800 ℃, respectively (reprinted and adapted from Ref. [65] with permission from Elsevier)
    • Table 1. Advantages and disadvantages of different BEUV light sources

      View table

      Table 1. Advantages and disadvantages of different BEUV light sources

      Light sourceAdvantageDisadvantage
      FELHigh radiation brightness,high power,high efficiency,wide tunability of wavelength,ultra-short pulses19

      Limited output power in narrowband,

      large volume of existing facilities15

      LPPLow debris,feasible power scalability,small & stable plasma spot,design freedom around plasma28Lower conversion efficiency from electricity to EUV,complicated system28
      LDPSimple structure,better target utilization,high energy injection27High thermal load on the electrodes,more prone to corrosion29
    • Table 2. Summary of relevant parameters for BEUV multilayers

      View table

      Table 2. Summary of relevant parameters for BEUV multilayers

      Year

      PMMs

      structure

      d /nmΓPeriod

      Interface roughness

      σ /nm

      Measured

      (theoretical)

      reflectivity /%

      Deposition methodReference
      2013W/B4C3.470.2850

      0.3/0.47

      (W-on-B4C/B4C-on-W)

      7.6Magnetron sputtering58
      2013La/B4C/C3.350.5N/AN/A58.6Magnetron sputtering54
      2013La/B3.48N/A40N/A4.5Electron beam evaporation57
      2013LaN/B3.5N/A175N/A57.3(60)Magnetron sputtering57
      2015La/B4C4.80.4120

      0.4/0.9

      (La-on-B4C/B4C-on-La)

      54.4(69.7)DC magnetron sputtering36
      2015La/LaN/B3.4N/A220N/A64.1DC magnetron sputtering7
      2017La/B4C3.4N/A250

      0.4/1.5

      (La-on-B4C/B4C-on-La)

      51.1DC magnetron sputtering59
      2017LaN/B4C3.4N/A250

      0.4/1.2

      (LaN-on-B4C/B4C-on-LaN)

      58.1DC magnetron sputtering59
      2020MoXC1-X/B4C3.60.4100

      0.2/0.3

      (MoXC1-X-on-B4C/B4C-on- MoXC1-X

      10DC magnetron sputtering60
      2021Mo/B3.40.353000.3‒0.453(63)DC and RF magnetron sputtering40
      2023C/B3.350.6220N/AN/A(58)RF magnetron sputtering61
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    Xiaoran Li, Hetao Tang, Jiaoling Zhao, Fenghua Li. Research Progress of Beyond Extreme Ultraviolet Multilayers at 6.X nm[J]. Chinese Journal of Lasers, 2024, 51(7): 0701010

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    Paper Information

    Category: laser devices and laser physics

    Received: Dec. 11, 2023

    Accepted: Feb. 6, 2024

    Published Online: Apr. 2, 2024

    The Author Email: Zhao Jiaoling (jolin923@siom.ac.cn)

    DOI:10.3788/CJL231495

    CSTR:32183.14.CJL231495

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