Journal of Inorganic Materials, Volume. 40, Issue 6, 719(2025)

Enhancement of Piezoelectric Properties in CaBi4Ti4O15-based Ceramics through Bi3+ Self-doping Strategy

Yangyang ZHOU1,2, Yanyan ZHANG1,2, Ziyi YU1, Zhengqian FU1, Fangfang XU1, Ruihong LIANG1, and Zhiyong ZHOU1、*
Author Affiliations
  • 11. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
  • 22. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
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    Figures & Tables(8)
    (a-e) Surface SEM images of CBT-xBi ceramics after thermal etching; (f) XRD patterns of CBT-xBi ceramics and corresponding localized enlarged patterns(a) x=0; (b) x=0.02; (c) x=0.04; (d) x=0.06; (e) x=0.08
    Dielectric properties of CBT-xBi ceramics(a-c) Dielectric constant as a function of temperature at different frequencies after polarization: (a) x=0, (b) x=0.04 and (c) x=0.06; (d-f) Dielectric constant as a function of temperature at 100 Hz before and after polarization: (d) x=0, (e) x=0.04 and (f) x=0.06
    XPS core-level spectra of CBT-xBi ceramics(a) O1s; (b) Bi4f; (c) Bi4d3/2 and Ti2p
    Characterization of CBT-0.06Bi ceramic sintered in a flowing oxygen atmosphere(a) XRD patterns; (b) SEM image of the thermal etching surface; (c) O1s XPS spectrum; (d) Dielectric temperature spectra at 100 Hz before and after polarization
    (a) Dielectric temperature spectra of CBT-xBi ceramics; (b) Temperature dependence of DC resistivity of CBT-xBi ceramics; (c) Effect of heat treatment on the piezoelectric constants of CBT-xBi ceramics (set temperature annealing 2 h); (d) In-situ XRD patterns of CBT-0.06Bi ceramic; (e) Relationship between lattice constants and unit cell volume with temperature; (f) (119) peak position and I(200)/I(020) changed with temperature
    (a) XRD refinement results of CBT-xBi ceramics; (b) Visual crystal structures of CBT-xBi ceramics; (c) Raman scattering spectra in the range of 80-900 cm-1; (d) Wavenumber displacements of B2g, B3g, A1g, and B1g modes
    PFM characterization of CBT-xBi ceramics(a-c) PFM phase images for (a) x=0, (b) x=0.04, and (c) x=0.06; (d-f) PFM amplitude distribution histograms for (d) x=0, (e) x=0.04, and (f) x=0.06; (g) TEM image of CBT-0.06Bi; (h) 5 μm×5 μm PFM phase image of CBT-0.06Bi; (i) Hysteresis loops of CBT-xBi ceramics after polarizing at 180 ℃ and 1 Hz. Colorful figures are available on website
    • Table 1.

      Results of CBT-xBi ceramics O1s XPS peak fitting analysis

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      Table 1.

      Results of CBT-xBi ceramics O1s XPS peak fitting analysis

      xS1 (Oxygen vacancy area) S2 (Lattice oxygen area) S (Total area, S1+S2) S1/S2S1/S
      05581.8623546.9029128.760.240.19
      0.045635.4028758.7934394.190.200.16
      0.065078.4927836.6332915.120.180.15
      0.06 (Oxygen sintering)3969.8324463.1628432.990.160.14
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    Yangyang ZHOU, Yanyan ZHANG, Ziyi YU, Zhengqian FU, Fangfang XU, Ruihong LIANG, Zhiyong ZHOU. Enhancement of Piezoelectric Properties in CaBi4Ti4O15-based Ceramics through Bi3+ Self-doping Strategy [J]. Journal of Inorganic Materials, 2025, 40(6): 719

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    Paper Information

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    Received: Dec. 26, 2024

    Accepted: --

    Published Online: Sep. 2, 2025

    The Author Email: Zhiyong ZHOU (zyzhou@mail.sic.ac.cn)

    DOI:10.15541/jim20240537

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