Chinese Journal of Liquid Crystals and Displays, Volume. 38, Issue 2, 160(2023)
Research progress of green luminescent materials for lighting and displays
Fig. 1. (a)Comparison of photoluminescence properties of β-Sialon∶Eu2+ powders excited at 365 nm before and after annealing in reducing atmosphere;(b)CIE chromaticity coordinates of β-Sialon∶Eu2+ and K2SiF6∶Mn4+ encapsulated white LEDs;(c)Relationship between emission intensity and temperature of phosphor Sr3-3xSi13Al3O2N21∶3xEu2+;(d)CIE chromaticity coordinates of the white LED[17-19].
Fig. 2. Relationship between laser power density and luminous efficiency measured on samples of different concentrations(a)and thicknesses(b)[21]
Fig. 3. (a)Total spectral flux from the film measured under different laser power/power densities;(b)Infrared thermal image of the film under 26.4 W/mm2 laser irradiation[23].
Fig. 4. (a)PLE and PL spectra of RN∶Eu2+,RLSO∶Eu2+(red dotted line),and β-Sialon∶Eu2+(blue short dotted line);(b)PL spectra of the pristine RbNa(Li3SiO4)2∶Eu2+ and the sample exposed to ambient atmosphere for different days,and the inset shows the dependence of normalized integrated PL intensities on the time;(c)Temperature dependent emission spectra of RbNa(Li3SiO4)2∶Eu2+ at 455 nm excitation;(d)CIE chromaticity coordinates of white LED device[25].
Fig. 5. (a)PL spectra of Rb1+xNa2.97-x(Li3SiO4)4∶Eu2+(0≤x≤2.5)phosphors;(b)Normalized integrated emission intensities and peak intensities of Rb3Na(Li3SiO4)4∶Eu2+as a function of temperature[27].
Fig. 6. (a)Spatial structure of SrMgAl10O17∶Eu2+,Mn2+ phosphors. In the Sr-O conductive layer,Eu2+ ion replaces the Sr2+ ion. In MgAl10O16 spinel,Mn2+ ions replace Mg2+ ions;(b)PL spectrum of the phosphor SrMgAl10O17∶0.4 Eu2+,0.6 Mn2+ excited by 430 nm[32].
Fig. 7. (a)Eu2+ concentration-dependent PL spectra of Sr2(Mg,Mn)Al22O36∶Eu2+samples(λex = 360 nm);(b)Temperature-dependent PL spectra of optimal Sr2(Mg,Mn)Al22O36∶Eu2+sample(λex = 360 nm)[33].
Fig. 8. (a)CIE Chromaticity coordinates of LED encapsulated with YAGG∶Ce ceramics(Inset:picture of Y3Al5-xGaxO12∶Ce(x=0~4)ceramics excited by blue LED chip);(b)Temperature-dependent luminescence intensity of Y3Al5–xGaxO12∶Ce(x=0~4)ceramics[34].
Fig. 9. (a)Luminous efficiency and luminous flux of films with thickness of 0.2 mm under excitation of different input power densities;(b)Temperature dependence of the integrated luminescence intensities for YAGG phosphor and composite films in the temperature range of 25~300 ℃[36].
Fig. 10. (a)At 430 nm excitation,the emission intensity of NaBaB9O15∶Eu2+ varied with temperature,and the emission peak and emission peak intensity of NaBaB9O15∶Eu2+ varied with temperature;(b)Blue LED and K2SiF6∶Mn4+ encapsulated with(Na0.97Eu0.03)BaB9O15,Ba1.14Sr0.86SiO4∶Eu2+ and β-SiAlON∶Eu2+,respectively,to form the CIE Chromaticity coordinates of white LED devices[48].
Fig. 11. (a)Room temperature photoluminescence(PL)and photoluminescence excitation(PLE)spectra of x=2.33;(b)Room temperature photoluminescence(PL)and photoluminescence excitation(PLE)spectra of x=2[50].
Fig. 12. (a)PLE and PL spectra of ZBO∶Mn2+ sample;(b)Thermal stability(integrated emission intensity)comparison between ZBO∶Mn2+ and some representative phosphors[51].
Fig. 13. (a)Emission spectra of ZBO∶Mn2+ and commercial green phosphor(BaSr)2SiO4∶Eu2+ and β- SiAlON∶Eu2+;(b)Thermal quenching data of ZBO∶0.05 Mn2+ and(BaSr)2SiO4∶Eu2+ phosphor[53].
Fig. 14. (a)Emission spectra of BZBP∶0.07 Tb3+ phosphors using traditional solid state reaction method and microwave assisted solid state reaction method;(b)Normalized PL intensity depending on temperature ranging from 298 K to 473 K[62].
Fig. 15. (a)Relationship between x and FWHM at 550 nm for KAlSiO4∶1.5% Tb3+,x% Li+ sample;(b)Variation of spectral light intensity of KAlSiO4∶1.5% Tb3+,1.5% Li+ with temperature[64].
Fig. 16. Excitation and emission spectra of the(a)CGHAO∶0.04 Ce3+(λem=499 nm;λex=408 nm)and(b)CGHAO∶0.4 Tb3+(λem=543 nm;λex=266 nm)phosphors;(c)Comparison of excitation spectrum of CGHAO∶0.4 Tb3+(λem=543 nm)and emission spectrum of CGHAO∶0.04 Ce3+(λex=408 nm)phosphors,demonstrating the existence of spectral overlap;(d)Excitation and emission spectra of CGHAO∶0.04 Ce3+,0.4 Tb3+ phosphors(λem=543 nm;λex=408 nm)[66].
Fig. 17. (a)PL spectra of γ-AlON∶0.07 Mn2+,0.10 Mg2+,0.07 M(M=Li+,Na+,K+,Si4+). The inset shows the correlation of integrated emission intensity and FWHM with different charge compensators;(b)Dependence of the normalized emission intensity of γ-AlON∶0.07 Mn2+,0.10 Mg2+,0.07 M(M=Li+,Na+,K+,Si4+)as a function of temperature[69].
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Xing-can LI, Li-li LU, Chen-yang SHAO, Gui-lu WANG, Xi-gui ZHENG, Yue-long MA, Ye TIAN. Research progress of green luminescent materials for lighting and displays[J]. Chinese Journal of Liquid Crystals and Displays, 2023, 38(2): 160
Category: Research Articles
Received: Aug. 17, 2022
Accepted: --
Published Online: Feb. 20, 2023
The Author Email: Yue-long MA (uhgdmyl@haut.edu.cn), Ye TIAN (yetian@haut.edu.cn)