Journal of Synthetic Crystals, Volume. 54, Issue 3, 462(2025)

Preparation of Ga2O3∶Si Thin Films and Study on the Performance of Its Solar-Blind Ultraviolet Photodetectors

ZHANG Xian, YUE Zhiang, ZHAO Enqin, WEI Shuaikang, YE Wenxuan, HUANG Minyi, XIN Meibo, ZHAO Yang, and WANG Hui*
Author Affiliations
  • Henan Key Laboratory of Photoelectric Energy Storage Materials and Applications, School of Physics and Engineering, Henan University of Science and Technology, Luoyang 471023, China
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    Solar-blind ultraviolet photodetectors (SBPDs) exhibit significant potential for many fields, including military, civil, and medical sectors. In this paper, Si-doped Ga2O3 thin films were prepared by radio frequency magnetron sputtering. The effect of the argon-oxygen flow ratio on the physical properties of the films was studied. The analysis results of crystal structure, optical properties, and surface morphology indicate that the crystalline quality of the film is best when the argon-oxygen flow ratio is 30∶20. The Ga2O3∶Si thin film exhibits preferential growth along the 4ˉ02 crystal plane, with a smooth and flat surface without micro-holes, and an average transmittance of 90% in the range of 400 nm to 800 nm. We fabricated p-GaN/n-Ga2O3∶Si self-powered SBPDs using optimized preparation parameters. Under 254 nm illumination at 0 V, the device shows rise time and decay time of 0.450 and 0.509 s, respectively. The light-dark current ratio (PDCR), responsivity (R), and specific detectivity (D*) are 23, 0.24 mA/W, and 1.67×108 Jones, respectively. The time-response characteristics of the device under 0~-6 V bias were studied. Under 0 V, the device has a spike in response at the 254 nm irradiation. When a reverse bias is applied, the spike disappear. Finally, the energy band diagrams of the p-GaN/Ga2O3∶Si heterojunction before contact, after contact, and under reverse bias are analyzed.

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    ZHANG Xian, YUE Zhiang, ZHAO Enqin, WEI Shuaikang, YE Wenxuan, HUANG Minyi, XIN Meibo, ZHAO Yang, WANG Hui. Preparation of Ga2O3∶Si Thin Films and Study on the Performance of Its Solar-Blind Ultraviolet Photodetectors[J]. Journal of Synthetic Crystals, 2025, 54(3): 462

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    Paper Information

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    Received: Nov. 19, 2024

    Accepted: Apr. 23, 2025

    Published Online: Apr. 23, 2025

    The Author Email: WANG Hui (wanghui08@haust.edu.cn)

    DOI:10.16553/j.cnki.issn1000-985x.2024.0289

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