Chinese Journal of Lasers, Volume. 49, Issue 13, 1311001(2022)

Detection of Plastics Based on Terahertz Time-Domain Spectroscopy

Tong Zhang, Haochong Huang*, Zili Zhang, Hua Gao, Lu Gao, and Zhiyuan Zheng**
Author Affiliations
  • School of Science, China University of Geosciences, Beijing 100083, China
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    Figures & Tables(10)
    Schematic of THz-TDS experimental setup
    Terahertz spectra of HDPE, PP and PVC with different particle sizes. (a) Terahertz time-domain spectra of HDPE, PP, and PVC with particle size of less than 74 μm with corresponding frequency spectra shown in inset; (b) frequency-absorption coefficient correlation curves of HDPE with different particle sizes; (c) frequency-absorption coefficient correlation curves of PP with different particle sizes; (d) frequency-absorption coefficient correlation curves of PVC with different grain sizes with partial enlargement shown in inset
    Terahertz spectra of PVC-PP for different mass ratios. (a) Frequency-absorption coefficient spectra; (b) frequency-refractive index spectra; (c) effects of mass fraction of PVC on refractive index and absorption coefficient measured at 1.3 THz
    Frequency-absorption coefficient and frequency-refractive index correlation curves of HDPE, PP, and PVC mixed with different fillers
    Optical parameters of plastic-filler mixtures versus filler concentration at 1.3 THz. (a) Absorption coefficient of mixture versus CaCO3 concentration; (b) refractive index of mixture versus CaCO3 concentration; (c) absorption coefficient of mixture versus Kaolin concentration; (d) refractive index of mixture versus Kaolin concentration
    Frequency-absorption coefficient correlation curves of HDPE, PP, and PVC after adsorption of MO solutions for 24 h as well as those before and after oscillation of MO solutions for 24 h
    Terahertz spectra of original (0 h), final (24 h) MO solution and MO solution after adsorption by PVC for different time. (a) Time-domain spectra with corresponding frequency spectra shown in inset; (b) frequency-absorption coefficient spectra with time-absorption coefficient curves at 0.6 THz and 1.2 THz shown in inset
    Terahertz spectra of MO solutions after adsorption of 3 h by PVC with particle sizes of less than 74 μm and 2.6 μm. (a) Time-domain spectra; (b) frequency-absorption coefficient spectra
    • Table 1. Equation calculation coefficients of absorption coefficient of different plastic-filler blends

      View table

      Table 1. Equation calculation coefficients of absorption coefficient of different plastic-filler blends

      Plastic-fillerB0B1B2
      HDPE-CaCO32.33448±0.8260012.25343±7.76956105.88678±14.91574
      PP-CaCO35.06831±1.48516-4.07601±13.96981127.17168±26.81878
      PVC-CaCO326.62112±1.842475.43897±17.33076119.50486±33.27101
      HDPE-Kaolin2.93417±0.584503.05178±5.4980053.55443±10.55487
      PP-Kaolin4.66624±1.06257-11.96193±9.9948584.20270±19.18778
      PVC-Kaolin25.34433±0.370208.25077±3.4821914.18593±6.68500
    • Table 2. Equation calculation coefficients of refractive indices of different plastic-filler blends

      View table

      Table 2. Equation calculation coefficients of refractive indices of different plastic-filler blends

      Plastic-fillerC0C1C2
      HDPE-CaCO31.41548±0.007180.45779±0.067580.31674±0.12973
      PP-CaCO31.41191±0.003350.33582±0.031560.22995±0.06058
      PVC-CaCO31.49298±0.015990.62482±0.150420.03751±0.28878
      HDPE-Kaolin1.41333±0.010840.39423±0.101990.03782±0.1958
      PP-Kaolin1.41838±0.008840.13914±0.083110.14634±0.15955
      PVC-Kaolin1.49792±0.010790.17731±0.101530.38627±0.19490
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    Tong Zhang, Haochong Huang, Zili Zhang, Hua Gao, Lu Gao, Zhiyuan Zheng. Detection of Plastics Based on Terahertz Time-Domain Spectroscopy[J]. Chinese Journal of Lasers, 2022, 49(13): 1311001

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    Paper Information

    Category: spectroscopy

    Received: Sep. 14, 2021

    Accepted: Nov. 18, 2021

    Published Online: Jun. 13, 2022

    The Author Email: Huang Haochong (hchhuang@cugb.edu.cn), Zheng Zhiyuan (zhyzheng@cugb.edu.cn)

    DOI:10.3788/CJL202249.1311001

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