Chinese Optics Letters, Volume. 18, Issue 9, 091403(2020)

Broadband photochromic effect and photoluminescence modulation in rare-earth-doped (Pb,La)(Zr,Ti)O3 ceramics

Long Xu1, Ruiqi Zhu1, and Caixia Xu2、*
Author Affiliations
  • 1School of Physical Science and Technology, Southwest University, Chongqing 400715, China
  • 2School of Primary Education, Chongqing Normal University, Chongqing 400700, China
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    Figures & Tables(4)
    (a) X-ray diffraction spectrum of undoped PLZT, 1 mol% Er3+-doped, and 1 mol% Nd3+-doped PLZT ceramics; (b) the surface appearance photograph of undoped PLZT ceramics taken by an AFM; (c) the room temperature ground state absorption spectra; and (d) the transmittance spectra of undoped PLZT, 1 mol%–3 mol% Er3+-doped, and 1 mol% Nd3+-doped PLZT samples (the inset is the photograph of the undoped, Er3+-doped, and Nd3+-doped PLZT samples).
    (a) Schematic illustration of the experimental setup of the photochromic effect; (b) the dynamic change of the transmittance of light in the darkening, self-bleaching, and infrared bleaching processes; (c) the trapping and detrapping process of electrons in TDT; (d) extinction coefficient and (e) refractive index change after UV light exposure; (f) the two-dimensional pseudo color distribution of the transmittance of light at different wavelengths in undoped PLZT ceramics (the inserted green line is the absorption spectrum of undoped PLZT ceramics).
    Two-dimensional pseudo color distribution of the transmittance of light at different wavelengths in (a) the 1 mol% Nd3+ ion-doped PLZT ceramics and (b)–(d) the 1 mol%–3 mol% Er3+ ion-doped PLZT ceramics.
    (a) Upconversion spectra of 1 mol% Er3+-doped PLZT ceramics excited by the laser at 980 nm after being irradiated by UV light at 365 nm with a power of 0 mW, 0.1 mW, and 0.12 mW for 1 min each (the inset is the schematic setup to measure the photoluminescence spectrum); (b) photoluminescence at 1550 nm of 1 mol% Er3+-doped PLZT excited by the laser at 980 nm after being irradiated by UV light at 365 nm with a power of 0 mW, 0.1 mW, and 0.12 mW for 1 min each.
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    Long Xu, Ruiqi Zhu, Caixia Xu, "Broadband photochromic effect and photoluminescence modulation in rare-earth-doped (Pb,La)(Zr,Ti)O3 ceramics," Chin. Opt. Lett. 18, 091403 (2020)

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    Paper Information

    Category: Lasers and Laser Optics

    Received: Mar. 15, 2020

    Accepted: May. 27, 2020

    Published Online: Aug. 3, 2020

    The Author Email: Caixia Xu (noendness@126.com)

    DOI:10.3788/COL202018.091403

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