Indium-doped perovskite-related cesium copper halide scintillator films for high-performance X-ray imaging

Rui Liu; Zhiyong Liu; Chengxu Lin; Guangda Niu; Xuning Zhang; Bo Sun; Tielin Shi; Guanglan Liao

doi:10.1364/PRJ.501477

Photonics Research, Volume. 12, Issue 2, 369(2024)

Indium-doped perovskite-related cesium copper halide scintillator films for high-performance X-ray imaging

Rui Liu¹, Zhiyong Liu^1、*, Chengxu Lin¹, Guangda Niu², Xuning Zhang¹, Bo Sun³, Tielin Shi¹, and Guanglan Liao^1,4

¹State Key Laboratory of Digital Manufacturing Equipment and Technology, Huazhong University of Science and Technology, Wuhan 430074, China

²Wuhan National Laboratory for Optoelectronics and School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China

³School of Aerospace Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

⁴e-mail: guanglan.liao@hust.edu.cn

show less

References(59)

[1] H. Tsai, F. Liu, S. Shrestha. A sensitive and robust thin-film X-ray detector using 2D layered perovskite diodes. Sci. Adv., 6, eaay815(2020).

[2] V. B. Mykhaylyk, H. Kraus, M. Saliba. Bright and fast scintillation of organolead perovskite MAPbBr₃ at low temperatures. Mater. Horiz., 6, 1740-1747(2019).

[3] M. Zhang, X. Wang, B. Yang. Metal halide scintillators with fast and self-absorption-free defect-bound excitonic radioluminescence for dynamic X-ray imaging. Adv. Funct. Mater., 31, 2009973(2020).

[4] S. Deumel, A. van Breemen, G. Gelinck. High-sensitivity high-resolution X-ray imaging with soft-sintered metal halide perovskites. Nat. Electron., 4, 681-688(2021).

[5] J. Zhao, L. Zhao, Y. Deng. Perovskite-filled membranes for flexible and large-area direct-conversion X-ray detector arrays. Nat. Photonics, 14, 612-617(2020).

[6] M. J. Weber. Inorganic scintillators: today and tomorrow. J. Lumin., 100, 35-45(2002).

[7] P. Lecoq. Development of new scintillators for medical applications. Nucl. Instrum. Methods Phys. Res. A, 809, 130-139(2016).

[8] L. Borgese, F. Bilo, R. Dalipi. Total reflection X-ray fluorescence as a tool for food screening. Spectrochim. Acta B, 113, 1-15(2015).

[9] F. Maddalena, L. Tjahjana, A. Xie. Inorganic, organic, and perovskite halides with nanotechnology for high-light yield X- and γ-ray scintillators. Crystals, 9, 88(2019).

[10] K. Naresh, K. A. Khan, R. Umer. The use of X-ray computed tomography for design and process modeling of aerospace composites: a review. Mater. Des., 190, 108553(2020).

[11] J. A. Rowlands. Material change for X-ray detectors. Nature, 550, 47-48(2017).

[12] H. Wei, J. Huang. Halide lead perovskites for ionizing radiation detection. Nat. Commun., 10, 1066(2019).

[13] T. Chen, X. Li, Y. Wang. Centimeter-sized Cs₃Cu₂I₅ single crystals grown by oleic acid assisted inverse temperature crystallization strategy and their films for high-quality X-ray imaging. J. Energy Chem., 79, 382-389(2023).

[14] J. H. Heo, D. H. Shin, J. K. Park. High-performance next-generation perovskite nanocrystal scintillator for nondestructive X-ray imaging. Adv. Mater., 30, 1801743(2018).

[15] W. Mengesha, T. D. Taulbee, B. D. Rooney. Light yield nonproportionality of CsI (Tl), CsI (Na), and YAP. IEEE Trans. Nucl. Sci., 45, 456-461(1998).

[16] I. Mouhti, A. Elanique, M. Y. Messous. Characterization of CsI (Tl) and LYSO (Ce) scintillator detectors by measurements and Monte Carlo simulations. Appl. Radiat. Isot., 154, 108878(2019).

[17] A. Kryemadhi, L. Barner, A. Grove. A LYSO crystal array readout by silicon photomultipliers as compact detector for space applications. Nucl. Instrum. Methods Phys. Res. A, 912, 93-96(2018).

[18] S. Weber, D. Christ, M. Kurzeja. Comparison of LuYAP, LSO, and BGO as scintillators for high resolution PET detectors. IEEE Trans. Nucl. Sci., 50, 1370-1372(2003).

[19] E. V. D. van Loef, P. Dorenbos, C. W. E. van Eijk. High-energy-resolution scintillator: Ce³⁺ activated LaBr₃. Appl. Phys. Lett., 79, 1573-1575(2001).

[20] C. W. E. van Eijk. Inorganic scintillators in medical imaging. Phys. Med. Biol., 47, R85-R106(2002).

[21] O. Moseley, T. Doherty, R. Parmee. Halide perovskites scintillators: unique promise and current limitations. J. Mater. Chem. C, 9, 11588-11604(2021).

[22] A. Y. Martin Nikl. Recent R&D trends in inorganic single-crystal scintillator materials for radiation detection. Adv. Opt. Mater., 3, 463-481(2015).

[23] Y. Zhang, R. Sun, X. Ou. Metal halide perovskite nanosheet for X-ray high-resolution scintillation imaging screens. ACS Nano, 13, 2520-2525(2019).

[24] Y. Cao, J. Wei, C. Li. Optimal operating control strategy for biogas generation under electricity spot market. J. Eng., 2019, 5183-5186(2019).

[25] Y. Li, P. Vashishtha, Z. Zhou. Room temperature synthesis of stable, printable Cs₃Cu₂X₅ (X = I, Br/I, Br, Br/Cl, Cl) colloidal nanocrystals with near-unity quantum yield green emitters (X = Cl). Chem. Mater., 32, 5515-5524(2020).

[26] Q. Chen, J. Wu, X. Ou. All-inorganic perovskite nanocrystal scintillators. Nature, 561, 88-93(2018).

[27] B. Yang, L. Yin, G. Niu. Lead-free halide Rb₂CuBr₃ as sensitive X-ray scintillator. Adv. Mater., 31, 1904711(2019).

[28] S. Seth, T. Ahmed, A. De. Tackling the defects, stability, and photoluminescence of CsPbX₃ perovskite nanocrystals. ACS Energy Lett., 4, 1610-1618(2019).

[29] Q. Zhou, J. Ren, J. Xiao. Highly efficient copper halide scintillators for high-performance and dynamic X-ray imaging. Nanoscale, 13, 19894-19902(2021).

[30] W. Gao, G. Niu, L. Yin. One-dimensional all-inorganic K₂CuBr₃ with violet emission as efficient X-ray scintillators. ACS Appl. Electron. Mater., 2, 2242-2249(2020).

[31] Y. Zhou, X. Wang, T. He. Large-area perovskite-related copper halide film for high-resolution flexible X-ray imaging scintillation screens. ACS Energy Lett., 7, 844-846(2022).

[32] T. Jiang, W. Ma, H. Zhang. Highly efficient and tunable emission of lead-free manganese halides toward white light-emitting diode and X-ray scintillation applications. Adv. Funct. Mater., 31, 2009973(2021).

[33] T. Jun, T. Handa, K. Sim. One-step solution synthesis of white-light-emitting films via dimensionality control of the Cs-Cu-I system. Appl. Mater., 7, 111113(2019).

[34] P. Cheng, L. Sun, L. Feng. Colloidal synthesis and optical properties of all-inorganic low-dimensional cesium copper halide nanocrystals. Angew. Chem. Int. Ed., 58, 16087-16091(2019).

[35] Y. Li, Z. Shi, W. Liang. Highly stable and spectrum-selective ultraviolet photodetectors based on lead-free copper-based perovskites. Mater. Horiz., 7, 530-540(2020).

[36] W. Liang, L. Wang, Y. Li. Stable and ultraviolet-enhanced broadband photodetectors based on Si nanowire arrays-Cs₃Cu₂I₅ nanocrystals hybrid structures. Mater. Today Phys., 18, 100398(2021).

[37] S. Cheng, A. Beitlerova, R. Kucerkova. Zero-dimensional Cs₃Cu₂I₅ perovskite single crystal as sensitive X-ray and γ-ray scintillator. Phys. Status Solidi-RRL, 14, 2000374(2020).

[38] N. Li, Z. Xu, Y. Xiao. Flexible, high scintillation yield Cs₃Cu₂I₅ film made of ball-milled powder for high spatial resolution X-ray imaging. Adv. Opt. Mater., 10, 2102232(2022).

[39] Z. Guo, J. Li, R. Pan. All-inorganic copper(I)-based ternary metal halides: promising materials toward optoelectronics. Nanoscale, 12, 15560-15576(2020).

[40] D. Yuan. Air-stable bulk halide single-crystal scintillator Cs₃Cu₂I₅ by melt growth: intrinsic and Tl doped with high light yield. ACS Appl. Mater. Interfaces, 12, 38333-38340(2020).

[41] X. Li, J. Chen, D. Yang. Mn²⁺ induced significant improvement and robust stability of radioluminescence in Cs₃Cu₂I₅ for high-performance nuclear battery. Nat. Commun., 12, 3879(2021).

[42] K. Qu, Y. Lu, P. Ran. Zn (II)-doped cesium copper halide nanocrystals with high quantum yield and colloidal stability for high-resolution X-ray imaging. Adv. Opt. Mater., 11, 2202883(2023).

[43] Q. Wang, Q. Zhou, M. Nikl. Highly resolved X-ray imaging enabled by In(I) doped perovskite-like Cs₃Cu₂I₅ single crystal scintillator. Adv. Opt. Mater., 10, 2200304(2022).

[44] X. Hu, P. Yan, P. Ran. In situ fabrication of Cs₃Cu₂I₅: Tl nanocrystal films for high-resolution and ultrastable X-ray imaging. J. Phys. Chem. Lett., 13, 2862-2870(2022).

[45] T. Jun, K. Sim, S. Iimura. Lead-free highly efficient blue-emitting Cs₃Cu₂I₅ with 0D electronic structure. Adv. Mater., 30, 1804547(2018).

[46] H. Peng, Y. Tian, Z. Zhang. Bulk assembly of zero-dimensional organic copper bromide hybrid with bright self-trapped exciton emission and high antiwater stability. J. Phys. Chem. C, 125, 20014-20021(2021).

[47] T. Hu, M. D. Smith, E. R. Dohner. Mechanism for broadband white-light emission from two-dimensional (110) hybrid perovskites. J. Phys. Chem. Lett., 7, 2258-2263(2016).

[48] T. He, Y. Zhou, X. Wang. High-performance copper-doped perovskite-related silver halide X-ray imaging scintillator. ACS Energy Lett., 7, 2753-2760(2022).

[49] F. Zhang, Y. Zhou, Z. Chen. Thermally activated delayed fluorescence zirconium-based perovskites for large-area and ultraflexible X-ray scintillator screens. Adv. Mater., 34, 2204801(2022).

[50] Z. Li, F. Zhou, H. Yao. Halide perovskites for high-performance X-ray detector. Mater. Today, 48, 155-175(2021).

[51] Y. Haruta, M. Kawakami, Y. Nakano. Scalable fabrication of metal halide perovskites for direct X-ray flat-panel detectors: a perspective. Chem. Mater., 34, 5323-5333(2022).

[52] H. Wu, Y. Ge, G. Niu. Metal halide perovskites for X-ray detection and imaging. Matter, 4, 144-163(2021).

[53] R. Duan, Z. Chen, D. Xiang. Large-area flexible scintillator screen based on copper-based halides for sensitive and stable X-ray imaging. J. Lumin., 253, 119482(2023).

[54] X. Zhao, T. Jin, W. Gao. Embedding Cs₃Cu₂I₅ scintillators into anodic aluminum oxide matrix for high-resolution X-ray imaging. Adv. Opt. Mater., 9, 2101194(2021).

[55] Q. Xu, S. Zhou, J. Huang. Ultra-flexible and highly sensitive scintillation screen based on perovskite quantum dots for non-flat objects X-ray imaging. Mater. Today Phys., 18, 100390(2021).

[56] K. Han, K. Sakhatskyi, J. Jin. Seed-crystal-induced cold sintering toward metal halide transparent ceramic scintillators. Adv. Mater., 34, 2110420(2022).

[57] M. Zhang, J. Zhu, B. Yang. Oriented-structured CsCu₂I₃ film by close-space sublimation and nanoscale seed screening for high-resolution X-ray imaging. Nano Lett., 21, 1392-1399(2021).

[58] W. Zhu, W. Ma, Y. Su. Low-dose real-time X-ray imaging with nontoxic double perovskite scintillators. Light Sci. Appl., 9, 112(2020).

[59] N. Zhang, R. Zhang, X. Xu. X-ray-activated long afterglow double-perovskite scintillator for detection and extension imaging. Adv. Opt. Mater., 11, 2300187(2023).

Tools

Get Citation

Copy Citation Text

Rui Liu, Zhiyong Liu, Chengxu Lin, Guangda Niu, Xuning Zhang, Bo Sun, Tielin Shi, Guanglan Liao, "Indium-doped perovskite-related cesium copper halide scintillator films for high-performance X-ray imaging," Photonics Res. 12, 369 (2024)

Download Citation

EndNote(RIS)BibTex Plain Text

Set citation alerts for article

Save article for my favorites

Paper Information

Category: Optical and Photonic Materials

Received: Aug. 29, 2023

Accepted: Nov. 14, 2023

Published Online: Feb. 2, 2024

The Author Email: Zhiyong Liu (zhiyong_liu@hust.edu.cn)

DOI:10.1364/PRJ.501477

Topics

laser devices and laser physics

Lasers and Laser Optics

Laser physics

laser manufacturing

Instrumentation, Measurement and Metrology