Spectroscopy and Spectral Analysis, Volume. 41, Issue 9, 2800(2021)

Preparation and Properties of Micro-Cavity Silver Modified Fiber SERS Probe

Xing-hu FU*, Zhen-xing WANG, Shuang-yu MA, Fei ZHAO, Xin LU, Guang-wei FU, Wa JIN, and Wei-hong BI
Author Affiliations
  • School of Information Science and Engineering, The Key Laboratory for Special Fiber and Fiber Sensor of Hebei Province, Yanshan University, Qinhuangdao 066004, China
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    Figures & Tables(10)
    Experimental device for SERS spectrum detection of micro-cavity fiber probe
    The change of micro-cavity length with etching time(a): Microscope image; (b): Quantitative result figure
    Experimental results of the mixed solution to find the best enhancement effect(a): Raman spectra of nano silver sol and R6G solutions mixed with different mix orders and ratios;(b): Raman intensity of different mixed solutions at Raman shift of 1 510 cm-1
    Micro-cavity fiber SERS experiment results(a): SERS results of optical fiber micro-cavity with different etching time;(b): Raman intensity of fiber micro-cavity with different etching time at Raman shift of 1 510 cm-1
    The active fiber tip modified with silver nanoparticles by magnetron sputtering method modified with silver nanoparticles by magnetron sputtering method
    Probe performance results(a): Sensitivity test; (b): Linear relationship between logI and logC centered at 1 362 cm-1 in Raman spectrum
    Experimental results(a): Reproducibility test of fiber SERS probe; (b): Raman spectra of fiber probe and bare fiber
    • Table 1. Linear relationships between R6G concentrations and Raman intensities at characteristic peaks of R6G

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      Table 1. Linear relationships between R6G concentrations and Raman intensities at characteristic peaks of R6G

      Peak/cm-1Linear functionR2
      1 311y=0.359x+5.3560.989
      1 362y=0.290x+5.2640.980
      1 510y=0.326x+5.3980.983
      1 651y=0.358x+4.8570.987
    • Table 2. RSD values at different major peaks of R6G

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      Table 2. RSD values at different major peaks of R6G

      Raman peaks/cm-1RSD values/%
      1 1848.427
      1 3118.048
      1 3626.453
      1 5107.525
      1 5757.364
      1 6516.753
    • Table 3. AEFs of the Raman band centered at 1 184, 1 311, 1 362, 1 575 and 1 651 cm-1

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      Table 3. AEFs of the Raman band centered at 1 184, 1 311, 1 362, 1 575 and 1 651 cm-1

      Peak/cm-11 1841 3111 3621 5751 651
      ISERS/(a.u.)2.24×1031.76×1034.63×1032.93×1037.54×103
      IR/(a.u.)0.85×1020.85×1021.90×1020.18×1020.55×102
      cSERS/(mol·L-1)1.00×10-61.00×10-61.00×10-61.00×10-61.00×10-6
      cR/(mol·L-1)1.00×10-11.00×10-11.00×10-11.00×10-11.00×10-1
      AEF2.64×1062.09×1062.44×1061.60×1061.36×106
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    Xing-hu FU, Zhen-xing WANG, Shuang-yu MA, Fei ZHAO, Xin LU, Guang-wei FU, Wa JIN, Wei-hong BI. Preparation and Properties of Micro-Cavity Silver Modified Fiber SERS Probe[J]. Spectroscopy and Spectral Analysis, 2021, 41(9): 2800

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    Paper Information

    Category: Research Articles

    Received: Jun. 28, 2020

    Accepted: --

    Published Online: Oct. 29, 2021

    The Author Email: FU Xing-hu (fuxinghu@ysu.edu.cn)

    DOI:10.3964/j.issn.1000-0593(2021)09-2800-07

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