Highly luminescent and stable lead-free cesium copper halide perovskite powders for UV-pumped phosphor-converted light-emitting diodes

Lingling Xie; Bingkun Chen; Fa Zhang; Ziheng Zhao; Xinxin Wang; Lijie Shi; Yue Liu; Lingling Huang; Ruibin Liu; Bingsuo Zou; Yongtian Wang

doi:10.1364/PRJ.387707

Photonics Research, Volume. 8, Issue 6, 768(2020)

Highly luminescent and stable lead-free cesium copper halide perovskite powders for UV-pumped phosphor-converted light-emitting diodes Spotlight on Optics

Lingling Xie^1、†, Bingkun Chen^2、†,*, Fa Zhang², Ziheng Zhao², Xinxin Wang¹, Lijie Shi¹, Yue Liu², Lingling Huang², Ruibin Liu^1,4, Bingsuo Zou¹, and Yongtian Wang^2,3

Author Affiliations

¹Beijing Key Laboratory of Nanophotonics and Ultrafine Optoelectronic Systems, School of Physics, Beijing Institute of Technology, Beijing 100081, China

²Beijing Engineering Research Center of Mixed Reality and Advanced Display, School of Optics and Photonics, Beijing Institute of Technology, Beijing 100081, China

³AICFVE of Beijing Film Academy, Beijing 100088, China

⁴e-mail: liusir@bit.edu.cn

show less

References(68)

[1] Q. A. Akkerman, G. Raino, M. V. Kovalenko, L. Manna. Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals. Nat. Mater., 17, 394-405(2018).

[2] S. Chang, Z. L. Bai, H. Z. Zhong. In situ fabricated perovskite nanocrystals: a revolution in optical materials. Adv. Opt. Mater., 6, 1800380(2018).

[3] M. V. Kovalenko, L. Protesescu, M. I. Bodnarchuk. Properties and potential optoelectronic applications of lead halide perovskite nanocrystals. Science, 358, 745-750(2017).

[4] N. J. Jeon, J. H. Noh, Y. C. Kim, W. S. Yang, S. Ryu, S. I. Seok. Solvent engineering for high-performance inorganic-organic hybrid perovskite solar cells. Nat. Mater., 13, 897-903(2014).

[5] C. X. Ran, J. Xi, W. Y. Gao, F. Yuan, T. Lei, B. Jiao, X. Hou, Z. X. Wu. Bilateral interface engineering toward efficient 2D-3D bulk heterojunction tin halide lead-free perovskite solar cells. ACS Energy Lett., 3, 713-721(2018).

[6] E. M. Sanehira, A. R. Marshall, J. A. Christians, S. P. Harvey, P. N. Ciesielski, L. M. Wheeler, P. Schulz, L. Y. Lin, M. C. Beard, J. M. Luther. Enhanced mobility CsPbI₃ quantum dot arrays for record-efficiency, high-voltage photovoltaic cells. Sci. Adv., 3, eaao4204(2017).

[7] J. B. You, L. Meng, T.-B. Song, T.-F. Guo, Y. M. Yang, W.-H. Chang, Z. R. Hong, H. J. Chen, H. P. Zhou, Q. Chen, Y. S. Liu, N. D. Marco, Y. Yang. Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers. Nat. Nanotechnol., 11, 75-81(2016).

[8] Y. Cao, N. N. Wang, H. Tian, J. S. Guo, Y. Q. Wei, H. Chen, Y. F. Miao, W. Zou, K. Pan, Y. R. He, H. Cao, Y. Ke, M. M. Xu, Y. Wang, M. Yang, K. Du, Z. W. Fu, D. C. Kong, D. X. Dai, Y. Z. Jin, G. Q. Li, H. Li, Q. M. Peng, J. P. Wang, W. Huang. Perovskite light-emitting diodes based on spontaneously formed submicrometre-scale structures. Nature, 562, 249-253(2018).

[9] T. Chiba, S. Ohisa, Y. Hayashi, H. Ebe, K. Hoshi, J. Sato, S. Sato, Y.-J. Pu, S. Ohisa, J. Kido. Anion-exchange red perovskite quantum dots with ammonium iodine salts for highly efficient light-emitting devices. Nat. Photonics, 12, 681-687(2018).

[10] K. B. Lin, J. Xing, L. N. Quan, F. P. G. de Arquer, X. W. Gong, J. X. Lu, L. Q. Xie, W. J. Zhao, D. Zhang, C. Z. Yan, W. Q. Li, X. Y. Liu, Y. Lu, J. Kirman, E. H. Sargent, Q. H. Xiong, Z. H. Wei. Perovskite light-emitting diodes with external quantum efficiency exceeding 20 percent. Nature, 562, 245-248(2018).

[11] M. Lu, Y. Zhang, S. Wang, J. Guo, W. W. Yu, A. L. Rogach. Metal halide perovskite light-emitting devices: promising technology for next-generation displays. Adv. Funct. Mater., 29, 1902008(2019).

[12] D. B. Han, M. Imran, M. J. Zhang, S. Chang, X. G. Wu, X. Zhang, J. L. Tang, M. S. Wang, S. Ali, X. G. Li, G. Yu, J. B. Han, B. S. Zou, H. Z. Zhong. Efficient light-emitting diodes based on in situ fabricated FaPbBr₃ nanocrystals: the enhancing role of the ligand-assisted reprecipitation process. ACS Nano, 12, 8808-8816(2018).

[13] Y. Liu, J. Y. Cui, K. Du, H. Tian, Z. F. He, Q. H. Zhou, Z. L. Yang, Y. Z. Deng, D. Chen, X. B. Zuo, Y. Ren, L. Wang, H. M. Zhu, B. D. Zhao, D. W. Di, J. P. Wang, R. H. Friend, Y. Z. Jin. Efficient blue light-emitting diodes based on quantum-confined bromide perovskite nanostructures. Nat. Photonics, 13, 760-767(2019).

[14] Z. C. Li, Z. M. Chen, Y. C. Yang, Q. F. Xue, H.-L. Yip, Y. Cao. Modulation of recombination zone position for quasi-two-dimensional blue perovskite light-emitting diodes with efficiency exceeding 5%. Nat. Commun., 10, 1027(2019).

[15] Y. J. Fang, Q. F. Dong, Y. C. Shao, Y. B. Yuan, J. S. Huang. Highly narrowband perovskite single-crystal photodetectors enabled by surface-charge recombination. Nat. Photonics, 9, 679-686(2015).

[16] M. I. Saidaminov, V. Adinolfi, R. Comin, A. L. Abdelhady, W. Peng, I. Dursun, M. Yuan, S. Hoogland, E. H. Sargent, O. M. Bakr. Planar-integrated single-crystalline perovskite photodetectors. Nat. Commun., 6, 8724(2015).

[17] L. Wang, L. H. Meng, L. Chen, S. Huang, X. G. Wu, G. Dai, L. G. Deng, J. B. Han, B. S. Zou, C. F. Zhang, H. Z. Zhong. Ultralow-threshold and color-tunable continuous-wave lasing at room-temperature from in situ fabricated perovskite quantum dots. J. Phys. Chem. Lett., 10, 3248-3253(2019).

[18] Y. F. Jia, R. A. Kerner, A. J. Grede, B. P. Rand, N. C. Giebink. Continuous-wave lasing in an organic-inorganic lead halide perovskite semiconductor. Nat. Photonics, 11, 784-788(2017).

[19] Q. Wei, X. J. Li, C. Liang, Z. P. Zhang, J. Guo, G. Hong, G. C. Xing, W. Huang. Recent progress in metal halide perovskite micro- and nanolasers. Adv. Opt. Mater., 7, 1900080(2019).

[20] B.-W. Park, S. I. Seok. Intrinsic instability of inorganic-organic hybrid halide perovskite materials. Adv. Mater., 31, 1805337(2019).

[21] A. Babayigit, A. Ethirajan, M. Muller, B. Conings. Toxicity of organometal halide perovskite solar cells. Nat. Mater., 15, 247-251(2016).

[22] A. F. Wang, Y. Y. Guo, F. Muhammad, Z. T. Deng. Controlled synthesis of lead-free cesium tin halide perovskite cubic nanocages with high stability. Chem. Mater., 29, 6493-6501(2017).

[23] D. H. Fabini, G. Laurita, J. S. Bechtel, C. C. Stoumpos, H. A. Evans, A. G. Kontos, Y. S. Raptis, P. Falaras, A. V. D. Ven, M. G. Kanatzidis, R. Seshadri. Dynamic stereochemical activity of the Sn²⁺ lone pair in perovskite CsSnBr₃. J. Am. Chem. Soc., 138, 11820-11832(2016).

[24] B. M. Benin, D. N. Dirin, V. Morad, M. Wçrle, S. Yakunin, G. Rainò, O. Nazarenko, M. Fischer, I. Infante, M. V. Kovalenko. Highly emissive self-trapped excitons in fully inorganic zero dimensional tin halides. Angew. Chem., 130, 11499-11503(2018).

[25] X. Zhang, C. Wang, Y. Zhang, X. Zhang, S. Wang, M. Lu, H. Cui, S. V. Kershaw, W. W. Yu, A. L. Rogach. Bright orange electroluminescence from lead-free two-dimensional perovskites. ACS Energy Lett., 4, 242-248(2019).

[26] J.-T. Lin, C.-C. Liao, C.-S. Hsu, D.-G. Chen, H.-M. Chen, M.-K. Tsai, P.-T. Chou, C.-W. Chiu. Harnessing dielectric confinement on tin perovskites to achieve emission quantum yield up to 21%. J. Am. Chem. Soc., 141, 10324-10330(2019).

[27] M. Y. Leng, Y. Yang, K. Zeng, Z. W. Chen, Z. F. Tan, S. R. Li, J. H. Li, B. Xu, D. B. Li, M. P. Hautzinger, Y. P. Fu, T. Y. Zhai, L. Xu, G. D. Niu, S. Jin, J. Tang. All-inorganic bismuth-based perovskite quantum dots with bright blue photoluminescence and excellent stability. Adv. Funct. Mater., 28, 1704446(2017).

[28] B. Yang, J. S. Chen, F. Hong, X. Mao, K. B. Zheng, S. Q. Yang, Y. J. Li, T. Pullerits, W. Q. Deng, K. L. Han. Lead-free, air-stable all-inorganic cesium bismuth halide perovskite nanocrystals. Angew. Chem. (Int. Ed.), 56, 12471-12475(2017).

[29] M. Leng, Y. Yang, Z. Chen, W. Gao, J. Zhang, G. Niu, D. Li, H. Song, J. Zhang, S. Jin, J. Tang. Surface passivation of bismuth-based perovskite variant quantum dots to achieve efficient blue emission. Nano Lett., 18, 6076-6083(2018).

[30] Y. Bekenstein, J. C. Dahl, J. M. Huang, W. T. Osowiecki, J. K. Swabeck, E. M. Chan, P. D. Yang, A. P. Alivisatos. The making and breaking of lead-free double perovskite nanocrystals of cesium silver-bismuth halide compositions. Nano Lett., 18, 3502-3508(2018).

[31] Q. Li, Y. G. Wang, W. C. Pan, W. G. Yang, B. Zou, J. Tang, Z. W. Quan. High-pressure band-gap engineering in lead-free Cs₂AgBiBr₆ double perovskite. Angew. Chem. (Int. Ed.), 56, 15969-15973(2017).

[32] L. Zhou, J. F. Liao, Z. G. Huang, J. H. Wei, X. D. Wang, W. G. Li, H. Y. Chen, D. B. Kuang, C. Y. Su. A highly red-emissive lead-free indium-based perovskite single crystal for sensitive water detection. Angew. Chem. (Int. Ed.), 58, 5277-5281(2019).

[33] L. Zhou, J. F. Liao, Z. G. Huang, J. H. Wei, X. D. Wang, H. Y. Chen, D. B. Kuang. Intrinsic self-trapped emission in 0D lead-free (C₄H₁₄N₂)₂In₂Br₁₀ single crystal. Angew. Chem. (Int. Ed.), 58, 2-8(2019).

[34] F. Umar, J. Zhang, Z. X. Jin, I. Muhammad, X. K. Yang, H. Deng, K. Jahangeer, Q. S. Hu, H. S. Song, J. Tang. Dimensionality controlling of Cs₃Sb₂I₉ for efficient all-inorganic planar thin film solar cells by HCl-assisted solution method. Adv. Opt. Mater., 7, 1801368(2019).

[35] J. Zhang, Y. Yang, H. Deng, U. Farooq, X. Yang, J. Khan, J. Tang, H. Song. High quantum yield blue emission from lead-free inorganic antimony halide perovskite colloidal quantum dots. ACS Nano, 11, 9294-9302(2017).

[36] X. T. Wu, W. D. Song, Q. Li, X. X. Zhao, D. S. He, Z. W. Quan. Synthesis of lead-free CsGeI₃ perovskite colloidal nanocrystals and electron beam-induced transformations. Chem. Asian J., 13, 1654-1659(2018).

[37] P. F. Cheng, T. Wu, J. W. Zhang, Y. J. Li, J. X. Liu, L. Jiang, X. Mao, R. F. Lu, W. Q. Deng, K. L. Han. (C₆H₅C₂H₄NH₃)₂GeI₄: a layered two-dimensional perovskite with potential for photovoltaic applications. J. Phys. Chem. Lett., 8, 4402-4406(2017).

[38] D. Cortecchia, H. A. Dewi, J. Yin, A. Bruno, S. Chen, T. Baikie, P. P. Boix, M. Grätzel, S. Mhaisalkar, C. Soci, N. Mathews. Lead-free Ma₂CuCl_xBr_4-x hybrid perovskites. Inorg. Chem., 55, 1044-1052(2016).

[39] P. F. Cheng, L. Sun, L. Feng, S. Q. Yang, Y. Yang, D. Y. Zheng, Y. Zhao, Y. B. Sang, R. L. Zhang, D. H. Wei, W. Q. Deng, K. L. Han. Colloidal synthesis and optical properties of all-inorganic low-dimensional cesium copper halide nanocrystals. Angew. Chem. (Int. Ed.), 131, 16233-16237(2019).

[40] T. Jun, K. Sim, S. Iimura, M. Sasase, H. Kamioka, J. Kim, H. Hosono. Lead-free highly efficient blue-emitting Cs₃Cu₂I₅ with 0D electronic structure. Adv. Mater., 30, 1804547(2018).

[41] T. Li, X. M. Mo, C. Y. Peng, Q. C. Lu, C. J. Qi, X. M. Tao, Y. Ouyang, Y. L. Zhou. Distinct green electroluminescence from lead-free CsCuBr₂ halide micro-crosses. Chem. Commun., 55, 4554-4557(2019).

[42] R. Roccanova, A. Yangui, H. Nhalil, H. L. Shi, M. H. Du, B. Saparov. Near-unity photoluminescence quantum yield in blue-emitting Cs₃Cu₂Br_5-xI_x (0 ≤ x ≤ 5). ACS Appl. Electron. Mater., 1, 269-274(2019).

[43] E. P. Booker, J. T. Griffiths, L. Eyre, C. Ducati, N. C. Greenham, N. J. L. K. Davis. Synthesis, characterization, and morphological control of Cs₂CuCl₄ nanocrystals. J. Phys. Chem. C, 123, 16951-16956(2019).

[44] P. Yang, G. N. Liu, B. D. Liu, X. D. Liu, Y. B. Lou, J. X. Chen, Y. X. Zhao. All-inorganic Cs₂CuX₄ (X = Cl, Br, and Br/I) perovskite quantum dots with blue-green luminescence. Chem. Commun., 54, 11638-11641(2018).

[45] S. Thapa, G. C. Adhikari, H. Y. Zhu, A. Grigoriev, P. F. Zhu. Zn-alloyed all-inorganic halide perovskite-based white light-emitting diodes with superior color quality. Sci. Rep., 9, 1(2019).

[46] G. C. Adhikari, S. Thapa, H. Zhu, P. Zhu. Mg²⁺-alloyed all-inorganic halide perovskites for white light-emitting diodes by 3D-printing method. Adv. Opt. Mater., 7, 1900916(2019).

[47] Q. Hu, Z. Li, Z. Tan, H. Song, C. Ge, G. Niu, J. Han, J. Tang. Rare earth ion-doped CsPbBr₃ nanocrystals. Adv. Opt. Mater., 6, 1700864(2018).

[48] R. A. Sheldon. Green solvents for sustainable organic synthesis: state of the art. Green Chem., 7, 267-278(2005).

[49] F. Gomollón-Bel. Ten chemical innovations that will change our world: IUPAC identifies emerging technologies in chemistry with potential to make our planet more sustainable. Chem. Int., 41, 12-17(2019).

[50] D. Prochowicz, M. Saski, P. Yadav, M. Grätzel, J. Lewinski. Mechanoperovskites for photovoltaic applications: preparation, characterization, and device fabrication. Acc. Chem. Res., 52, 3233-3243(2019).

[51] Z. Y. Zhu, Q. Q. Yang, L. F. Gao, L. Zhang, A. Y. Shi, C. L. Sun, Q. Wang, H. L. Zhang. Solvent-free mechanosynthesis of composition-tunable cesium lead halide perovskite quantum dots. J. Phys. Chem. Lett., 8, 1610-1614(2017).

[52] L. Protesescu, S. Yakunin, O. Nazarenko, D. N. Dirin, M. V. Kovalenko. Low-cost synthesis of highly luminescent colloidal lead halide perovskite nanocrystals by wet ball milling. ACS Appl. Nano Mater., 1, 1300-1308(2018).

[53] D. Q. Chen, J. N. Li, X. Chen, J. K. Chen, J. S. Zhong. Grinding synthesis of APbX₃ (A = Ma, Fa, Cs; X = Cl, Br, I) perovskite nanocrystals. ACS Appl. Mater Interfaces, 11, 10059-10067(2019).

[54] J. J. Luo, X. M. Wang, S. R. Li, J. Liu, Y. M. Guo, G. D. Niu, L. Yao, Y. H. Fu, L. Gao, Q. S. Dong, C. Y. Zhao, M. Y. Leng, F. S. Ma, W. X. Liang, L. D. Wang, S. Y. Jin, J. B. Han, L. J. Zhang, J. Etheridge, J. B. Wang, Y. F. Yan, E. H. Sargent, J. Tang. Efficient and stable emission of warm-white light from lead-free halide double perovskites. Nature, 563, 541-545(2018).

[55] Z. Yuan, C. K. Zhou, Y. Tian, Y. Shu, J. Messier, J. C. Wang, L. J. van de Burgt, K. Kountouriotis, Y. Xin, E. Holt, K. Schanze, R. Clark, T. Siegrist, B. W. Ma. One-dimensional organic lead halide perovskites with efficient bluish white-light emission. Nat. Commun., 8, 14051(2017).

[56] S. Seth, A. Samanta. Photoluminescence of zero-dimensional perovskites and perovskite-related materials. J. Phys. Chem. Lett., 9, 176-183(2018).

[57] B. T. Diroll, G. Nedelcu, M. V. Kovalenko, R. D. Schaller. High-temperature photoluminescence of CsPbX₃ (X = Cl, Br, I) nanocrystals. Adv. Funct. Mater., 27, 1606750(2017).

[58] R. An, F. Y. Zhang, X. S. Zou, Y. Y. Tang, M. L. Liang, I. Oshchapovskyy, Y. C. Liu, A. Honarfar, Y. Q. Zhong, C. S. Li, H. F. Geng, J. S. Chen, S. E. Canton, T. N. Pullerits, K. B. Zheng. Photostability and photodegradation processes in colloidal CsPbI₃ perovskite quantum dots. ACS Appl. Mater Interfaces, 10, 39222-39227(2018).

[59] M. Y. Gao, C. Zhang, L. Y. Lian, J. W. Guo, Y. Xia, F. Pan, X. M. Su, J. B. Zhang, H. L. Li, D. L. Zhang. Controlled synthesis and photostability of blue emitting Cs₃Bi₂Br₉ perovskite nanocrystals by employing weak polar solvents at room temperature. J. Mater. Chem. C, 7, 3688-3695(2019).

[60] C. Zhou, H. Lin, Q. He, L. Xu, M. Worku, M. Chaaban, S. Lee, X. Shi, M.-H. Du, B. Ma. Low dimensional metal halide perovskites and hybrids. Mater. Sci. Eng. R, 137, 38-65(2019).

[61] G. D. Niu, W. Z. Li, F. Q. Meng, L. D. Wang, H. P. Dong, Y. Qiu. Study on the stability of CH₃NH₃PbI₃ films and the effect of post-modification by aluminum oxide in all-solid-state hybrid solar cells. J. Mater. Chem. A, 2, 705-710(2014).

[62] T. Zhang, M. I. Dar, G. Li, F. Xu, N. Guo, M. Grätzel, Y. Zhao. Bication lead iodide 2D perovskite component to stabilize inorganic α-CsPbI₃ perovskite phase for high-efficiency solar cells. Sci. Adv., 3, e1700841(2017).

[63] S. Hull, P. Berastegui. Crystal structures and ionic conductivities of ternary derivatives of the silver and copper monohalides–II: ordered phases within the (AgX)_x-(MX)_1-x and (CuX)_x-(MX)_1-x (M=K, Rb and Cs; X=Cl, Br and I) systems. J. Solid State Chem., 177, 3156-3173(2004).

[64] A. Verma, D. P. Jaihindh, Y.-P. Fu. Photocatalytic 4-nitrophenol degradation and oxygen evolution reaction in CuO/g-C₃N₄ composites prepared by deep eutectic solvent-assisted chlorine doping. Dalton Trans., 48, 8594-8610(2019).

[65] L. G. Liu, H. Z. Zhong, Z. L. Bai, T. Zhang, W. P. Fu, L. J. Shi, H. Y. Xie, L. G. Deng, B. S. Zou. Controllable transformation from rhombohedral Cu_1.8S nanocrystals to hexagonal CuS clusters: phase- and composition-dependent plasmonic properties. Chem. Mater., 25, 4828-4834(2013).

[66] N. F. Mott, A. M. Stoneham. The lifetime of electrons, holes and excitons before self-trapping. J. Phys. C, 10, 3391-3398(1977).

[67] Z. Luo, Q. Li, L. Zhang, T. L. Wu, C. Zou, Y. Liu, Z. Quan. 0D Cs₃Cu₂X₅ (X = I, Br, and Cl) nanocrystals: colloidal syntheses and optical properties. Small, 16, 1905226(2019).

[68] R. L. Zhang, X. Mao, Y. Yang, S. Q. Yang, W. Y. Zhao, T. Wumaier, D. H. Wei, W. Q. Deng, K. L. Han. Air-stable, lead-free zero-dimensional mixed bismuth-antimony perovskite single crystals with ultrabroadband emission. Angew. Chem., 131, 2751-2755(2019).

CLP Journals

[1] Ranran Fan, Shaofan Fang, Chengchuan Liang, Zhaoxing Liang, Haizhe Zhong, "Controllable one-step doping synthesis for the white-light emission of cesium copper iodide perovskites," Photonics Res. 9, 694 (2021)

[2] Qiang Xu, Juan Wang, Qindong Zhang, Xiao Ouyang, Maheng Ye, Weiting Xie, Xuewen Yan, Deyuan Li, Xiaoping Ouyang, Xiaobing Tang, Xiaodong Zhang, "Solution-processed lead-free bulk 0D Cs₃Cu₂I₅ single crystal for indirect gamma-ray spectroscopy application," Photonics Res. 9, 351 (2021)

[3] Shuangyi Zhao, Qionghua Mo, Wensi Cai, Huaxin Wang, Zhigang Zang, "Inorganic lead-free cesium copper chlorine nanocrystal for highly efficient and stable warm white light-emitting diodes," Photonics Res. 9, 187 (2021)

Tools

Get Citation

Copy Citation Text

Lingling Xie, Bingkun Chen, Fa Zhang, Ziheng Zhao, Xinxin Wang, Lijie Shi, Yue Liu, Lingling Huang, Ruibin Liu, Bingsuo Zou, Yongtian Wang, "Highly luminescent and stable lead-free cesium copper halide perovskite powders for UV-pumped phosphor-converted light-emitting diodes," Photonics Res. 8, 768 (2020)

Download Citation

EndNote(RIS)BibTex Plain Text

Set citation alerts for article

Save article for my favorites

Paper Information

Category: Optical and Photonic Materials

Received: Jan. 14, 2020

Accepted: Mar. 10, 2020

Published Online: Apr. 29, 2020

The Author Email: Bingkun Chen (chenbk@bit.edu.cn)

DOI:10.1364/PRJ.387707

Topics

laser devices and laser physics

Lasers and Laser Optics

Laser physics

laser manufacturing

Instrumentation, Measurement and Metrology