Chinese Journal of Lasers, Volume. 52, Issue 4, 0402301(2025)

Preparation of Copper/Nickel Dissimilar Metals by Laser Additive Manufacturing Based on Copper Alloy Surface Pretreatment

Xunjie Yao1,2, Yanyan Zhu1,2、*, Xi Han2, Junwei Yang1,2, Long Chen1,2, Xinyi Wang1,2, and Huaming Wang1,2
Author Affiliations
  • 1School of Materials Science and Engineering, Beihang University, Beijing 100191, China
  • 2National Engineering Laboratory of Additive Manufacturing for Large Metallic Components, Beihang University, Beijing 100191, China
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    Figures & Tables(16)
    Schematic of laser-directed energy deposition as well as powder morphology and statistical size. (a) Schematic showing laser-directed energy deposition of GH4169 on a CuCrZr substrate; (b) morphology and statistical size of GH4169 alloy powder
    Partial CuCrZr substrate plates with surface treatment. (a) Surface treatment schematics; (b)(c) thermal spraying; (d) cold spraying; (e) physical vapor deposition (PVD); (f) electroplating; (g) surface powder spreading (pre-grooved)
    Laser coaxial powder delivery additive manufacturing. (a) CuCrZr/GH4169 dissimilar metals block specimen; (b) sampling diagram of specimens for tensile test and microstructure observation; (c) dimension of tensile specimen; (d) physical diagram of tensile specimen
    Coatings with different thicknesses prepared by different surface pre-treatment processes. (a)‒(c) Thermal spraying; (d)‒(f) cold spraying; (g)‒(i) electroplating; (j)‒(k) PVD; (l) surface powder spreading
    Comparison chart of the designed and actual coating thickness for different surface pre-treatment processes
    Metallographic images showing cross-sections of the specimens obtained by single-pass deposition with three processes on thermal-spraying pretreated CuCrZr substrate
    Metallographic images showing cross-sections of the specimens obtained by single-pass deposition with three processes on cold-spraying pretreated CuCrZr substrate
    Metallographic images showing cross-sections of the specimens obtained by single-pass deposition with three processes on CuCrZr substrate pretreated by electroplating, PVD, and surface powder spreading
    Cross-section parameters of single-pass cladding samples. (a) Schematic diagram of the cross-section parameters; (b) radar chart of the cross-section parameters
    CuCrZr/GH4169 dissimilar metals additive manufacturing block specimens and their nondestructive testing results. (a) Actual photograph; (b) cross-sectional view; (c)(d) nondestructive testing results
    Microstructure at the interface of CuCrZr/GH4169 dissimilar metals specimen. (a) Metallographic image; (b) SEM image; (c)‒(g) EDS elemental mapping images of Cu, Cr, Zr, Ni, Nb; (h) metallographic image of the transition zone; (i) sampling diagram in transition zone for EDS analysis; (j) SEM image of GH4169 zone
    Tensile test results of CuCrZr/GH4169 dissimilar alloy additive manufacturing specimens. (a) Tensile curves and residual specimen images; (b) subsurface image of the tensile fracture; (c) SEM image of the tensile fracture surface
    • Table 1. Chemical composition of GH4169 powder

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      Table 1. Chemical composition of GH4169 powder

      ElementMass fraction /%
      Ni53.22
      Cr18.03
      Nb5.12
      Mo2.91
      Ti0.70
      Co1.00
      Al0.55
      FeBal.
    • Table 2. Chemical composition of CuCrZr substrate plate

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      Table 2. Chemical composition of CuCrZr substrate plate

      ElementMass fraction /%
      Cr0.88
      Zr0.05
      CuBal.
    • Table 3. Chemical composition and thickness of the coatings prepared by different surface pre-treatment processes

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      Table 3. Chemical composition and thickness of the coatings prepared by different surface pre-treatment processes

      Surface pre-treatment processCompositionDesign thickness /μm
      Thermal sprayingGH416950, 100, 150
      Cold sprayingNi50, 100, 150
      ElectroplatingNi10, 20, 40
      Physical vapor deposition (PVD)Ni20, 40
      Powder spreadingGH4169150, 250
    • Table 4. Elemental analysis results of each point shown in Fig. 11(i)

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      Table 4. Elemental analysis results of each point shown in Fig. 11(i)

      No.Mass fraction /%
      NiCrCuZrNbMoFe
      Point 147.4518.907.090.584.863.2017.89
      Point 243.3122.835.600.553.214.1520.32
      Point 345.7118.887.930.775.363.6017.70
      Point 47.345.7379.30007.52
      Point 517.158.0965.20009.46
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    Xunjie Yao, Yanyan Zhu, Xi Han, Junwei Yang, Long Chen, Xinyi Wang, Huaming Wang. Preparation of Copper/Nickel Dissimilar Metals by Laser Additive Manufacturing Based on Copper Alloy Surface Pretreatment[J]. Chinese Journal of Lasers, 2025, 52(4): 0402301

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    Paper Information

    Category: Laser Additive Manufacturing

    Received: Jul. 15, 2024

    Accepted: Aug. 26, 2024

    Published Online: Jan. 9, 2025

    The Author Email: Zhu Yanyan (zhuyy@buaa.edu.cn)

    DOI:10.3788/CJL241054

    CSTR:32183.14.CJL241054

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