Acta Physica Sinica, Volume. 69, Issue 11, 114201-1(2020)

Optical properties and microstructure of two Ge-Sb-Se thin films

Lei Pan1,2, Bao-An Song1,2、*, Chuan-Fu Xiao1,2, Pei-Qing Zhang2,3, Chang-Gui Lin2,3, and Shi-Xun Dai2,3
Author Affiliations
  • 1Faculty of Electrical Engineering and Computer Science, Ningbo University, Ningbo 315211, China
  • 2Zhejiang Key Laboratory of Photoelectric Detection Materials and Devices, Ningbo University, Ningbo 315211, China
  • 3Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China
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    Figures & Tables(13)
    Schematic of the structure of a thin film coated on a transparent silica glass substrate.
    Transmittance curve of Si-H thin film on finite glass substrate.
    Comparison of refractive index and dispersion of thin film obtained by six different models.
    Relation between the refractive index and the dispersion obtained by six dispersion models (include MCM) and the true value as a function of wavelength: (a) Δnvs. wavelength; (b) ΔDvs. wavelength.
    Comparison of five filtering methods to reduce noise: (a) Adjacent averaging method; (b) Savitaky-Golay method; (c) percentile filter method; (d) FFT filter method; (e) piecewise fitting method.
    Transmission curve with upper and lower tangent envelopes obtained by using the improved Swanepoel method: (a) Ge20Sb15Se65 film; (b) Ge28Sb12Se60 film.
    Refractive index and dispersion of Ge-Sb-Se films: (a) Refractive index vs. wavelength; (b) dispersion vs. wavelength.
    Absorption characteristics of Ge-Sb-Se films: (a) Absorption coefficient vs. wavelength; (b) square root of the product of the absorption coefficient and photon energy vs. the photon energy in the strong absorption region.
    Raman spectrum of Ge-Sb-Se film.
    • Table 1. [in Chinese]

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      Table 1. [in Chinese]

      名称模型
      Cauchy$n = A + \dfrac{B}{{{\lambda ^2}}} + \dfrac{C}{{{\lambda ^4}}}$
      二阶归一化标准Sellmeier$n = \sqrt {1 + \dfrac{{A \cdot {\lambda ^2}}}{{{\lambda ^2} - B}} + \dfrac{{C \cdot {\lambda ^2}}}{{{\lambda ^2} - D}}} $
      三阶归一化标准Sellmeier$n = \sqrt {1 + \dfrac{{A \cdot {\lambda ^2}}}{{{\lambda ^2} - B}} + \dfrac{{C \cdot {\lambda ^2}}}{{{\lambda ^2} - D}} + \dfrac{{E \cdot {\lambda ^2}}}{{{\lambda ^2} - F}}} $
      二阶非标准形式的Sellmeier$n = \sqrt {A + \dfrac{{B \cdot {\lambda ^2}}}{{{\lambda ^2} - C}} + D \cdot {\lambda ^2}} $
      Conrady$n = A + \dfrac{B}{\lambda } + \dfrac{C}{{{\lambda ^{3.5}}}}$
      Herzberger$n = A + B \cdot {\lambda ^2} + C \cdot {\lambda ^2} + \dfrac{D}{{\left( {{\lambda ^2} - 0.028} \right)}} + \dfrac{E}{{{{\left( {{\lambda ^2} - 0.028} \right)}^2}}}$
    • Table 2.

      Values of λ, TM, and Tm obtained in Fig. 2 and the values of n and d calculated by the improved Swanepoel method

      图2中数据获得的λ, TMTm的值以及通过改进后的Swanepoel方法计算的nd

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      Table 2.

      Values of λ, TM, and Tm obtained in Fig. 2 and the values of n and d calculated by the improved Swanepoel method

      图2中数据获得的λ, TMTm的值以及通过改进后的Swanepoel方法计算的nd

      λTMTmndm0mn0d0
      972.40.92020.50072.91736.0016.02.91691000.0
      911.20.91990.49042.96136.5016.52.96111000.0
      859.00.91930.48013.00661000.07.0027.03.00621000.0
      814.10.91830.46973.05271000.47.5017.53.05261000.1
      774.90.91650.45913.09961000.18.0028.03.09931000.0
      740.50.91340.44853.1471999.58.5028.53.14681000.0
      710.00.90800.43763.1951999.79.0029.03.19471000.0
      682.80.89840.42603.2435999.49.5029.53.2430999.9
      658.40.88180.41323.29211000.210.00210.03.29171000.0
      636.30.85300.39823.3410999.310.50310.53.3402999.9
      616.30.80500.37963.3898999.611.00311.03.3893999.9
      598.10.72520.35463.43351020.411.48311.53.43871001.6
      581.30.61270.31913.48781000.612.00212.03.48741000.0
      565.90.45950.26783.5368981.912.50212.53.53651000.0
      551.70.28790.19653.58561001.613.00113.03.58571000.1
      注: $ \qquad \quad \overline d = 1000.2;{\sigma _1} = 7.58;\overline {{d_0}} = 1000.1;{\sigma _0} = 0.40$.
    • Table 3.

      Refractive index at multiple wavelengths of two thin films obtained by MCM.

      多点柯西法获得的两种薄膜多个波长处的折射率

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      Table 3.

      Refractive index at multiple wavelengths of two thin films obtained by MCM.

      多点柯西法获得的两种薄膜多个波长处的折射率

      波长/nmGe20Sb15Se65薄膜 Ge28Sb12Se60薄膜
      TexpTMmnTexpTMmn
      6000.24490.26828.73312.69020.00090.025313.37932.8670
      6200.34630.40368.01312.65300.04170.072612.76202.8259
      6400.49870.54967.41602.62080.11070.095712.20732.7902
      6600.47490.68456.91062.59290.24490.251911.70572.7592
      6800.77240.78916.47602.56850.29140.395711.24952.7320
      7000.65660.85526.09722.54720.52220.526611.02592.7081
      7500.90880.90965.76342.50410.74690.785310.10682.6597
      8000.61600.92195.46652.47200.61550.91239.34552.6233
      9000.61990.93214.96022.42850.86670.96818.14942.5735
      10000.76660.93884.54332.40140.75470.97357.24482.5420
      11000.80850.94294.19322.38350.61240.97736.53162.5210
      12000.75800.94553.89452.37110.96780.98055.95232.5062
      13000.68500.94723.63642.36220.61860.98135.47092.4955
      14000.94180.94803.41092.35560.95560.98065.06382.4875
      15000.78140.94823.21212.35060.72820.98014.71452.4813
      16000.65210.94793.03562.34660.64300.98004.41122.4765
      17000.72440.94742.87762.34350.88530.98004.14522.4726
      18000.89140.94703.12132.34100.93830.98013.90992.4694
      19000.93840.94702.95442.33890.71640.98013.70022.4668
      20000.82490.94762.80462.33720.62820.98003.51212.4647
      21000.71210.94912.66942.33580.68680.98003.28382.4628
      22000.66140.95182.54682.33450.84110.98013.13252.4613
      23000.66790.95592.43492.33350.97050.98042.99472.4599
      24000.71880.96172.33262.33260.94410.98092.86862.4588
    • Table 4.

      Vibration modes in the Raman spectrum of Ge-Sb-Se system.

      Ge-Sb-Se薄膜拉曼光谱中对应的振动模式

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      Table 4.

      Vibration modes in the Raman spectrum of Ge-Sb-Se system.

      Ge-Sb-Se薄膜拉曼光谱中对应的振动模式

      拉曼峰位/cm–1振动模式
      160Se2Sb-SbSe2结构中的Sb—Sb同极键的振动
      170Ge2Se6/2结构中的Ge—Ge同极键的伸缩振动
      197SbSe3/2三角锥结构中的Sb—Se键的E1模式振动
      203共顶角GeSe4/2四面体中的Ge—Se键的V1模式振动
      215共边GeSe4/2四面体中的Ge—Se键振动
      235Sen环结构中的Se—Se键振动
      256Sen链结构中的Se—Se键振动
      270Ge-GemSe4-m结构中的Ge—Ge同极键的振动
      303GeSe4四面体的F2型不对称振动
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    Lei Pan, Bao-An Song, Chuan-Fu Xiao, Pei-Qing Zhang, Chang-Gui Lin, Shi-Xun Dai. Optical properties and microstructure of two Ge-Sb-Se thin films[J]. Acta Physica Sinica, 2020, 69(11): 114201-1

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    Paper Information

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    Received: Jan. 21, 2020

    Accepted: --

    Published Online: Dec. 2, 2020

    The Author Email:

    DOI:10.7498/aps.69.20200145

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