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Chinese Journal of Lasers, Volume. 52, Issue 6, 0611001(2025)

Analysis of Cu Elements in Soil by Spatially Constrained LIBS Combined with Resin Enrichment

Jinmei Wang1, Zhi Yang1, Peichao Zheng1、*, Guanghui Chen1, Xufeng Liu1, Zhicheng Sun1, Daming Dong2,3, Hongwu Tian2,3, and Lianbo Guo4
Author Affiliations
  • 1Chongqing Municipal Key Laboratory of Photoelectric Information Sensing and Transmission Technology, College of Optoelectronic Engineering, Chongqing University of Posts and Telecommunications, Chongqing 400065, China
  • 2Research Center of Intelligent Equipment, Beijing Academy of Agriculture and Forestry Sciences, Beijing 100097, China
  • 3Key Laboratory of Agricultural Sensors, Ministry of Agriculture and Rural Affairs, Beijing 100097, China
  • 4Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, Hubei , China
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    [1] He Y, Peng C, Zhang Y et al. Comparison of heavy metals in urban soil and dust in cities of China: characteristics and health risks[J]. International Journal of Environmental Science and Technology, 20, 2247-2258(2023).

    [2] Wu H Y, Yang F, Li H P et al. Heavy metal pollution and health risk assessment of agricultural soil near a smelter in an industrial city in China[J]. International Journal of Environmental Health Research, 30, 174-186(2020).

    [4] Custodio M, Peñaloza R, Cuadrado W et al. Data on the detection of essential and toxic metals in soil and corn and barley grains by atomic absorption spectrophotometry and their effect on human health[J]. Chemical Data Collections, 32, 100650(2021).

    [5] Geng M M, Zhang L P, Wang J R et al. Effects of sample particle size and preparation on the determination of 19 elements in soil samples by wavelength dispersive X-ray fluorescence spectrometry[J]. Soil and Fertilizer Sciences in China, 239-250(2023).

    [6] Guo Y M, Guo L B, Li J M et al. Research progress in Asia on methods of processing laser-induced breakdown spectroscopy data[J]. Frontiers of Physics, 11, 114212(2016).

    [7] Zhang Y, Zhang T L, Li H. Application of laser-induced breakdown spectroscopy (LIBS) in environmental monitoring[J]. Spectrochimica Acta Part B: Atomic Spectroscopy, 181, 106218(2021).

    [8] Guo L B, Zhang D, Sun L X et al. Development in the application of laser-induced breakdown spectroscopy in recent years: a review[J]. Frontiers of Physics, 16, 22500(2021).

    [9] Shi M X, Wu J, Wu D et al. Multi-element quantitative analysis of shale and sandstone based on laser induced breakdown spectroscopy[J]. Chinese Journal of Lasers, 51, 0811002(2024).

    [10] Yu K Q, Ren J, Zhao Y R. Principles, developments and applications of laser-induced breakdown spectroscopy in agriculture: a review[J]. Artificial Intelligence in Agriculture, 4, 127-139(2020).

    [11] Fu X L, Li G L, Dong D M. Improving the detection sensitivity for laser-induced breakdown spectroscopy: a review[J]. Frontiers in Physics, 8, 68(2020).

    [12] Li X L, Huang J, Chen R Q et al. Chromium in soil detection using adaptive weighted normalization and linear weighted network framework for LIBS matrix effect reduction[J]. Journal of Hazardous Materials, 448, 130885(2023).

    [13] Pan C C, Zhao N J, Ma M J et al. Highly sensitive detection of Cd in soil using laser-induced breakdown spectroscopy[J]. Laser & Optoelectronics Progress, 60, 1730006(2023).

    [14] Lin X M, Yang Y H, Lin J J et al. Effect of pH value on chelating resin removal of heavy metals in sewage using laser-induced breakdown spectroscopic detection[J]. Journal of Applied Spectroscopy, 89, 1185-1192(2023).

    [15] Wang J M, Li G, Zheng P C et al. Highly sensitive detection of heavy metal elements using laser-induced breakdown spectroscopy coupled with chelating resin enrichment[J]. Chemosensors, 11, 228(2023).

    [16] Zhao S Y, Gao X, Chen A M et al. Effect of spatial confinement on Pb measurements in soil by femtosecond laser-induced breakdown spectroscopy[J]. Applied Physics B, 126, 7(2019).

    [17] Fu X L, Li G L, Tian H W et al. Detection of cadmium in soils using laser-induced breakdown spectroscopy combined with spatial confinement and resin enrichment[J]. RSC Advances, 8, 39635-39640(2018).

    [18] Wang Y Q, Jia Y Y, Gao L et al. The effects of cavity diameter and material type of spatial confinement on intensity of laser-induced breakdown spectroscopy[J]. Physica Scripta, 98, 015610(2023).

    [19] Cai Y C, Bu Y, Wang Y H et al. Effect of spatial confinement on plasma evolution and spectrum in laser induced breakdown spectroscopy[J]. Acta Optica Sinica, 43, 0730001(2023).

    [20] Wang X W, Chen A M, Wang Y et al. Spatial confinement effect on femtosecond laser-induced Cu plasma spectroscopy[J]. Physics of Plasmas, 24, 103305(2017).

    [21] Li C M, Guo L B, He X N et al. Element dependence of enhancement in optics emission from laser-induced plasma under spatial confinement[J]. Journal of Analytical Atomic Spectrometry, 29, 638-643(2014).

    [22] Zheng Z K, Ma X H, Zhao H F et al. Research on laser induced breakdown spectroscopy for detection of trace Cu in polluted soil[J]. Spectroscopy and Spectral Analysis, 29, 3383-3387(2009).

    [23] Liu Y, Bousquet B, Baudelet M et al. Improvement of the sensitivity for the measurement of copper concentrations in soil by microwave-assisted laser-induced breakdown spectroscopy[J]. Spectrochimica Acta Part B: Atomic Spectroscopy, 73, 89-92(2012).

    [24] Popov A M, Labutin T A, Zaytsev S M et al. Determination of Ag, Cu, Mo and Pb in soils and ores by laser-induced breakdown spectrometry[J]. Journal of Analytical Atomic Spectrometry, 29, 1925-1933(2014).

    [25] Meng D S, Zhao N J, Ma M J et al. Application of a mobile laser-induced breakdown spectroscopy system to detect heavy metal elements in soil[J]. Applied Optics, 56, 5204-5210(2017).

    [26] Akhtar M, Jabbar A, Ahmed N et al. Analysis of lead and copper in soil samples by laser-induced breakdown spectroscopy under external magnetic field[J]. Applied Physics B, 125, 110(2019).

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    Jinmei Wang, Zhi Yang, Peichao Zheng, Guanghui Chen, Xufeng Liu, Zhicheng Sun, Daming Dong, Hongwu Tian, Lianbo Guo. Analysis of Cu Elements in Soil by Spatially Constrained LIBS Combined with Resin Enrichment[J]. Chinese Journal of Lasers, 2025, 52(6): 0611001

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    Paper Information

    Category: spectroscopy

    Received: Sep. 2, 2024

    Accepted: Sep. 18, 2024

    Published Online: Mar. 18, 2025

    The Author Email: Peichao Zheng (zhengpc@cqupt.edu.cn)

    DOI:10.3788/CJL241179

    CSTR:32183.14.CJL241179

    Topics

    laser devices and laser physics
    Lasers and Laser Optics
    Laser physics
    laser manufacturing
    Instrumentation, Measurement and Metrology