Chinese Journal of Lasers, Volume. 50, Issue 18, 1813007(2023)

Advances in Structural Color Research Based on Two-Photon Polymerization 3D Printing Technology

Sihua Su1,2, Kaiyang Wang1,2, Can Huang1,2, Limin Jin1,2, Shumin Xiao1,2, and Qifeng Ruan1,2、*
Author Affiliations
  • 1Ministry of Industry and Information Technology Key Lab of Micro-Nano Optoelectronic Information System, Harbin Institute of Technology (Shenzhen), Shenzhen 518055, Guangdong, China
  • 2Guangdong Provincial Key Laboratory of Semiconductor Optoelectronic Materials and Intelligent Photonic Systems, Harbin Institute of Technology (Shenzhen), Shenzhen 518055, Guangdong, China
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    Figures & Tables(7)
    Dip-in (left) and oil immersion (right) configurations for TPL process
    Structural colors of one- and two-dimensional gratings. (a) Schematic, (b) scanning electron microscope (SEM) image[27], and (c) transmission spectra and optical micrograph[27] of 1D grating; (d) transmission optical micrographs of TPL-printed gratings under normal (left) and oblique (right) incident light, where dashed line outlines highlight the same grating structures showing completely different colors under two lighting modes[28]; (e) schematic, (f) top-view and tilt-view SEM images[29], and (g) transmission optical micrograph[29] of two-dimensional arrays of nanopillars
    Structural colors of 3D photonic crystals. (a)(b) SEM images and (c) transmission spectra of gyroid structure prepared by double-beam super-resolution TPL[15]; (d) schematic, (e) side view and main parameters, (f) SEM image, and (g) reflected optical microscopic image of woodpile structure on glass substrate[31]
    Structural colors of butterfly biomimetic structures. (a) Schematic of tree-like butterfly biomimetic structure prepared by interference-assisted TPL[39]; (b) SEM image of printed tree-like layered structure[39]; (c) fabricated structural color micro-patterns[39]; (d) structure diagram of double-layer orthogonal grating[40]; (e) SEM images of double-layer gratings printed by TPL[40]; (f) photo of Cynandra opis butterfly[40]; (g) SEM image of blue scales on butterfly wings[40]; (h) structural color palette generated by double-layer grating structure[40]; (i) color painting reproduced by biomimetic grating structure[40]
    Structural colors from single micro/nanostructure. (a) Reflected optical micrograph of water droplets condensed on polystyrene Petri dish with photograph of water droplet on underside of Petri dish lid shown in inset[19]; (b) color image produced when water condenses onto polystyrene petri dish[19]; (c) schematics of geometry and composition of biphasic droplet[19]; (d) droplets with different sizes show different colors in reflection with macroscopic view of polydisperse droplets reflecting glittery white light shown in inset[19]; (e) high-magnification and low-magnification (inset) SEM images of TPL-printed cylindrical lens structures[19]; (f) reflected color distribution from cylindrical lens at vertical incidence[19]; (g) structural colors of nanopillars independent of number of columns[44]; (h) structural diagram of nanopillar[45]; (i) top-view and tilted-view SEM images of nanopillar[45];(j) simulated scattering and transmission spectra of nanopillar written directly by laser with multipolar decomposition analysis on scattering[45]; (k) optical micrographs of individual nanopillar under different exposure time with color distribution of representative nanopillar shown in magnified image[45]
    Stereoscopic structural color information. (a) Structural design of woodpile photonic crystal with side view of unit cell; (b) Merlion based on woodpile photonic crystals[33]; (c) microstructure diagram, (d) SEM image, and (e) optical information encryption effect of 3D inverse opal structure[46]; (f) design drawing, SEM image, and optical image of multi-color lotus structure printed by TPL[47]; (g) optical micrographs of various cartoon images of animals displayed by TPL-printed gratings in sectors at different rotation angles under oblique incident light[28]; (h) cartoon face of print in 25 viewing angles and (i) SEM image of its basic unit[44]
    Dynamic information of structural colors. (a) Schematic, (b) optical micrograph, and (c) SEM image of 3D-printed liquid crystal microstructure showing dual responses to changes in humidity and temperature[7]; (d) “photonic tallies” composed of 3D-printed color vortex optical unit structure for optical encryption[52]; diagrams of (e) color and (f) shape changes of microstructures printed by pH-responsive hydrogel[10]; (g)(h) reconfigurable shape memory polymer nanopillars[54]; (i) color and (j) shape changes of 3D-printed shape memory polymer grid-like grating structures[8]; (k)-(m) elastomeric structures that can hide multiple sets of optical information[9]
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    Sihua Su, Kaiyang Wang, Can Huang, Limin Jin, Shumin Xiao, Qifeng Ruan. Advances in Structural Color Research Based on Two-Photon Polymerization 3D Printing Technology[J]. Chinese Journal of Lasers, 2023, 50(18): 1813007

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    Paper Information

    Category: micro and nano optics

    Received: Apr. 20, 2023

    Accepted: Jun. 27, 2023

    Published Online: Aug. 28, 2023

    The Author Email: Ruan Qifeng (ruanqifeng@hit.edu.cn)

    DOI:10.3788/CJL230749

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