Spectroscopy and Spectral Analysis, Volume. 41, Issue 11, 3418(2021)

Scientific Research on Warring States Ink Unearthed From Jiangling Jiudian Tomb in Hubei Province

Na YAO1、1;, Zi-fan CHEN2、2;, Xiong ZHAO2、2;, and Shu-ya WEI1、1; *;
Author Affiliations
  • 11. Institute of Cultural Heritage and History of Science & Technology, University of Science and Technology Beijing, Beijing 100083, China
  • 22. Hubei Provincial Museum, Wuhan 430077, China
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    Figures & Tables(11)
    A set of writing tools excavated in the tomb of Jiudian village, Jiangling County and presented in the Hubei Museum
    The ancient ink discovered in the tomb of Jiudian village, Jiangling County and presented in the Hubei Museum
    FTIR spectra of lamp soot ink (LM), pine wood ink (PM) and ancient ink (GM)
    The morphologies of lamp soot ink (a), pine wood ink (b) and ancient ink (c) by using Transmission Electron Microscope (×50 000)
    The particle size and size distribution of pine wood ink, lamp soot ink and ancient ink
    The chromatograms(TIC) obtained by Py-GC/MS analysis of ancient ink discovered in Jiudian village, Jiangling County
    The select ion chromatogram (SIM) of ancient ink discovered in Jiudian village by using Py-GC/MS
    The chemical structures of several marker compounds
    • Table 1. Samples used in this study

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      Table 1. Samples used in this study

      类别古墨现代参考墨
      样品江陵九店战国墨松烟墨油烟墨
      来源湖北省博物馆江西安徽绩溪
    • Table 2. Pyrolysis compounds of ancient ink discovered in Jiudian village, Jiangling County by Py-GC/MS

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      Table 2. Pyrolysis compounds of ancient ink discovered in Jiudian village, Jiangling County by Py-GC/MS

      保留时间峰面积/%主要离子化合物
      12.471.4351, 78, (104)苯乙烯
      Cam14.761.0255, 81, (95), 108, 152樟脑
      Nap15.931.2651, 102, (128)
      216.420.66(55), 69, 97, 1681-十二烷醇
      319.611.44115, (142)1-甲基萘
      E123.183.1293, 105, (119), 161, 204α-柏木烯
      E223.41.9769, 93, 133, (161), 204β雪松烯
      E324.941.72105, 119, (132), 145, 202花侧柏烯
      E428.224.7669, 95, (150), 161, 204雪松醇
      S132.23.5776, 89, 152, (178)
      432.778.03(77), 121, 2141,2-二苯氧基-乙烷
      533.541.3(58), 85, 124, 2506,10,14-三甲基-2-十五酮
      634.81.91(192)3-甲基菲
      735.32.1395, (192)2-甲基蒽
      836.280.92101, 150, (204)2-苯基萘
      S238.532.9288, 101, (202)荧蒽
      S339.12.8288, 101, (202)
      T140.91.43189, 204, (219), 234惹烯
      942.856.32(179), 261, 343未知
      T243.120.32(239), 299, 314脱氢松香酸甲酯
      S445.131.37101, 113, (228), 229三亚苯
      S550.522.6113, 125, (252)苯并[k]荧蒽
      1052.030.44239, 321, 403, (485)未知
      1155.790.18138, (276)苯并[ghi]苝
    • Table 3. The relative contents of the main PAHs in the modern pine wood ink (PM), lamp soot ink (LM), carbon black (CB) in literature and ancient ink (GM) in Jiudian village, Jiangling County by Py-GC/MS analysis in SIM mode

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      Table 3. The relative contents of the main PAHs in the modern pine wood ink (PM), lamp soot ink (LM), carbon black (CB) in literature and ancient ink (GM) in Jiudian village, Jiangling County by Py-GC/MS analysis in SIM mode

      PAHs样品
      PMLMCBGM
      S1 area(%) (m/z 178)13.914.571.426.8
      S2 area(%) (m/z 202)27.034.39.822.0
      S3 area(%) (m/z 202)28.934.79.121.2
      S4 area(%) (m/z 228)10.03.80.010.3
      S5 area(%) (m/z 252)20.212.59.519.6
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    Na YAO, Zi-fan CHEN, Xiong ZHAO, Shu-ya WEI. Scientific Research on Warring States Ink Unearthed From Jiangling Jiudian Tomb in Hubei Province[J]. Spectroscopy and Spectral Analysis, 2021, 41(11): 3418

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    Paper Information

    Category: Orginal Article

    Received: May. 16, 2021

    Accepted: --

    Published Online: Dec. 17, 2021

    The Author Email:

    DOI:10.3964/j.issn.1000-0593(2021)11-3418-06

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