Journal of Inorganic Materials, Volume. 39, Issue 2, 115(2023)

Chemical Scissor-mediated Structural Editing of Inorganic Materials

Haoming DING1,2, Ke CHEN1,2, Mian LI1,2, Youbing LI3, Zhifang CHAI1,2, and Qing HUANG1,2、*
Author Affiliations
  • 11. Engineering Laboratory of Advanced Energy Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  • 22. Qianwan Institute of CHiTECH, Ningbo 315336, China
  • 33. School of Radiation Medicine and Protection, Soochow University, Suzhou 215123, China
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    Figures & Tables(16)
    Preparation of graphene nanoribbons by photolithographic plasma etching technique[13]
    Metal nanoparticles as catalyst scissors cutting graphene [19]
    Photocatalytic cutting of graphene[12]
    Schematic illustration of scanning probe microscopy (SPM) technique for cutting graphene nanosheets[11]
    H2SO4/HNO3 as chemical scissors cutting g-C3N4[22]
    Pd single-atom modification by selectively trimming the Pd atoms on the PCN surface using chemical scissors[23]
    N atomic vacancy modification of g-C3N4 realized by cutting of H2 chemical scissor[24]
    Mg/Zn/CO2 scissors rationally tailoring the carbon nanomaterials[25]
    Preparation of hollow nanostructure using chemical scissors
    Schematic representation of structural conversion using dppm as chemical scissor[60]
    Two-dimensional MOF materials synthesized by proton concentration modulation with chemical scissor effect[30]
    Schematic illustrations of different etching methods for preparation of MXene
    Chemical-scissors assisted structural editing strategy for layered transition metal carbides/nitrides[10]
    Lewis-acidic-melt method for the preparation of MAX phases and MXenes
    Chemical scissor-assisted atomic intercalation of transition metal dichalcogenides[38]
    • Table 1. Chemical mechanism of typical "chemical scissors" and applications in structural editing

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      Table 1. Chemical mechanism of typical "chemical scissors" and applications in structural editing

      Regulation mechanismChemical scissorChemical mechanismTargetPotential applicationsRef.
      Chemical cuttingPlasmaCollision and reaction of plasma on graphene surfaceGrapheneElectronic engineering[13, 16]
      O2/NH3Oxidation of edge carbon atomsGrapheneElectronic engineering[17]
      Metal nanoparticlesCatalytic hydrogenation of carbon atomsGrapheneElectronic engineering[18-19]
      TiO2 photocatalysisPhotoinduced oxidation of carbon atoms by highly active OH radicalsGrapheneElectronic engineering[12]
      HNO3/H2SO4/KClO3Thermal expansion caused by oxidation and decomposition of surface functional groups of graphiteGraphiteEnergy storage[20]
      NH3/H2O2Oxidation of carbon atomsg-C3N4Catalysis, Sensor[21]
      HNO3/H2SO4Oxidation of carbon atomsg-C3N4Catalysis, Sensor[22]
      Chemical modificationFeCl3Oxidation of Pd atomsPd clustersCatalysis, Sensor[23]
      H2Hydrogenation of N atomsg-C3N4Catalysis, Sensor[24]
      CO2Oxidation of carbon atomsCarbon materialsEnergy storage[25]
      Chemical synthesisC2H5OHThe breaking of organic bonds results in the dissolution of organic substances3-aminophenol formaldehyde resinCatalysis[14]
      AcetoneThe breaking of organic bonds results in the dissolution of organic substances3-aminophenol formaldehyde resinCatalysis, energy storage[26-27]
      Lone pair cations and halogen ionsControl of coordination environmentsSb2ZnO3Cl2Sb16Cd8O25Cl14Te6O11Cl2Sb4O5Cl2Catalysis, energy storage[15, 28-29]
      H+Control of reaction dynamicsMetal-benzene hexethiol (BHT) coordination polymerCatalysis[30]
      Chemical etching and intercalationLewis acidic melts (CuCl2, ZnCl2)Oxidation of A-site atoms in MAX phasesMAX phasesCatalysis, energy storage, electronic engineering[10, 31-35]
      HF, HCl/LiFAcidic dissolution of A-site atoms in MAX phasesMAX phasesCatalysis, energy storage[36-37]
      Metal atoms (Mn, Fe, Co, Ni,Cu, Ag)Regulating electronic structure by injecting electrons into host materialsTransition metal chalcogenidesCatalysis, energy storage[38]
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    Haoming DING, Ke CHEN, Mian LI, Youbing LI, Zhifang CHAI, Qing HUANG. Chemical Scissor-mediated Structural Editing of Inorganic Materials[J]. Journal of Inorganic Materials, 2023, 39(2): 115

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    Paper Information

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    Received: Nov. 10, 2023

    Accepted: --

    Published Online: Jul. 8, 2024

    The Author Email: Qing HUANG (huangqing@nimte.ac.cn)

    DOI:10.15541/jim20230527

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