Chinese Journal of Liquid Crystals and Displays, Volume. 38, Issue 3, 342(2023)

Application of perovskite quantum dot glass backlight

Ji-dong LIN and Da-qin CHEN*
Author Affiliations
  • College of Physics and Energy,Fujian Normal University,Fuzhou 350000,China
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    Figures & Tables(9)
    Three typical configurations of backlight systems in LCDs with placement of quantum dot materials.(a)On chip;(b)On edge;(c)On surface[35].
    Light-emitting devices made with(a)CsPbBr3@glass slice,(b)CsPb(BrI)3@glass slice,and(c)CsPbBr3@glass+CsPb(BrI)3@glass slices in scheme 1;(d)Luminous efficiency and external quantum efficiency of CsPbBr3@glass slice and CsPb(BrI)3@glass slice;(e)CsPbBr3@glass+ CsPb(BrI)3@glass slices in schemes 1 and 2 and(f)their chromaticity coordinates as a function of forward bias current[29].
    (a)Color reproduction range of LED mounted with the PIG with the BRG arrangement(inset figure)with and without application of the color filter function. The insets are EL+PL spectrum and actual photograph;(b)Transmittance spectra of red,green,and blue(R,G,and B)color filters [42].
    Color gamuts of sRGB,NTSC 1953,DCI-P3 and Rec.2020 in the CIE diagram.
    (a)PLQY value versus emitting wavelength for the CsPbX3@glass samples prepared with two different kinds of glass compositions. For comparison,the PLQY values of colloidal CsPb(Br/I)3 PeQDs with different green emission wavelengths are also provided. All the measurements are under the same excitation wavelength of 450 nm;(b)Decay lifetime of exciton recombination versus emitting wavelength for the CsPbX3@glass samples;Two-dimensional femtosecond pumping transient absorption spectra of(c)CsPbBr3@glass and(d)CsPbBr2.52I0.48@glass samples. The blue and red regions correspond to ground state bleaching and excited emission respectively,indicating that additional defective state trapping exciton radiation is produced when mixed halogen quantum dots are precipitated[35].
    Thermal cycling test results of perovskite quantum dot glass samples.(a)~(c)Samples from Liu et al[29];(d)Samples from Guo et al[48];(e)Samples from Im et al[42];(f)Samples from Chen et al[35].
    (a)Dependence of PLQYs for the green film(CsPbBr3@glass@PDMS)on the weight ratio of[CsPbBr3@glass]/PDMS,insets are the photographs of the luminescent films;(b)Dependence of PLQYs for the CsPbBr3@glass@PDMS and CsPbBr1.5I1.5@glass@PDMS films on the wavelength of incident excitation light;(c)Photostability test under UV light(6 W)irradiation for 7 days;(d)Humidity-resistance test under the strengthening condition by directly immersing CsPbX3@glass@PDMS films in water maintained at 90 ℃ for 24 h,as a comparison,the data for colloidal CsPbBr3 PeQDs in PDMS(CsPbBr3@PDMS)are also provided in(c,d);Comparison between a display prototype integrated with a perovskite quantum dot glass optical film(e)and a commercial display(f)[27];Comparisons between a display prototype integrated with a perovskite quantum dot optical film(g)and Apple MacBook Air(h)[55].
    (a)EL spectra of white light backlight unit fabricated by combining blue LGP with CsPbBr3@glass@PDMS film and KSF∶Mn4+ film,insets are the backlight unit under daylight and 3.3 V applied voltage;(b)Schematic diagram of the LCD device structure using the as-prepared backlight unit;Display performance of LCD screen with commercial backlight unit((c),(e))and CsPbBr3@glass@PDMS film backlight unit((d),(f));(g)Color gamut of the commercial screen(green line),the CsPbBr3@glass@PDMS film screen with and without color filters(dash line and black line,respectively),NSTC 1953 standard(blue line)and Rec. 2020 standard(red line)in the CIE diagram[60].
    • Table 1. Comparison of key optical parameters between perovskite quantum dot colloid and quantum dot glass

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      Table 1. Comparison of key optical parameters between perovskite quantum dot colloid and quantum dot glass

      钙钛矿量子点所处环境PLQY/%发射峰值波长/nmFWHM/nm参考文献
      CsPbBr3玻璃81.1530~2029
      CsPbBr3玻璃63517~2135
      CsPbBr3玻璃86.95161861
      CsPbBr3玻璃71.552523.949
      CsPbBr3玻璃91.45192341
      CsPbBr3玻璃@PDMS~10051827
      CsPb(BrI)3玻璃0~10520~530~2135
      CsPbBr3玻璃8052062
      CsPbBr3玻璃28.7~55517~52824.93~26.3744
      CsPbBr3玻璃@PDMS805241760
      MAPbBr3溶液@PVDF94.652523.243
      CsPbBr3溶液955132063
      CsPbX3溶液50~90410~70012~4214
      CsPbBr3溶液905171764
      FaPbBr3溶液855302265
      CsPbBr3溶液@PMMA82.652018.666
      CsPbBr1.5I1.5玻璃46627~3635
      CsPbBr1.5I1.5玻璃@PDMS~8063027
      CsPbBrxI3-x玻璃50~60580~65062
      CsPbBrI2玻璃15.6/20.2630/640~3029
      CsPb(BrI)3玻璃23.3~49627~63745
      γ-RbxCs1-xPbI3溶液@PMMA826303167
      CsPb(BrI)3溶液70~80548~64026~3863
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    Ji-dong LIN, Da-qin CHEN. Application of perovskite quantum dot glass backlight[J]. Chinese Journal of Liquid Crystals and Displays, 2023, 38(3): 342

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    Paper Information

    Category: Research Articles

    Received: Jul. 1, 2022

    Accepted: --

    Published Online: Apr. 3, 2023

    The Author Email: Da-qin CHEN (dqchen@fjnu.edu.cn)

    DOI:10.37188/CJLCD.2022-0223

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