Chinese Journal of Quantum Electronics, Volume. 42, Issue 3, 295(2025)

Mechanism of vitamin C and 9,10⁃anthraquinone photoinduced reaction based on time⁃resolved photoluminescence spectroscopy technology

WEI Yaxiong1,2、*, FU Tingting1,2, LIU Yi1,2, and XU Xinsheng1,2、**
Author Affiliations
  • 1School of Physics and Electronic Information, Anhui Normal University, Wuhu 241002, China
  • 2Anhui Key Laboratory for Control and Applications of Optoelectronic Information Materials, Wuhu 241002, China
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    Figures & Tables(6)
    Molecular structure of anthraquinone (AQ), vitamin C (VC), and vitamin C anion (VCA-)
    (a) CIDEP spectra of AQ and AQ+VC in EG/H2O homogeneous solutions, delay time td = 0.6 µs;(b) The reaction dynamic of AQ+VC in EG/H2O homogeneous solution
    Surface tension versus lg[TX-100] of TX-100 in EG-H2O (9/1, v/v) micelle solution when the temperature is 25 oC
    In EG/H2O/TX-100 micelle solution: CIDEP spectrum of AQ+VC, the delay time td = 0.6 µs (a); Plot of I[EG-H•]0 / I[EG-H•] versus c[VC] (b); Transient absorption spectra of AQ, the delay times are 0.5, 5.0, 20.0, 50.0 µs, respectively (c); The decay kinetics curve corresponding to the 390 nm absorption peak in the transient absorption spectra of AQ (d)
    (a) The molecular structures of the four surfactants. In aqueous solution, AOT and SDS are anions, TX-100 is a neutral molecule, and CTAB is an cation; (b) Schematic diagram of molecular diffusion collision of AQ+VC in different micelle solutions
    • Table 1. The bimolecular quenching rates constant of AQ+VC in different micelle solutions

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      Table 1. The bimolecular quenching rates constant of AQ+VC in different micelle solutions

      Reaction solventSurface chargekSV / (mol⋅L-1)τ / μskq / (mol⋅L-1⋅s-1)
      EG/H2O-78 ± 410.3 ± 0.2(0.76 ± 0.04) × 107
      EG/H2O/TX-100No charge49 ± 49.6 ± 0.1(0.52 ± 0.04) ×107
      EG/H2O/AOTNegative23 ± 19.0 ± 0.2(0.26 ± 0.01) ×107
      EG/H2O/SDSNegative21 ± 28.8 ± 0.1(0.24 ± 0.02) ×107
      EG/H2O/CTABPositive130 ± 49.7 ± 0.2(1.35 ± 0.04) ×107
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    Yaxiong WEI, Tingting FU, Yi LIU, Xinsheng XU. Mechanism of vitamin C and 9,10⁃anthraquinone photoinduced reaction based on time⁃resolved photoluminescence spectroscopy technology[J]. Chinese Journal of Quantum Electronics, 2025, 42(3): 295

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    Paper Information

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    Received: Dec. 22, 2023

    Accepted: --

    Published Online: Jun. 11, 2025

    The Author Email: Yaxiong WEI (Davidl@mail.ustc.edu.cn), Xinsheng XU (xxsheng@mail.ahnu.edu.cn)

    DOI:10.3969/j.issn.1007-5461.2025.03.001

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