NUCLEAR TECHNIQUES, Volume. 47, Issue 4, 040203(2024)

Exploring the defects evolution of nuclear graphite by using micro-Raman characterization on the cross-section of 107Ag5+ ion irradiated nuclear graphite at high temperature

Yiyan LI1,2, Zhoutong HE2, Xiuliang ZHAO1、*, Shancheng PENG2,3, and Huilei MA2,3
Author Affiliations
  • 1School of Nuclear Science and Technology, University of South China, Hengyang 421001, China
  • 2Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China
  • 3University of Chinese Academy of Sciences, Beijing 100049, China
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    Figures & Tables(12)
    Schematic diagram of sample irradiation and cross-sectional micro-Raman spectroscopy(a) The micro-Raman device, (b) Two-dimensional Raman spectroscopy physics and pixel size (color online)
    Energy loss of 30 MeV 58Ni5+ and 107Ag5+ ions in graphite carbon (ICRU-906) target calculated by using the all-cascade damage model, the vacancies and ion distributions generated by the two types of ions(a) Electron energy loss, (b) Nuclear energy loss, (c) Total energy loss, (d) 58Ni5+, (e) 107Ag5+
    Normalized Raman spectra of nuclear graphite irradiated by 107Ag5+ ions as a function of different depths: the line scan graph (a) and typical Raman spectra at different depths (c) under dose of 0.3×1016 ions∙cm-2; the line scan graph (b) and typical Raman spectra at different depths (d) under dose of 0.9×1016 ions∙cm-2 (color online)
    Schematic diagram of the Raman spectra fitting for nuclear graphite (color online)(a) Pristine nuclear graphite, (b) Irradiated nuclear graphite
    Grayscale map of different Raman parameters for the D peak and G peak under different doses of 0.3×1016 ions∙cm-2 (a~h) and 0.9×1016 ions∙cm-2 (a1~h1): (a, a1) D Position, (b, b1) D area, (c, c1) FWHM(D), (d, d1) D height, (e, e1) G position, (f, f1) G area, (g, g1) FWHM(G), (h, h1) G height
    Comparison of ID/IG at different depths of nuclear graphite irradiated by 107Ag5+ ions with different fluences: the grayscale map (a) and scatter plots (c) under dose of 0.3×1016 ions∙cm-2; the grayscale map (b) and scatter plots (d) under dose of 0.9×1016 ions∙cm-2
    Variation of the G peak position of nuclear graphite and comparison of Raman spectra between heavily irradiated regions and unirradiated regions under irradiation fluence of 0.3×1016 ions∙cm-2 (a) and 0.9×1016 ions∙cm-2 (b); Standard error plots of G peak at different depths under irradiation fluence of 0.3×1016 ions∙cm-2 (c) and 0.9×1016 ions∙cm-2 (d)
    Scatter plot showing the variation of Raman spectral characteristic parameters of IG-110 irradiated with 107Ag5+ and 58Ni5+[23] ions as a function of DPA (a) ID/IG , (b) FWHM(G)
    ID/IGvs. FWHM(G) for irradiated regions (solid symbols) and unirradiated regions (hollow symbols) under different ion irradiations (color online)
    • Table 1. Nominal physical and mechanical properties of IG-110

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      Table 1. Nominal physical and mechanical properties of IG-110

      性质PropertiesIG-110
      块体密度Bulk density / g·cm-31.77
      晶粒尺寸Grain size / μm20
      孔隙度Porosity / %21.3
      孔径尺寸Pore throat size / μm2.0
      抗拉强度 Tensile strength / MPa39.2
      抗压强度 Compressive strength / MPa78.4
      热膨胀系数 Coefficient of thermal expansion / 10-6·℃-14.5
      热导率 Coefficient of thermal conductivity / W·m-1·K-1120
    • Table 2. Ion irradiation parameters of nuclear graphitic materials

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      Table 2. Ion irradiation parameters of nuclear graphitic materials

      离子

      Ions

      温度

      Temperature / ℃

      离子能量

      Ion energy / MeV

      注量

      Fluence / ions∙cm-2

      辐照损伤剂量

      Radiation damage dose / dpa

      107Ag5+420300.3×10162.32
      107Ag5+420300.9×10166.02
      58Ni5+420300.5×10162.70
      58Ni5+420301.2×10166.21
      58Ni5+420302.3×101612.15
      58Ni5+420303.7×101619.46
    • Table 3. Comparison of fitting results for 107Ag5+ and 58Ni5+[23]

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      Table 3. Comparison of fitting results for 107Ag5+ and 58Ni5+[23]

      离子种类Ion species拟合结果 Fitting results
      107Ag5+ID/IG=0.020 58×(FWHM(G)+9.53)
      58Ni5+ID/IG=0.027×(FWHM(G)-7)
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    Yiyan LI, Zhoutong HE, Xiuliang ZHAO, Shancheng PENG, Huilei MA. Exploring the defects evolution of nuclear graphite by using micro-Raman characterization on the cross-section of 107Ag5+ ion irradiated nuclear graphite at high temperature[J]. NUCLEAR TECHNIQUES, 2024, 47(4): 040203

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    Paper Information

    Category: Research Articles

    Received: Feb. 22, 2024

    Accepted: --

    Published Online: May. 28, 2024

    The Author Email: Xiuliang ZHAO (赵修良)

    DOI:10.11889/j.0253-3219.2024.hjs.47.040203

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