Journal of the Chinese Ceramic Society, Volume. 53, Issue 5, 1369(2025)

A Review on the Physics of Capillary Absorption and on the Significance of Capillary Sorptivity for Cement-Based Materials

GUO Xinzhi1, ZHANG Yun1, ZENG Qiang2, WANG Zhendi3, HONG Shuxian4, WANG Zuqi5, and ZHOU Chunsheng1
Author Affiliations
  • 1School of Civil Engineering, Harbin Institute of Technology, Harbin 150090, China
  • 2School of Civil Engineering, Zhejiang University, Hangzhou 310058, China
  • 3State Key Laboratory of Green Building Materials, China Building Materials Academy, Beijing 100024, China
  • 4Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering, Shenzhen University, Shenzhen 518060, Guangzhou, China
  • 5China Academy of Building Research, Beijing 100013, China
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    References(101)

    [1] [1] HALL C. Water sorptivity of mortars and concretes: A review[J]. Mag Concr Res, 1989, 41(147): 51-61.

    [2] [2] HALL C, HOFF W D. Water Transport in Brick, Stone and Concrete[M]. 3rd Ed. London: CRC Press, 2021.

    [3] [3] ZHOU C S, ZHANG X Y, WANG Z D, et al. Water sensitivity of cement-based materials[J]. J Am Ceram Soc, 2021, 104(9): 4279-4296.

    [4] [4] REINHARDT H E. Penetration and permeability of concrete: Barriers to organic and contaminating liquids[M]. London: Routledge, 2004

    [5] [5] HALL C, TSE T K. Water movement in porous building materials: VII. The sorptivity of mortars[J]. Build Environ, 1986, 21(2): 113-118.

    [6] [6] PHILIP J R. The theory of infiltration[J]. Soil Sci, 84(3): 257-264.

    [7] [7] YANG L, LIU G J, GAO D Y, et al. Experimental study on water absorption of unsaturated concrete: w/c ratio, coarse aggregate and saturation degree[J]. Constr Build Mater, 2021, 272: 121945.

    [8] [8] ZHOU C S. Predicting water permeability and relative gas permeability of unsaturated cement-based material from hydraulic diffusivity[J]. Cem Concr Res, 2014, 58: 143-151.

    [9] [9] BRUTSAERT W. The concise formulation of diffusive sorption of water in a dry soil[J]. Water Resour Res, 1976, 12(6): 1118-1124.

    [10] [10] LOCKINGTON D, PARLANGE J Y, DUX P. Sorptivity and the estimation of water penetration into unsaturated concrete[J]. Mater Struct, 1999, 32(5): 342-347.

    [11] [11] REN F Z, ZHOU C S, LI L, et al. Modeling the dependence of capillary sorptivity on initial water content for cement-based materials in view of water sensitivity[J]. Cem Concr Res, 2023, 168: 107158.

    [12] [12] ZHOU C S, REN F Z, WANG Z D, et al. Why permeability to water is anomalously lower than that to many other fluids for cement-based material?[J]. Cem Concr Res, 2017, 100: 373-384.

    [13] [13] HALL C, HOFF W D, SKELDON M. The sorptivity of brick: Dependence on the initial water content[J]. J Phys D: Appl Phys, 1983, 16(10): 1875-1880.

    [14] [14] ZHOU C S, CHEN W, WANG W, et al. Indirect assessment of hydraulic diffusivity and permeability for unsaturated cement-based material from sorptivity[J]. Cem Concr Res, 2016, 82: 117-129.

    [15] [15] WATKINS C M, BUTTERWORTH B. The absorption of water by clay building bricks and some related properties[J]. Trans Ceram Soc, 1933, 33:444-478.

    [16] [16] BUTTERWORTH B. The rate of absorption of water by partly saturated bricks[J]. Trans Br Ceram Soc, 1947, 46: 72-76.

    [17] [17] DESOUZA S J. Test methods for the evaluation of the durability of covercrete[D]. Toronto, Canada: University of Toronto, 1996.

    [18] [18] NOKKEN M R, HOOTON R D. Dependence of rate of absorption on degree of saturation of concrete[J]. Cem Concr Aggreg, 2002, 24(1): 20-24.

    [19] [19] WONG S F, WEE T H, SWADDIWUDHIPONG S, et al. Study of water movement in concrete[J]. Mag Concr Res, 2001, 53(3): 205-220.

    [20] [20] REN F Z, ZHOU C S, ZENG Q, et al. The dependence of capillary sorptivity and gas permeability on initial water content for unsaturated cement mortars[J]. Cem Concr Compos, 2019, 104: 103356.

    [21] [21] GUMMERSON R J, HALL C, HOFF W D. The suction rate and the sorptivity of bricks[J]. Transac J British Ceramic Soc, 1981, 80(5): 150-152.

    [22] [22] TAYLOR S C, HALL C, HOFF W D, et al. Partial wetting in capillary liquid absorption by limestones[J]. J Colloid Interface Sci, 2000, 224(2): 351-357.

    [23] [23] IOANNOU I, HALL C, WILSON M A, et al. Direct measurement of the wetting front capillary pressure in a clay brick ceramic[J]. J Phys D: Appl Phys, 2003, 36(24): 3176-3182.

    [25] [25] TAYLOR S C, HOFF W D, WILSON M A, et al. Anomalous water transport properties of Portland and blended cement-based materials[J]. J Mater Sci Lett, 1999, 18(23): 1925-1927.

    [26] [26] MARTYS N S, FERRARIS C F. Capillary transport in mortars and concrete[J]. Cem Concr Res, 1997, 27(5): 747-760.

    [27] [27] HALL C. Anomalous diffusion in unsaturated flow: Fact or fiction?[J]. Cem Concr Res, 2007, 37(3): 378-385.

    [28] [28] HALL C, RAYMOND YAU M H. Water movement in porous building materials: IX. The water absorption and sorptivity of concretes[J]. Build Environ, 1987, 22(1): 77-82.

    [29] [29] HALL C, HOFF W D, TAYLOR S C, et al. Water anomaly in capillary liquid absorption by cement-based materials[J]. J Mater Sci Lett, 1995, 14(17): 1178-1181.

    [30] [30] KRUS M, HANSEN K K, KNZEL H M. Porosity and liquid absorption of cement paste[J]. Mater Struct, 1997, 30(7): 394-398.

    [31] [31] HANI L, ILI R. Relationship between liquid sorptivity and capillarity in concrete[J]. Cem Concr Res, 2003, 33(9): 1385-1388.

    [32] [32] LAMPACHER B J, BLIGHT G E. Permeability and sorption properties of mature near-surface concrete[J]. J Mater Civ Eng, 1998, 10(1): 21-25.

    [33] [33] HANI L, KOSEC L, ANEL I. Capillary absorption in concrete and the Lucas-washburn equation[J]. Cem Concr Compos, 2010, 32(1): 84-91.

    [34] [34] BEAUDOIN J J, GU P, MARCHAND J, et al. Solvent replacement studies of hydrated Portland cement systems: The role of calcium hydroxide[J]. Adv Cem Based Mater, 1998, 8(2): 56-65.

    [35] [35] TAMTSIA B T, BEAUDOIN J J. Effect of solvent exchange on length change and creep of D-dried hydrated C3S paste[J]. Adv Cem Res, 2001, 13(1): 1-9.

    [36] [36] YANG Zhenli. Investigations into the effects of several factors affecting the water sensitivity of cement-based materials [D]. Harbin: Harbin Institute of Technology, 2022.

    [37] [37] REN F Z, ZHOU C S, ZENG Q, et al. Quantifying the anomalous water absorption behavior of cement mortar in view of its physical sensitivity to water[J]. Cem Concr Res, 2021, 143: 106395.

    [38] [38] WILSON M A, CARTER M A, HOFF W D. British standard and RILEM water absorption tests: A critical evaluation[J]. Mater Struct, 1999, 32(8): 571-578.

    [39] [39] SABIR B B, WILD S, O’FARRELL M. A water sorptivity test for martar and concrete[J]. Mater Struct, 1998, 31(8): 568-574.

    [40] [40] RADA TAHA M M, EL-DIEB A S, SHRIVE N G. Sorptivity: A reliable measurement for surface absorption of masonry brick units[J]. Mater Struct, 2001, 34(7): 438-445.

    [41] [41] CHEN J J, KWAN A K H, JIANG Y. Adding limestone fines as cement paste replacement to reduce water permeability and sorptivity of concrete[J]. Constr Build Mater, 2014, 56: 87-93.

    [42] [42] GITMAN I M, ASKES H, SLUYS L J. Representative volume: Existence and size determination[J]. Eng Fract Mech, 2007, 74(16): 2518-2534.

    [43] [43] Build N T. 368-1991. Concrete, repair materials: Capillary absorption[S]. Espoo, Nordtest, 1991.

    [44] [44] RILEM TC 116-PCD-1999. Concrete Durability- An Approach Towards performance Testing, in Materials and Structures [S]. Copenhagen, 1999.

    [45] [45] Methods of test for mortar for masonry - Part 18: Determination of water absorption coefficient due to capillary action of hardened mortar: DS/EN 1015-18: 2003[S]. Danish Standards[ds], 2003.

    [46] [46] Standard Test Method for Measurement of Rate of Absorption of Water by Hydraulic-Cement Concretes: ASTM C1585-20[S]. ASTM International, 2020.

    [47] [47] ISO 15148:2002. Hygrothermal performance of building materials and products. Determination of water ab-sorption coefficient by partial immersion[S]. European Committee for Standardization, 2002.

    [48] [48] Department of Civil Engineering, Durability Index Testing Procedure Manual[S]. University of Cape Town, 2009.

    [49] [49] LIU Z C, HANSEN W. Pore damage in cementitious binders caused by deicer salt frost exposure[J]. Constr Build Mater, 2015, 98: 204-216.

    [50] [50] WONG H S, ZOBEL M, BUENFELD N R, et al. Influence of the interfacial transition zone and microcracking on the diffusivity, permeability and sorptivity of cement-based materials after drying[J]. Mag Concr Res, 2009, 61(8): 571-589.

    [51] [51] WU Z, WONG H S, BUENFELD N R. Influence of drying-induced microcracking and related size effects on mass transport properties of concrete[J]. Cem Concr Res, 2015, 68: 35-48.

    [52] [52] PIGEON M, GARNIER F, PLEAU R, et al. Influence of drying on the chloride ion permeability of hpc[J]. Concr Int, 1993, 15: 65-69.

    [53] [53] FAGERLUND G. The critical degree of saturation method of assessing the freeze/thaw resistance of concrete[J]. Matriaux Constr, 1977, 10(4): 217-229.

    [54] [54] KONECNY L, NAQVI S J. The effect of different drying techniques on the pore size distribution of blended cement mortars[J]. Cem Concr Res, 1993, 23(5): 1223-1228.

    [55] [55] ZHANG Z D, SCHERER G W. Physical and chemical effects of isopropanol exchange in cement-based materials[J]. Cem Concr Res, 2021, 145: 106461.

    [56] [56] GRAN H C, HANSEN E W. Exchange rates of ethanol with water in water-saturated cement pastes probed by NMR[J]. Adv Cem Based Mater, 1998, 8(3-4): 108-117.

    [57] [57] MUKADAM Z, ALEXANDER M G, BEUSHAUSEN H D. The effect of drying preconditioning on the South African durability index tests[J]. Cem Concr Compos, 2016, 69: 1-8.

    [58] [58] REN F Z, ZHOU C S, ZENG Q, et al. Numerical investigations into the physical significance of sorptivity for cement-based materials considering water sensitivity[J]. J Build Eng, 2023, 66: 105952.

    [59] [59] ZHANG Z D, ANGST U. Different anomalies of two-stage water absorption in carbonated and non-carbonated cement-based materials[J]. Cem Concr Res, 2024, 183: 107560.

    [60] [60] DIAS W P S. Influence of drying on concrete sorptivity[J]. Mag Concr Res, 2004, 56(9): 537-543.

    [61] [61] SHEN Chunhua. Researches on The Moisture Transport of Cement- Based Materials [D]. Wuhan: Wuhan University of Technology, 2007.

    [62] [62] BUENFELD N R, OKUNDI E. Effect of cement content on transport in concrete[J]. Mag Concr Res, 1998, 50(4): 339-351.

    [63] [63] BUENFELD N R, OKUNDI E, ALEXANDER M G, et al. Discussion: Effect of cement content on transport in concrete[J]. Mag Concr Res, 2000, 52(1): 73-76.

    [64] [64] CHAN S Y N, JI X H. Water sorptivity and chloride diffusivity of oil shale ash concrete[J]. Constr Build Mater, 1998, 12(4): 177-183.

    [65] [65] CASTRO J, BENTZ D, WEISS J. Effect of sample conditioning on the water absorption of concrete[J]. Cem Concr Compos, 2011, 33(8): 805-813.

    [66] [66] HAZAREE C, WANG K J, CEYLAN H, et al. Capillary transport in RCC: Water-to-cement ratio, strength, and freeze-thaw resistance[J]. J Mater Civ Eng, 2011, 23(8): 1181-1191.

    [67] [67] LEUNG H Y, KIM J, NADEEM A, et al. Sorptivity of self-compacting concrete containing fly ash and silica fume[J]. Constr Build Mater, 2016, 113: 369-375.

    [68] [68] FOLAGBADE S O. Sorptivity of cement combination concretes containing portland cement, fly ash and metakaolin[J]. Inter J Eng Res Appl ISSN, 2012: 2248-9622.

    [69] [69] BENLI A, KARATA M, BAKIR Y. An experimental study of different curing regimes on the mechanical properties and sorptivity of self-compacting mortars with fly ash and silica fume[J]. Constr Build Mater, 2017, 144: 552-562.

    [70] [70] HATUNGIMANA D, TAKPR C, MUTLU , et al. Compressive strength, water absorption, water sorptivity and surface radon exhalation rate of silica fume and fly ash based mortar[J]. J Build Eng, 2019, 23: 369-376.

    [71] [71] ZHUTOVSKY S, DOUGLAS HOOTON R. Role of sample conditioning in water absorption tests[J]. Constr Build Mater, 2019, 215: 918-924.

    [72] [72] TUMIDAJSKI P J. Effect of slag, silica fume, and finishing on the sorptivities of field concrete[J]. Can J Civ Eng, 2006, 33(8): 1022-1026.

    [73] [73] GOPALAN M K. Sorptivity of fly ash concretes[J]. Cem Concr Res, 1996, 26(8): 1189-1197.

    [75] [75] GONEN T, YAZICIOGLU S. The influence of compaction pores on sorptivity and carbonation of concrete[J]. Constr Build Mater, 2007, 21(5): 1040-1045.

    [76] [76] LIU B J, LUO G, XIE Y J. Effect of curing conditions on the permeability of concrete with high volume mineral admixtures[J]. Constr Build Mater, 2018, 167: 359-371.

    [77] [77] KELHAM S. A water absorption test for concrete[J]. Mag Concr Res, 1988, 40(143): 106-110.

    [78] [78] TASDEMIR C. Combined effects of mineral admixtures and curing conditions on the sorptivity coefficient of concrete[J]. Cem Concr Res, 2003, 33(10): 1637-1642.

    [79] [79] BAI J, WILD S, SABIR B B. Sorptivity and strength of air-cured and water-cured PC-PFA-MK concrete and the influence of binder composition on carbonation depth[J]. Cem Concr Res, 2002, 32(11): 1813-1821.

    [80] [80] DIAS W P S. Reduction of concrete sorptivity with age through carbonation[J]. Cem Concr Res, 2000, 30(8): 1255-1261.

    [81] [81] KHATIB J M, CLAY R M. Absorption characteristics of metakaolin concrete[J]. Cem Concr Res, 2004, 34(1): 19-29.

    [82] [82] LI Hongma, PAN Zhihua, CHEN Yangyi, et al. Research on the factors influencing water transport in cement-based materials[J].Concrete, 2015(9): 97-100.

    [84] [84] BADOGIANNIS E G, SFIKAS I P, VOUKIA D V, et al. Durability of metakaolin self-compacting concrete[J]. Constr Build Mater, 2015, 82: 133-141.

    [85] [85] UYSAL M, AKYUNCU V. Durability performance of concrete incorporating Class F and Class C fly ashes[J]. Constr Build Mater, 2012, 34: 170-178.

    [86] [86] DINKU A, REINHARDT H W. Gas permeability coefficient of cover concrete as a performance control[J]. Mater Struct, 1997, 30(7): 387-393.

    [87] [87] HAN B G, YANG Z X, SHI X M, et al. Transport properties of carbon-nanotube/cement composites[J]. J Mater Eng Perform, 2013, 22(1): 184-189.

    [88] [88] GESOLU M, GNEYISI E, ALI B, et al. Strength and transport properties of steam cured and water cured lightweight aggregate concretes[J]. Constr Build Mater, 2013, 49: 417-424.

    [89] [89] TSIVILIS S, CHANIOTAKIS E, BATIS G, et al. The effect of clinker and limestone quality on the gas permeability, water absorption and pore structure of limestone cement concrete[J]. Cem Concr Compos, 1999, 21(2): 139-146.

    [90] [90] LI L, LIU W F, YOU Q X, et al. Relationships between microstructure and transport properties in mortar containing recycled ceramic powder[J]. J Clean Prod, 2020, 263: 121384.

    [91] [91] AUSTIN S A, AL-KINDY A A. Air permeability versus sorptivity: Effects of field curing on cover concrete after one year of field exposure[J]. Mag Concr Res, 2000, 52(1): 17-24.

    [92] [92] ALEXANDER M G, MAGEE B J. Durability performance of concrete containing condensed silica fume[J]. Cem Concr Res, 1999, 29(6): 917-922.

    [93] [93] KARAGIANNIS N, KAROGLOU M, BAKOLAS A, et al. Effect of temperature on water capillary rise coefficient of building materials[J]. Build Environ, 2016, 106: 402-408.

    [94] [94] KUBISSA W, PACEWSKA B, WILISKA I. Comparative investigations of some properties related to durability of cement concretes containing different fly ashes[J]. Adv Mater Res, 2014, 1054: 154-161.

    [95] [95] LIU X M, CHIA K S, ZHANG M H. Water absorption, permeability, and resistance to chloride-ion penetration of lightweight aggregate concrete[J]. Constr Build Mater, 2011, 25(1): 335-343.

    [96] [96] NATH P, SARKER P. Effect of fly ash on the durability properties of high strength concrete[J]. Procedia Eng, 2011, 14: 1149-1156.

    [97] [97] LO T Y, CUI H Z, NADEEM A, et al. The effects of air content on permeability of lightweight concrete[J]. Cem Concr Res, 2006, 36(10): 1874-1878.

    [98] [98] ELIK Z, BINGL A F, ASU A S. Fresh, mechanical, sorptivity and rapid chloride permeability properties of self-compacting concrete with silica fume and fly ash[J]. Iran J Sci Technol Trans Civ Eng, 2022, 46(2): 789-799.

    [99] [99] SIDDIQUE R. Compressive strength, water absorption, sorptivity, abrasion resistance and permeability of self-compacting concrete containing coal bottom ash[J]. Constr Build Mater, 2013, 47: 1444-1450.

    [100] [100] SHAH V, MACKECHNIE J, SCOTT A. Determination of carbonation resistance of concrete through a combination of cement content and tortuosity[J]. J Build Eng, 2022, 60: 105176.

    [101] [101] BENTUR A, JAEGERMANN C. Effect of curing and composition on the properties of the outer skin of concrete[J]. J Mater Civ Eng, 1991, 3(4): 252-262.

    [102] [102] AMINI K, VOSOUGHI P, CEYLAN H, et al. Effect of mixture proportions on concrete performance[J]. Constr Build Mater, 2019, 212: 77-84.

    [103] [103] MAJHI R K, NAYAK A N. Bond, durability and microstructural characteristics of ground granulated blast furnace slag based recycled aggregate concrete[J]. Constr Build Mater, 2019, 212: 578-595.

    [104] [104] MUDULI R, MUKHARJEE B B. Performance assessment of concrete incorporating recycled coarse aggregates and metakaolin: A systematic approach[J]. Constr Build Mater, 2020, 233: 117223.

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    GUO Xinzhi, ZHANG Yun, ZENG Qiang, WANG Zhendi, HONG Shuxian, WANG Zuqi, ZHOU Chunsheng. A Review on the Physics of Capillary Absorption and on the Significance of Capillary Sorptivity for Cement-Based Materials[J]. Journal of the Chinese Ceramic Society, 2025, 53(5): 1369

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    Paper Information

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    Received: Nov. 24, 2024

    Accepted: May. 29, 2025

    Published Online: May. 29, 2025

    The Author Email:

    DOI:10.14062/j.issn.0454-5648.20240750

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