Journal of Semiconductors, Volume. 45, Issue 12, 122402(2024)

Self-powered PEDOT:PSS/Sn:α-Ga2O3 heterojunction UV photodetector via organic/inorganic hybrid ink engineering

Yifan Yao, Suhao Yao, Jiaqing Yuan, Zeng Liu, Maolin Zhang, Lili Yang*, and Weihua Tang**
Author Affiliations
  • Innovation Center of Gallium Oxide Semiconductor (IC-GAO), College of Integrated Circuit Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023, China
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    Figures & Tables(9)
    (Color online) (a) Experimental procedures of the Mist-CVD. (b) Fabrication process of the HJD−PD.
    (Color online) Optical absorbance spectra of (a) PEDOT:PSS film and (b) Sn:α-Ga2O3 film (the inset calculates the Eg of the Sn:α-Ga2O3 film). (c) XRD pattern of Sn:α-Ga2O3.
    (Color online) (a) Surface of the Sn:α-Ga2O3 thin film and (b) interface of Sn:α-Ga2O3 and PEDOT:PSS. (c) Cross-section SEM photograph at the interface of PEDOT:PSS and Sn:α-Ga2O3.
    (Color online) (a) The XPS spectrum of the sample of the Sn:α-Ga2O3 film. (b) The high-resolution XPS spectrum of the Ga 2p1/2 and Ga 2p3/2. (c) The high-resolution XPS spectrum of the O 1s. (d) The UPS spectrum of the Sn:α-Ga2O3 film.
    (Color online) Logarithmic coordinate I−V curve of (a) HJD (the inset is the linear coordinate I−V curve) and (b) Sn:α-Ga2O3 PD. (c) R, (d) EQE, (e) D*, and (f) the functional relationship between the Iph and light intensity (the inset is the relationships at different devices and bias).
    (Color online) I−t curves of the HJD under different light intensities and different biases, (a) 0 V, (b) −5 V, and (c) 5 V. (d) I−t curves of the Sn:α-Ga2O3 PD under different light intensities and 5 V bias.
    (Color online) Fitted curve of the current rise and decay processes responding to 254 nm light of HJD under (a) 0 V, (b) −5 V, and (c) 5 V. (d) Sn:α-Ga2O3 PD under 5 V bias.
    (Color online) Schematic energy band diagrams of the PEDOT:PSS/Sn:α-Ga2O3 hybrid heterojunction under (a) before contact, (b) dark, and (c) ultraviolet illumination at 0 V bias.
    • Table 1. Performance comparison of Ga2O3-based heterojunction PDs.

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      Table 1. Performance comparison of Ga2O3-based heterojunction PDs.

      PhotodetectorTechnologyDeviceId (A)R (mA/W)D* (Jones)τr/τd (s)Ref.
      PEDOT:PSS/Sn:α-Ga2O3Mist-CVDHJD@0 V7.06 × 10−115.61.14 × 10110.36/0.09this work
      PEDOT:PSS/Ga2O3NWs/n-SiCVDHJD@0 V1 × 10−1026.81.4 × 10120.017/0.038[46]
      Ga2O3/Bi2WO6MOCVDHJD@0 V6.3 × 10−152.210.132/0.069[47]
      Spiro/Ga2O3/SiMOCVDHJD@0 V4.330.03/0.196[48]
      β-Ga2O3 nanoflakes/p-SiHYDROTHERMALHJD@0 V2.33 × 10−90.16[49]
      MoS2/β-Ga2O3HJD@0 V9 × 10−132.051.21 × 1011[50]
      PEDOT: PSS/Ga2O3 microwireEFGHJD@0 V39.82.4 × 10125.3 × 10−4/6.75 × 10−3[25]
      PEDOT:PSS/ Ga2O3MOCVDHJD@0 V3.7 × 10−1237.49.2 × 10123.3 × 10−6/7.12 × 10−5[51]
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    Yifan Yao, Suhao Yao, Jiaqing Yuan, Zeng Liu, Maolin Zhang, Lili Yang, Weihua Tang. Self-powered PEDOT:PSS/Sn:α-Ga2O3 heterojunction UV photodetector via organic/inorganic hybrid ink engineering[J]. Journal of Semiconductors, 2024, 45(12): 122402

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    Paper Information

    Category: Research Articles

    Received: Jun. 13, 2024

    Accepted: --

    Published Online: Jan. 15, 2025

    The Author Email: Lili Yang (LLYang), Weihua Tang (WHTang)

    DOI:10.1088/1674-4926/24050048

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