Acta Optica Sinica, Volume. 44, Issue 21, 2112003(2024)

Experimental System Design and Research on In‐Situ Rapid Detection of Benzene Series Fluorescence in Groundwater in Chemical Parks

Jinsong Chen1,2,3, Ruifang Yang2,3、*, Nanjing Zhao2,3、**, Gaofang Yin2,3, Peng Huang2, Yuxi Jiang1,2,3, Ming Gao2,3,4, Hengxin Song2,3,5, Liang Wang2,3,5, and Xiaowei Chen2
Author Affiliations
  • 1University of Science and Technology of China, Hefei 230026, Anhui , China
  • 2Anhui Institute of Optics and Fine Mechanics, Hefei Institutes of Physical Sciences, Chinese Academy of Sciences, Key Laboratory of Environmental Optics and Technology, Chinese Academy of Sciences, Hefei 230031, Anhui , China
  • 3State Environmental Protection Key Laboratory of Optical Monitoring Technology, Hefei 230031, Anhui , China
  • 4Institute of Physical Science and Information Technology, Anhui University, Hefei 230601, Anhui , China
  • 5School of Biology, Food and Environment, Hefei University, Hefei 230601, Anhui , China
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    Figures & Tables(16)
    Experimental system design
    Three-dimensional fluorescent spectra of eight monoaromatic hydrocarbons. (a) Benzene, 1 mg·L-1; (b) toluene, 100 μg·L-1; (c) ethylbenzene, 1 mg·L-1; (d) o-xylene, 2 mg·L-1; (e) m-xylene, 500 μg·L-1; (f) p-xylene, 500 μg·L-1; (g) styrene, 500 μg·L-1
    Appearance and its spectral curve of 255 nm UV light source. (a) Appearance; (b) spectral curve
    Hamamatsu H10721-210 and its response characteristic curve. (a) Appearance; (b) response characteristic curve
    Transmission curves of filter. (a) 255 nm filter; (b) LED with 255 nm filter; (c) 292 nm filter
    Fluorescence excitation-collection orthogonal light path
    Fluorescence excitation light path
    Fluorescence reception light path
    Physical diagrams of fluorescence signal detection circuits
    Experimental system
    Linear relationship between fluorescence signal and mass concentration of seven benzene series. (a) Benzene; (b) toluene,
    Fluorescence values of seven benzene series test samples. (a) Benzene; (b) toluene; (c) ethylbenzene; (d) o-xylene; (e) m-xylene; (f) p-xylene; (g) styrene
    • Table 1. Main reagents needed for experiment

      View table

      Table 1. Main reagents needed for experiment

      Chemical agentMolecular formulaPurityProduction company
      BenzeneC6H6AR: ≥99.5%Shanghai Aladdin Biochemical Technology Co., Ltd
      TolueneC7H8GC: ≥99.5%Sinopharm Chemical Reagent Co., Ltd
      EthylbenzeneC8H10AR: ≥99%Shanghai Aladdin Biochemical Technology Co., Ltd
      O-xyleneC8H10GC: ≥99%Shanghai Aladdin Biochemical Technology Co., Ltd
      M-xyleneC8H10GC: ≥99%Shanghai Aladdin Biochemical Technology Co., Ltd
      P-xyleneC8H10GC: ≥99%Shanghai Aladdin Biochemical Technology Co., Ltd
      StyreneC8H8GC: ≥99.9%Shanghai Aladdin Biochemical Technology Co., Ltd
    • Table 2. Linear regression equations, correlation coefficients, and detection limits of target benzene series

      View table

      Table 2. Linear regression equations, correlation coefficients, and detection limits of target benzene series

      BTEXLinear equation

      Fitting

      factor R2

      LOD /

      (mg·L-1

      Benzeney=403.8x-171.10.97540.14
      Tolueney=922.9x+5747.20.97910.11
      M-xyleney=411.1x-869.70.96340.21
      O-xyleney=1003.4x-730.10.99120.31
      Ethylbenzeney=725.4x-210.80.97080.26
      P-xyleney=7729.5x+525.10.98930.05
      Styreney=6138.9x+239.10.98170.08
    • Table 3. Average relative error, repeatability, and stability of target benzene series tested by experimental system

      View table

      Table 3. Average relative error, repeatability, and stability of target benzene series tested by experimental system

      BTEXAverage relative error /%DRSRSD /%
      Benzene9.30.087.5
      Toluene6.10.065.2
      Ethylbenzene8.80.086.3
      O-xylene8.30.076.5
      M-xylene8.60.077.0
      Paraxylene6.20.044.4
      Styrene7.10.065.6
    • Table 4. Mean relative error, repeatability, and stability of target benzene series tested by Hitachi F-7000

      View table

      Table 4. Mean relative error, repeatability, and stability of target benzene series tested by Hitachi F-7000

      BTEXAverage relative error /%DRSRSD /%
      Benzene7.50.108.8
      Toluene8.30.054.7
      Ethylbenzene9.70.119.3
      O-xylene9.20.066.9
      M-xylene8.40.087.4
      Paraxylene7.10.022.9
      Styrene5.30.076.3
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    Jinsong Chen, Ruifang Yang, Nanjing Zhao, Gaofang Yin, Peng Huang, Yuxi Jiang, Ming Gao, Hengxin Song, Liang Wang, Xiaowei Chen. Experimental System Design and Research on In‐Situ Rapid Detection of Benzene Series Fluorescence in Groundwater in Chemical Parks[J]. Acta Optica Sinica, 2024, 44(21): 2112003

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    Paper Information

    Category: Instrumentation, Measurement and Metrology

    Received: Apr. 7, 2024

    Accepted: May. 27, 2024

    Published Online: Nov. 19, 2024

    The Author Email: Yang Ruifang (rfyang@aiofm.ac.cn), Zhao Nanjing (njzhao@aiofm.ac.cn)

    DOI:10.3788/AOS240815

    CSTR:32393.14.AOS240815

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