Chinese Optics Letters, Volume. 13, Issue 4, 042301(2015)

Synthesis and properties of novel blue-emitting materials: anthracene-based derivatives

Gang Shi*, Jinguo Wang, Chunlong Xu, Xiaoting Li, and Zhen Wang
Author Affiliations
  • School of Science, Chang’an University, Xi’an 710064, China
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    Figures & Tables(8)
    UV–vis (L) and PL (R) spectra of β-ADN-2-PBD, β-ADN-2-TAZ, and ADN.
    TGA and DSC traces of β-ADN-2-PBD and β-ADN-2-TAZ
    I-V curves of β-ADN-2-PBD and β-ADN-2-TAZ.
    SEM images of (a) ADN, (b) β-ADN-2-PBD and (c) β-ADN-2-TAZ.
    Synthesis routes of two intermediates.
    Synthesis routes of two compounds.
    • Table 1. Photophysical and Thermal Properties of ADN, β-ADN-2-PBD, and β-ADN-2-TAZ

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      Table 1. Photophysical and Thermal Properties of ADN, β-ADN-2-PBD, and β-ADN-2-TAZ

       Absorption (nm)PLb(nm)  
      CompoundssolutionafilmsolutionfilmΦfcTg/dTm/dTde (°C)
      ADNf234, 257, 357, 375, 396––430––0.80––/388/397
      β-ADN-2-PBD236, 261, 328, 369, 388, 409239, 263, 330, 370, 388, 4104444560.87––/334/440
      β-ADN-2-TAZ237, 266, 322, 369, 388, 409240, 268, 325, 370, 389, 4104414541.12175/>350/459
    • Table 2. Electrochemical Properties of ADN, β-ADN-2-PBD, and β-ADN-2-TAZ

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      Table 2. Electrochemical Properties of ADN, β-ADN-2-PBD, and β-ADN-2-TAZ

      CompoundEox(V)λON(nm)Eg(eV)EHOMO(eV)ELUMO(eV)
      ADNa––4202.955.602.65
      β-ADN-2-PBD0.814302.885.612.73
      β-ADN-2-TAZ0.744292.895.542.65
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    Gang Shi, Jinguo Wang, Chunlong Xu, Xiaoting Li, Zhen Wang, "Synthesis and properties of novel blue-emitting materials: anthracene-based derivatives," Chin. Opt. Lett. 13, 042301 (2015)

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    Paper Information

    Category: Optical devices

    Received: Jan. 6, 2015

    Accepted: Feb. 12, 2015

    Published Online: Sep. 25, 2018

    The Author Email: Gang Shi (shigang_xa@126.com)

    DOI:10.3788/COL201513.042301

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