Acta Physica Sinica, Volume. 69, Issue 12, 127703-1(2020)

Dielectric, ferroelectric and high energy storage behavior of (1–x)K0.5Na0.5NbO3–xBi(Mg0.5Ti0.5)O3 lead free relaxor ferroelectric ceramics

Jin-Hua Du1,2,3, Yong Li1,2, Ning-Ning Sun1,2, Ye Zhao1,2, and Xi-Hong Hao1,2、*
Author Affiliations
  • 1Inner Mongolia Key Laboratory of Ferroelectric-related New Energy Materials and Devices, Inner Mongolia University of Science and Technology, Baotou 014010, China
  • 2Industrial Technology Research Institute, Inner Mongolia University of Science and Technology, Baotou 014010, China
  • 3School of Chemistry and Chemical Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China
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    Figures & Tables(10)
    Schematic diagram showing the increase of Wrec through decreasing the grain size by doping BMT in KNN ceramics.
    Circuit diagram of direct test system.
    XRD patterns of (1–x)KNN-xBMT ceramics.
    SEM images of the (1–x)KNN-xBMT ceramics with their grain size distribution and average grain size inserted: (a) x = 0.05; (b) x = 0.10; (c) x = 0.15; (d) x = 0.20.
    (a) Dielectric constant as a function of temperature in a temperature range of –150 ℃ to 300 ℃ for (1 – x)KNN-xBMT ceramics and 25 ℃ to 500 ℃ for pure KNN ceramics; (b) plots of ln(1/εr–1/εm) versus ln(T–Tm) of the (1–x)KNN-xBMT ceramics.
    P-E loop and I-E curves under 60 kV·cm–1 electric field of the (1–x)KNN-xBMT ceramics: (a) x = 0; (b) x = 0.05; (c) x = 0.10; (d) x = 0.15; (e) x = 0.20.
    (a) P-E loops, (b) Wrec and η of (1–x)KNN-xBMT ceramics at the maximum applied electric fields; (c) P-E loops, (d) Wrec and η of (1–x)KNN-xBMT ceramics under 200 kV·cm–1 electric fields.
    (a) P-E loops and (b) Wrec and η under different electric fields, (c) P-E loops and (d) Wrec and η at different frequencies, (e) P-E loops and (f) Wrec and η at different temperatures of 0.85KNN-0.15BMT ceramics.
    (a) Pulsed discharge current curves, (b) discharge energy density Wdis and discharge time t90, and (c) comparative figures of Wdis and Wrec under breakdown electric field of the (1–x)KNN-xBMT ceramics; (d) pulsed discharge current curves, (e) discharge energy density Wdis, and (f) the comparative figures of Wdis and Wrec under different electric fields of the 0.85KNN-0.15BMT ceramic
    • Table 1.

      Comparison of energy storage properties of 0.85 KNN-0.15 BMT ceramics and other lead-free ceramics.

      0.85 KNN-0.15 BMT陶瓷与其他部分无铅陶瓷储能性能的比较

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      Table 1.

      Comparison of energy storage properties of 0.85 KNN-0.15 BMT ceramics and other lead-free ceramics.

      0.85 KNN-0.15 BMT陶瓷与其他部分无铅陶瓷储能性能的比较

      Material systermWrec/J·cm–3η/% BDS /kV·cm–1Wdis/J·cm–3t90/ns Reference
      0.88BT-0.12BMT1.8188224[20]
      0.85BT-0.15BY0.50100[22]
      0.61BF-0.33BT-0.06BMN1.5675125[24]
      0.7BNT-0.3ST + 0.05MnO20.9674.695[25]
      0.8KNN-0.2SSN2.0281.4295[31]
      0.85KNN-0.15ST4.0352400[32]
      0.85KNN-0.15BMT2.25842751.5488This work
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    Jin-Hua Du, Yong Li, Ning-Ning Sun, Ye Zhao, Xi-Hong Hao. Dielectric, ferroelectric and high energy storage behavior of (1–x)K0.5Na0.5NbO3–xBi(Mg0.5Ti0.5)O3 lead free relaxor ferroelectric ceramics [J]. Acta Physica Sinica, 2020, 69(12): 127703-1

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    Paper Information

    Received: Feb. 12, 2020

    Accepted: --

    Published Online: Dec. 8, 2020

    The Author Email:

    DOI:10.7498/aps.69.20200213

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