Spectroscopy and Spectral Analysis, Volume. 41, Issue 11, 3618(2021)

Analysis and Evaluation of Inorganic Elements in Salvia miltiorrhiza and Rhizosphere Soils From Different Areas

Qin-rong LIU1、*, Zi-wei DU1、1;, Jia-zhen LI1、1;, Yi-shuo WANG1、1; 3; *;, Xuan GU2、2;, and Xiu-mei CUI2、2;
Author Affiliations
  • 11. School of Pharmacy, Henan University of Chinese Medicine, Zhengzhou 450046, China
  • 22. Beijing Huamiao Pharmaceutical Co., Ltd., Beijing 102600, China
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    Figures & Tables(14)
    Cluster analysis of inorganic elements in Salvia miltiorrhiza
    Score scatter
    PLS-DA model
    VIP plot
    • Table 1. Sample information

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      Table 1. Sample information

      编号产地品种生长年限土壤质地土壤类型
      S1河南确山栽培1年砂壤黄褐土
      S2河南方城栽培1年砂壤黄褐土
      S3河南方城栽培1年砂壤黄褐土
      S4陕西丹凤栽培1年砂壤褐土
      S5陕西丹凤栽培1年砂壤褐土
      S6四川中江栽培1年黏壤红褐土
      S7四川中江栽培1年黏壤红褐土
      S8山东诸城栽培1年砂壤棕壤土
      S9山东莒县栽培1年砂壤棕壤土
      S10山东临朐栽培1年砂壤棕壤土
      S11山西万荣栽培1年粉土黄棕土
      S12山西襄汾栽培1年粉土黄棕土
    • Table 2. Using parameters of atomic absorption spectrometer

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      Table 2. Using parameters of atomic absorption spectrometer

      元素波长/nm狭缝/nm灯电流/mA光电倍增管负高压/V乙炔流量/(L·min-1)乙炔压力/MPa燃气高度/mm
      Na589.00.410.0330/2352.00.067.5
      Mg285.21.37.5330/1722.00.0512.5
      K766.51.310.0380/2542.20.057.5
      Ca422.71.37.5560/2432.20.057.5
      Mn279.50.47.5400/3092.00.067.5
      Fe248.30.212.5400/4271.80.057.5
      Cu324.81.37.5330/2432.00.057.5
      Zn213.91.35.0430/3171.80.057.5
    • Table 3. Operating parameters of microwave digestion instrument

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      Table 3. Operating parameters of microwave digestion instrument

      程序时间/min功率/W温度/℃压力/atm
      15.080012010.0
      210.080015020.0
      330.080020030.0
    • Table 4. Linear regression equation and detection limit

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      Table 4. Linear regression equation and detection limit

      元素线性方程线性范围/(mg·L-1)相关系数r2检出限/(mg·L-1)
      Nay=2.62×10-2x+1.38×10-40~5.00.999 70.014 3
      Mgy=3.13×10-1x+3.83×10-30~0.50.999 10.090 2
      Ky=0.070 2x+0.027 30~100.998 10.041 5
      Cay=0.048 2x+0.025 10~100.997 80.069 8
      Mny=0.074 1x-0.000 50~0.90.999 90.001 1
      Fey=3.58×10-2x+6.33×10-30~100.999 40.030 2
      Cuy=0.028 5x-0.000 10~0.50.999 40.001 1
      Zny=2.41×10-1x+2.71×10-30~1.00.999 80.036 8
    • Table 5. Content of inorganic elements in Salvia miltiorrhiza

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      Table 5. Content of inorganic elements in Salvia miltiorrhiza

      编号NaMgKCaMnFeCuZn
      S11.8080.4895.1151.4880.0610.2080.0170.023
      S21.3140.2226.5341.9330.0920.1410.0150.038
      S31.2440.4946.2941.5960.0720.1500.0160.043
      S42.8540.4076.8221.9210.7650.7930.0650.016
      S53.1940.3556.7542.5610.6880.6650.0670.016
      S61.2751.5879.1443.8560.1342.3900.0490.065
      S71.4161.8739.6373.5160.2142.5800.0550.055
      S84.7340.6364.6601.5021.2591.1890.0760.064
      S94.6640.0884.5631.4551.2581.1570.0740.059
      S105.1920.6174.4391.4421.2521.1070.0660.046
      S115.8732.3534.4962.2860.0270.6790.0220.026
      S126.0032.6004.3512.7060.0260.5920.0240.022
    • Table 6. Content of inorganic elements in root soil

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      Table 6. Content of inorganic elements in root soil

      编号NaMgKCaMnFeCuZn
      T-S152.8361.67613.5291.68615.24219.9480.0220.141
      T-S260.1831.67913.6811.44613.49320.9390.0210.140
      T-S359.6501.55714.5571.55912.26820.2390.0220.143
      T-S459.8571.06613.8864.27916.02021.4550.0800.156
      T-S559.7691.07013.7774.21615.63821.2500.0820.155
      T-S654.6522.91516.6543.94610.24927.4720.0710.021
      T-S755.2702.15216.4042.95810.23928.6940.0610.026
      T-S859.8091.65914.0511.36216.26720.4391.0560.145D
      T-S961.0551.42514.2821.42617.66622.2610.0550.144
      T-S1060.9911.48614.0641.24217.18222.3660.0450.161
      T-S1157.6812.35714.6553.35010.69415.6680.0210.029
      T-S1259.1322.58915.1083.12510.52819.8280.0210.031
    • Table 7. Correlation analysis of elements between soil and medicinal

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      Table 7. Correlation analysis of elements between soil and medicinal

      编号T-NaT-MgT-KT-CaT-MnT-FeT-CuT-Zn
      Na0.4530.055-0.204-0.0440.211-0.527-0.138-0.071
      Mg-0.3670.832**0.664*0.413-0.812**0.021-0.242-0.925**
      K-0.4520.2300.650*0.473-0.4650.805**0.497-0.361
      Ca-0.4940.678*0.858**0.680*-0.752**0.623*0.340-0.806**
      Mn0.585*-0.565-0.352-0.2840.830**0.0580.5040.586*
      Fe-0.3460.4490.816**0.292-0.2950.833**0.571-0.539
      Cu0.347-0.3780.0130.1200.5730.3860.829**0.285
      Zn-0.0310.2990.489-0.427-0.0220.5620.154-0.149
    • Table 8. The characteristics of the principal component value and contribution

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      Table 8. The characteristics of the principal component value and contribution

      成分初始特征值提取载荷平方和旋转载荷平方和
      总计方差百分比累积/%总计方差百分比累积/%总计方差百分比累积/%
      12.73834.22034.2202.73834.22034.2202.62532.81732.817
      22.23127.88762.1082.23127.88762.1082.12026.50459.321
      31.75621.95184.0581.75621.95184.0581.97924.73784.058
      40.88411.05595.113
      50.2172.70997.822
      60.1461.82499.646
      70.0170.21699.863
      800.137100.000
    • Table 9. The initial factor loading matrix

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      Table 9. The initial factor loading matrix

      元素成分1成分2成分3
      Na0.1180.8580.437
      Mg-0.517-0.0620.722
      K0.4350.6520.401
      Ca-0.076-0.4880.693
      Mn0.5540.6530.335
      Fe0.835-0.4320.277
      Cu0.854-0.4560.106
      Zn0.727-0.089-0.032
    • Table 10. Principal component score and comprehensive score of S. miltiorrhiza

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      Table 10. Principal component score and comprehensive score of S. miltiorrhiza

      样品主成分1
      得分
      主成分2
      得分
      主成分3
      得分
      综合得分
      S1-2.006 6-1.162 0-0.383 7-1.302 6
      S2-1.685 1-0.599 4-0.796 1-1.092 8
      S3-1.539 1-0.474 7-1.266 8-1.114 9
      S4-0.511 0-0.007 5-1.410 0-0.578 7
      S5-0.653 9-0.188 0-0.810 1-0.540 1
      S62.450 6-1.982 3-0.285 80.265 4
      S71.664 3-2.691 61.757 60.243 5
      S81.925 61.236 70.139 21.230 6
      S91.355 71.275 2-0.804 60.764 9
      S101.582 72.411 8-0.567 81.296 2
      S11-1.173 11.257 71.820 10.415 0
      S12-1.410 30.924 12.607 90.413 5
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    Qin-rong LIU, Zi-wei DU, Jia-zhen LI, Yi-shuo WANG, Xuan GU, Xiu-mei CUI. Analysis and Evaluation of Inorganic Elements in Salvia miltiorrhiza and Rhizosphere Soils From Different Areas[J]. Spectroscopy and Spectral Analysis, 2021, 41(11): 3618

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    Paper Information

    Category: Orginal Article

    Received: May. 27, 2021

    Accepted: --

    Published Online: Dec. 17, 2021

    The Author Email: LIU Qin-rong (qinr1106@163.com)

    DOI:10.3964/j.issn.1000-0593(2021)11-3618-07

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