Journal of Inorganic Materials, Volume. 40, Issue 7, 735(2025)

Research Progress on Catalytic Oxidation of Volatile Organic Compounds by Perovskite Oxides

Wenjie ZHU1,2,3, Lu TANG1,2,3, Jichang LU1,2,3, Jiangping LIU1,2,3, and Yongming LUO2,3,4
Author Affiliations
  • 11. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China
  • 22. Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, Kunming 650500, China
  • 33. Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province, Kunming 650500, China
  • 44. Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China
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    Figures & Tables(11)
    Design strategies for perovskite oxides
    Catalytic oxidation of CO and toluene by multi-shelled spherical PrMnO3 perovskite[20]
    Water and sulfur resistance over LaFe0.8Cu0.2O3 in the temperature range of 100-600 ℃[25]
    Selective dissolution technique combined with Cu-doping modified LaMnO3 catalyst[37]
    Activity and stability tests of LaFeO3 (LxFO) with A-site cation deficiency in catalytic oxidation of toluene[46]
    Structure and characterization of LaxFeO3 (x=1.03, 1, 0.97) perovskite[47]
    Schematic diagrams of (a) MvK mechanism, (b) L-H mechanism and (c) E-R mechanism[62]
    Isothermal C16O oxidation reaction on perovskite with time-resolved isotopic 18O2[67]
    Comparison between experimental and simulated data for the LH-OS-ND model[69]
    • Table 1. A- and B-sites doped perovskite catalysts and their application in catalytic oxidation of VOCs

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      Table 1. A- and B-sites doped perovskite catalysts and their application in catalytic oxidation of VOCs

      CatalystVOCsρVOCs/(mg·L-1) aGHSV/(mL·g-1·h-1) Preparation methodbT50/℃ cT90/℃ dR/(mol·g-1·s-1) Ref.
      La0.95Ce0.05CoO3Chlorobenzene460560000Reactive grinding method3774341.083×10-3 (200 ℃)[31]
      Sol-Gel method3134256.775×10-9 (200 ℃)
      La0.9Ce0.1MnO3Styrene1278025000Sol-Gel method306328-[38]
      LaFe0.8Cu0.2O3Acrylonitrile6512120000Sol-Gel method-250-[25]
      LaFe0.8Co0.2O3Propylene172260000Sol-Gel method293345-[24]
      LaMn0.8Cu0.2O3Formaldehyde36812000Sol-Gel method138168-[39]
      LaMn0.8Ni0.2O3143200
      LaMn0.8Zn0.2O3146200
      LaMn0.7Mg0.3O3Methane32850000Sol-Gel method4504956.90×10-7 (400 ℃)[40]
      La0.5Sr0.5Co0.8Fe0.2O3Toluene377030000Sol-Gel method2512708.43×10-8 (230 ℃)[36]
      La0.8Ce0.2Mn0.8Ni0.2O3Trichloroethylene80610000Sol-Gel method310379-[35]
      La0.8Ce0.2Mn0.8Ni0.2O3Toluene377018000Sol-Gel method260295-[34]
      La0.9Sr0.1Co0.9Mn0.1O3Benzene639030000PMMA template method272328-[18]
    • Table 2. Perovskite-based supported catalysts and their application in catalytic oxidation of VOCs

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      Table 2. Perovskite-based supported catalysts and their application in catalytic oxidation of VOCs

      CatalystVOCsρVOCs/(mg·L−1) aGHSV/(mL·g−1·h−1) bT50/℃ cT90/℃ dRRef.
      Ag/LaCoO3-250Toluene3770300002312394.19×10−9 mol·m−2·s−1(225 ℃)[53]
      Ag/LaCoO3-4502602783.09×10−9 mol·m−2·s−1(225 ℃)
      Ag/LaCoO3-7002522673.44×10−9 mol·m−2·s−1(225 ℃)
      LaMnO3/CeO21,2-Dichloropropane462215000171260-[54]
      LaMnO3/Al2O3178243
      LaMnO3/TiO2183249
      LaMnO3/YSZ189243
      2%(in mass)Pd@N-L0.8S0.2MOToluene18836000-1669.61×10−9  mol·g−1·s−1(105 ℃)[56]
      20%(in mass)LaCoO3/Ce0.9Zr0.1O2Toluene640660000200-1.6×10−6 mol·g−1·s−1(300 ℃)[58]
      NiMnO3/CexZr1-xO2/cordieriteBenzene183415000-275 (eT95)-[59]
      CeO2-LaCo0.25Fe0.75O3Toluene377018000150205-[60]
      CeO2-LaMn0.25Fe0.75O3155215
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    Wenjie ZHU, Lu TANG, Jichang LU, Jiangping LIU, Yongming LUO. Research Progress on Catalytic Oxidation of Volatile Organic Compounds by Perovskite Oxides[J]. Journal of Inorganic Materials, 2025, 40(7): 735

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    Paper Information

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    Received: Jul. 16, 2024

    Accepted: --

    Published Online: Sep. 3, 2025

    The Author Email:

    DOI:10.15541/jim20240333

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