Chinese Journal of Lasers, Volume. 52, Issue 17, 1711003(2025)

Influence Law of Methanol Intermediate Solvent on Fluorescence Spectrum Detection of Benzene Series Compounds

Wen Li1,2, Anni Li1、*, Zhuofan Yu1, Xueke Luo3, and Sijia Hao1
Author Affiliations
  • 1Electromechanical Research Institute, School of Mechanical and Materials Engineering, North China University of Technology, Beijing 100144, China
  • 2Sanmen Nuclear Power Co., Ltd., Taizhou 355199, Zhejiang , China
  • 3Beijing Institute of Petrochemical Technology, Beijing 102617, China
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    Figures & Tables(13)
    Experimental detection device for methanol fluorescence spectrum
    Physical drawing of experimental testing platform for two-dimensional fluorescence spectrum
    Fluorescence measurement of solution
    Schematic diagram of molecular energy level transition
    Two-dimensional fluorescence spectra. (a) Pure water; (b) pure methanol
    Fluorescence spectra of benzene under different A and influence of B on fluorescence intensity of benzene. (a)(c)(e) Fluorescence spectra of benzene under different A; (b)(d)(f) influence of B on fluorescence intensity of benzene
    Fluorescence spectra of toluene under different C and influence of B on fluorescence intensity of toluene. (a)(c)(e) Fluorescence spectra of toluene under different C; (b)(d)(f) influence of B on fluorescence intensity of toluene
    Comparison of fluorescence spectra. (a) Pure benzene solution with mass concentration of 200 mg/L; (b) benzene methanol-water solution with mass concentration of 200 mg/L when B is 15%‒90%; (c) pure toluene solution with mass concentration of 20 mg/L; (d) toluene methanol-water solution with mass concentration of 20 mg/L when B is 5%‒90%
    Spectral repeatability plots of benzene under different mass concentrations
    Spectral repeatability plots of toluene under different mass concentrations
    Schematic diagrams of benzene molecule surrounded by methanol. (a) Three-dimensional; (b) two-dimensional
    Influence of methanol volume fraction on the fluorescence quenching effect. (a) Benzene solution with mass concentration of 200 mg/L; (b) toluene solution with mass concentration of 40 mg/L
    • Table 1. Statistical results of repeatability validation of benzene and toluene solutions

      View table

      Table 1. Statistical results of repeatability validation of benzene and toluene solutions

      SolutionMass concentration /(mg/L)Methanol volume fraction /%SDRSD /%
      Benzene1006023.525851.28
      Benzene2006040.706891.35
      Benzene3006093.445221.88
      Toluene1538.002133.60
      Toluene20547.426922.80
      Toluene40565.661561.95
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    Wen Li, Anni Li, Zhuofan Yu, Xueke Luo, Sijia Hao. Influence Law of Methanol Intermediate Solvent on Fluorescence Spectrum Detection of Benzene Series Compounds[J]. Chinese Journal of Lasers, 2025, 52(17): 1711003

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    Paper Information

    Category: spectroscopy

    Received: Mar. 10, 2025

    Accepted: May. 6, 2025

    Published Online: Sep. 13, 2025

    The Author Email: Anni Li (1156701102@qq.com)

    DOI:10.3788/CJL250600

    CSTR:32183.14.CJL250600

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