Laser & Optoelectronics Progress, Volume. 58, Issue 14, 1404002(2021)

Highly Sensitive Detection of Copper Ions by Reduced Glutathione Modified Gold Nanocluster Fluorescence Sensor

Zhenping Liu*, Rong Jiang, and Kejing Pang
Author Affiliations
  • Chongqing Vocational Institute of Safety & Technology, Chongqing 404020, China
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    Figures & Tables(13)
    Principle of Cu2+ detection by GSH-AuNCs fluorescence sensor
    GSH-AuNCs transmission electron microscope image, illustrated with particle size distribution
    Infrared spectra of GSH-AuNCs
    Fluorescence spectra of GSH-AuNCs
    Relationship between GSH-AuNCs fluorescence intensity and Cu2+ concentration
    Fluorescence attenuation curves of GSH-AuNCs and GSH-AuNCs /Cu2+
    Fluorescence emission spectra of GSH-AuNCs under different wavelengths of excitation light
    Effect of pH on fluorescence intensity of GSH-AuNCs
    Effect of different Cu2+ concentrations on fluorescence intensity of GSH-AuNCs, embedded images a and b are the photos of GSH-AuNCs before and after fluorescence is quenched by Cu2+ under ultraviolet light
    Relationship between Cu2+ concentration and natural logarithm of GSH-AuNCs fluorescence intensity ratios before and after quenching
    Specificity analysis of fluorescence sensor
    • Table 1. Comparison with other detection methods

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      Table 1. Comparison with other detection methods

      MethodLOD /(nmol·L-1)Linear range /(nmol·L-1)Ref.
      Capillary electrophoresis microchip134.0603--15600[49]
      Colorogenic probe of rhodamine B derivative12.0100--6000[50]
      RGO-Au-ZIF-8 electrochemical sensor7.810--10000[51]
      Polypyrrole nanowire electrochemical detection20.020--300[52]
      ICT colorimetric chemosensor37.00--5000[12]
      Tb3+-functionalized metal-organic framework230.00--2×105[53]
      GSH-AuNCs fluorescent sensor7.416.7--5000.0This work
    • Table 2. Test results of Cu2+ in water samples

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      Table 2. Test results of Cu2+ in water samples

      No.Standard /(nmol·L-1)Test data /(nmol·L-1)Standard recovery rate /%RSD /%
      18086.3107.94.47
      2200213.4106.73.29
      3400389.697.42.41
      41000951.795.24.19
      520001858.392.95.69
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    Zhenping Liu, Rong Jiang, Kejing Pang. Highly Sensitive Detection of Copper Ions by Reduced Glutathione Modified Gold Nanocluster Fluorescence Sensor[J]. Laser & Optoelectronics Progress, 2021, 58(14): 1404002

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    Paper Information

    Category: Detectors

    Received: Oct. 19, 2020

    Accepted: Nov. 12, 2020

    Published Online: Jul. 6, 2021

    The Author Email: Zhenping Liu (nping305@126.com)

    DOI:10.3788/LOP202158.1404002

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