NUCLEAR TECHNIQUES, Volume. 48, Issue 5, 050302(2025)

Study on cesium adsorption behavior of mineral colloid in surrounding rock of cavern disposal repository

Guoyi LU1, Shuyu OUYANG1, Jian YANG3, Zehua LI1, Jinzhao ZHANG2, and Yangchun LENG1、*
Author Affiliations
  • 1School of Defense Science and Technology, Southwest University of Science and Technology, Mianyang 621010, China
  • 2Third Institute of Oceanography, Ministry of Natural Resource, Xiamen 361005, China
  • 3Fujian Ningde Nuclear Power Co., LTD, Fuding355200, China
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    Figures & Tables(13)
    XRD pattern of surrounding rock and SRM colloid in the repository (color online)
    FT-IR spectra of surrounding rock and SRM colloid in the repository (color online)
    SEM images of surrounding rock powder (a, b) and SRM colloid (c, d)
    Variations of Cs+ adsorption capacity by SRM colloid and Kd with contact time (T=293 K, C0=10 mg·L-1, pH=7)
    (a) Change of Zeta potential and particle size of SRM colloid with temperature, (b) Curves of Cs+ adsorption capacity by SRM colloid and Kd changing with temperature (t=720 min, C0=10 mg·L-1, pH=7)
    Isotherm fitting curves of Cs+ adsorption capacity by SRM colloid (t=720 min, T=293 K, pH=7) (color online)
    Changes of Zeta potential and particle size of SRM colloid with pH value (a), curves of Cs+ adsorption capacity by SRM colloid and Kd changing with pH value (b) (t=720 min, T=293 K, C0=10 mg·L-1)
    Effects of co-existing ions on Zeta potential (a) and particle size of SRM colloid (b) (t=720 min, T=293 K, C0=10 mg·L-1, pH=7)
    Effect of coexisting cations on Cs+ adsorption by SRM colloid (t=720 min, T=293 K, C0=10 mg·L-1, pH=7) (color online)
    • Table 1. Main chemical composition of surrounding rock of disposal depot

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      Table 1. Main chemical composition of surrounding rock of disposal depot

      化学成分 Chemical componentω / %
      SiO273.28
      Al2O311.12
      K2O9.13
      Fe2O33.17
      CaO1.49
      Na2O0.75
      TiO20.10
      MgO0.06
      其他Others0.9
    • Table 2. Kinetic parameters of Cs+ in SRM colloid

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      Table 2. Kinetic parameters of Cs+ in SRM colloid

      核素

      nuclide

      准一级动力学模型

      Quasi-first-order kinetic model

      准二级动力学模型

      Quasi-second-order kinetic model

      qeqmk1R2qmk2R2
      Cs+47.3146.1140.0660.94147.6190.002 880.999
    • Table 3. Thermodynamic parameters of Cs+ in SRM colloid

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      Table 3. Thermodynamic parameters of Cs+ in SRM colloid

      核素

      Nuclide

      / kJ·mol-1/ J·(mol·K-1)-1/ kJ·mol-1
      293 K313 K333 K
      Cs+-7.19219.197-12.816-13.200-13.584
    • Table 4. Parameters of isothermal adsorption model of Cs+ adsorbed by surrounding rock

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      Table 4. Parameters of isothermal adsorption model of Cs+ adsorbed by surrounding rock

      核素

      Nuclide

      Langmuir等温吸附模型

      Langmuir isothermal adsorption model

      Freundlich等温吸附模型

      Freundlich isotherm adsorption model

      qmKLR2KF1/nR2
      Cs+223.6810.3890.94211.8820.7070.912
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    Guoyi LU, Shuyu OUYANG, Jian YANG, Zehua LI, Jinzhao ZHANG, Yangchun LENG. Study on cesium adsorption behavior of mineral colloid in surrounding rock of cavern disposal repository[J]. NUCLEAR TECHNIQUES, 2025, 48(5): 050302

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    Paper Information

    Category: NUCLEAR CHEMISTRY, RADIOCHEMISTRY, RADIOPHARMACEUTICALS AND NUCLEAR MEDICINE

    Received: Sep. 23, 2024

    Accepted: --

    Published Online: Jun. 26, 2025

    The Author Email: Yangchun LENG (冷阳春)

    DOI:10.11889/j.0253-3219.2025.hjs.48.240389

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