In order to solve the problem that the single performance of homogeneous ceramic materials and structures limits their application，an additive manufacturing technology for the photocuring/spray deposition composite process is proposed from the perspective of the working mechanism and integration of polymorphic modules，including the whole machine，worktable，multi-axis motion module，laser and mirror module，spray module，sensing and valve module，and process module.A prototype of photocuring/spray deposition multi-material ceramic additive continuous forming equipment is built，and the multi-system collaborative motion process of “coating+solidification+spray+solidification” is studied to optimize the stability of multi-module motion.The combination logic of the multi-process composite technology is studied，and the multi-material CeraMulti Slicer software and CeraMulti Driver configuration software are developed.A collaborative motion mechanism and a high-precision integrated control system are developed for the photopolymerization forming motion mechanism and spray deposition module.The integrated preparation of forming control for multi-material ceramic parts is explored.The results indicate that this technology can prepare multi-material ceramic samples with high accuracy，good interface bonding，and no defects.