Chinese Optics Letters, Volume. 23, Issue 9, 091901(2025)

Ultrafast optical response and efficient wavelength conversion in epsilon-near-zero aluminum-doped zinc oxide thin films

Yuanyuan Gou, Yuan He, Tiantian Zhou, Yi Feng, Lili Miao, and Chujun Zhao*
Author Affiliations
  • Key Laboratory for Micro/Nano Optoelectronic Devices of Ministry of Education & Hunan Provincial Key Laboratory of Low-Dimensional Structural Physics and Devices, School of Physics and Electronics, Hunan University, Changsha 410082, China
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    Figures & Tables(8)
    (a) SEM image, (b) EDS pattern, (c) linear absorption spectrum, and (d) linear complex permittivity of the AZO film. The shaded part in (d) represents the ENZ region.
    (a) Transient absorption spectra of the AZO film with a 350 nm pump. (b) Extracted carrier time response parameters: fast decay time τ1 (red hexagons) and slow relaxation time τ2 (purple rhombuses) under various probe wavelengths. Temporal evolution of the optical density change (ΔmOD) at (c) 517 and (d) 600 nm probe wavelengths.
    (a) Open-aperture and (b) closed-aperture results of the AZO film at the ENZ wavelength under different incident intensities.
    Plot of ln(ΔT) as a function of ln(I).
    (a) β (red dots) and (b) n2 (purple quadrates) under different excitation wavelengths.
    Experimental setup for THG measurement.
    (a) THG spectra under diverse incident wavelengths. (b) THG spectra under various excitation intensities at 1550 nm. (c) Dependence of THG power and excitation power. (d) Calculated THG efficiency at different excitation wavelengths.
    • Table 1. Comparison of THG Efficiency Between the AZO Film and Other Materials

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      Table 1. Comparison of THG Efficiency Between the AZO Film and Other Materials

      Optical materialThickness (nm)Pump wavelength (nm)Pulse width, repetition rateIncident angleTHG efficiencyRef.
      Graphene0.331720.4320 fs, 81 MHzθ = 0°2 × 10−10[34]
      Silicon membrane2001550100 fs, —θ = 0°6 × 10−9[35]
      ITO nanolayer20124050–102 fs, 1 kHzθ = 0°2.5 × 10−8[36]
      ITO film33140050 fs, 100 kHzθ = 45°3.3 × 10−6[37]
      CdO: In/Au film75/200210060 fs, 1 kHzθ = 50°10−5[38]
      AZO film203155035 fs, 1 kHzθ = 0°0.63 × 10−6This work
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    Yuanyuan Gou, Yuan He, Tiantian Zhou, Yi Feng, Lili Miao, Chujun Zhao, "Ultrafast optical response and efficient wavelength conversion in epsilon-near-zero aluminum-doped zinc oxide thin films," Chin. Opt. Lett. 23, 091901 (2025)

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    Paper Information

    Category: Nonlinear Optics

    Received: Apr. 25, 2025

    Accepted: May. 21, 2025

    Published Online: Sep. 2, 2025

    The Author Email: Chujun Zhao (cjzhao@hnu.edu.cn)

    DOI:10.3788/COL202523.091901

    CSTR:32184.14.COL202523.091901

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