Acta Optica Sinica, Volume. 39, Issue 8, 0816002(2019)

Luminescence Properties and Energy Transfer Mechanism of Sr3P4O13∶Ce 3+,Tb 3+ Green Phosphors

Wanxin Mi, Lili Cao, Siqi Chu, and Hongping Ma*
Author Affiliations
  • School of Mechanical and Energy Engineering, Zhejiang University of Science and Technology, Hangzhou, Zhejiang 310012, China
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    Figures & Tables(10)
    XRD patterns of different samples. (a) Sr3(1-x)P4O13∶3xCe3+(x=0.02,0.04,0.06,0.08,0.10); (b) Sr3(0.92-y)P4O13∶0.24Ce3+,3yTb3+(y=0,0.01,0.03,0.05,0.07,0.09)
    Refined XRD of Sr3P4O13
    Morphology analysis of Sr3P4O13. (a) EDS; (b) SEM image; (c) TEM image; (d) crystal lattice stripe; (e) electron diffraction pattern
    PL and PLE spectra of samples. (a) PLE spectra of Sr2.76P4O13∶0.24Ce3+ and PL spectra of Sr3(1-x)P4O13∶3xCe3+(x=0.02,0.04,0.06,0.08,0.10); (b) PL spectrum of Sr3P4O13∶Ce3+ and PLE spectrum of Sr3P4O13∶Tb3+; (c) PL and PLE spectra of Sr2.61P4O13∶0.24Ce3+, 0.15Tb3+
    Relationship between PL spectra and doping mole fraction y of sample. (a) PL spectra of Sr3(0.92-y)P4O13∶0.24Ce3+,3yTb3+(y=0,0.01,0.03,0.05,0.07,0.09) samples. (b) influences of emission intensities of Ce3+ and Tb3+ on Tb3+ mole fraction y
    Color coordinate of Sr2.61P4O13∶0.24Ce3+,0.15Tb3+
    Decay curves and energy transfer efficiency of Sr3(0.92-y)P4O13∶0.24Ce3+,3yTb3+ (y=0,0.01,0.03,0.05,0.07,0.09) phosphors. (a) Decay curves of Ce3+ demonstrated on a logarithmic intensity scale; (b) relationship among fluorescence decay lifetime of Ce3+, energy transfer efficiency of Ce3+, and doping mole fraction of Tb3+
    Relationship between IS0/IS of Ce3+ and C. (a) n=3; (b) n=6; (c) n=8; (d) n=10
    Emission spectra of Sr2.61P4O13∶0.24Ce3+,0.15Tb3+ at different temperatures when λex=290 nm (inset shows emission intensities under different temperatures)
    • Table 1. Refined parameters of Sr3P4O13

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      Table 1. Refined parameters of Sr3P4O13

      ParameterDescription or value
      Crystal systemTriclinic
      Crystal density /(g·cm3)3.660
      Units, Z2
      a /nm0.72755
      b /nm0.77260
      c /nm1.01935
      V /nm30.5397
      α /(°)102.28
      β /(°)103.46
      γ /(°)94.35
      Rexp /%4.67
      Rwp /%9.23
      Rp /%6.98
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    Wanxin Mi, Lili Cao, Siqi Chu, Hongping Ma. Luminescence Properties and Energy Transfer Mechanism of Sr3P4O13∶Ce 3+,Tb 3+ Green Phosphors [J]. Acta Optica Sinica, 2019, 39(8): 0816002

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    Paper Information

    Category: Materials

    Received: Mar. 6, 2019

    Accepted: Apr. 15, 2019

    Published Online: Aug. 7, 2019

    The Author Email: Hongping Ma (hongpingma@163.com)

    DOI:10.3788/AOS201939.0816002

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