Chinese Journal of Lasers, Volume. 52, Issue 18, 1803012(2025)

Fabrication of Diamond NV Centers Quantum Sensors and Their Applications in Power Systems (Invited)

Wenbo Luo1, Qiuming Fu1, Geming Wang1, Qirui Wu2, Zhibin Ma1, Hongyang Zhao1、*, Tingting Jia1、**, Shiao Wang1, Wenshu Liu1, Minghe Wang1, Ziyun Zhu1, and Zhenxiang Cheng3、***
Author Affiliations
  • 1Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, Wuhan Institute of Technology, Wuhan 430205, Hubei , China
  • 2Wuhan NARI Limited Liability Company, State Grid Electric Power Research Institute, Wuhan 430074, Hubei , China
  • 3Institute for Superconducting & Electronic Materials, University of Wollongong, NSW 2500, Australia
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    Figures & Tables(17)
    Schematic diagrams of the diamond NV center structure and energy level transition. (a) Schematic diagram of the NV center structure[9]; (b) energy level transition of the NV center[3]
    Two methods for measuring the resonance frequency of NV centers[21]. (a) Frequency scanning method for measuring the resonance frequency of NV centers; (b) calculating the resonance frequency using fluorescence intensity
    Principles of microwave frequency modulation and demodulation[31]
    Schematic diagram of the HPHT method and phase diagram of diamond. (a) Schematic diagram of diamond synthesis by the HPHT method and its principle[34]. The pressure chamber containing graphite, metallic melt, and diamond seed crystal is subjected to high pressure and high temperature conditions. The graphite dissolves in the metal and precipitates on the seed crystal, causing the diamond lattice to expand. (b) Phase diagram of graphite and diamond[35], which shows the regions of pressure and temperature where HPHT and CVD synthesis can occur. CVD is a non-equilibrium process, and for better visibility, the region illustrating CVD growth is exaggerated
    Schematic diagrams of MPCVD equipment and internal defects in diamond. (a) MPCVD (microwave plasma chemical vapor deposition) reactor[52]. Microwave radiation enters the darkroom through the waveguide and the antenna. The chamber forms a resonant cavity, which is tuned by moving the position of the antenna. Plasma is generated directly above the surface of the substrate. This plasma activates, ionizes, and dissociates the input gas, thus initiating the growth of diamond on the nearby substrate. (b) Various defects in diamond crystals[41]: a realistic form with various impurities mixed in, and an ideal form consisting of NV- center and isolated nitrogen (donors)
    Variation laws of T2* and sensitivity parameters of NV centers ensemble sensors with the mass fraction of isolated nitrogen[63]
    System framework diagram of current transformer based on diamond NV centers magnetometer[21]
    Integration schematic diagram. (a) Housing encapsulated by 3D printing[73]; (b) magnetometer integrated with LED[74]; (c) CMOS chip-level integration[33]; (d) fiber-optic coupled magnetometer probe[76]; (e) micro-nano integration of diamond and microwave antenna[79]; (f) diamond-embedded microwave antenna[80]
    Schematic diagram of the device structure for the three-axis vector magnetic field measurement based on the microwave-free magnetic measurement scheme[84]
    The development timeline of quantum magnetometers in domestic and international contexts
    Schematic diagrams of a QCT[101]. (a) Read out fluorescence through laser and microwave interrogation to obtain magnetic information on the high-voltage side; (b) insulation and measurement scheme
    Multifaceted applications of diamond quantum devices. (a) Prototype battery monitor based on the diamond quantum sensor[102]; (b) a diamond fiber-coupled scanning probe magnetometer is used for the detection of surface cracks in welds[105]; (c) a multi-parameter sensor for magnetic field and temperature based on NV centers in diamond[106]
    • Table 1. Comparison of DC and AC magnetic measurements for ensemble NV centers[2]

      View table

      Table 1. Comparison of DC and AC magnetic measurements for ensemble NV centers[2]

      Measurement methodKey techniqueLimiting factorMeasurement frequency range
      DC magnetic measurementRamsey sequence, CW-ODMR, pulsed ODMRT2*, linewidth, contrast0‒100 kHz (pulsed ODMR), 0‒10 kHz (CW-ODMR)
      AC magnetic measurementHahn echo, spin echo, dynamical decoupling sequencesT2T1Center frequency of 1 kHz‒10 MHz, bandwidth 100 kHz
    • Table 2. Comparison of performance between microwave-free measurement scheme and CW-ODMR scheme

      View table

      Table 2. Comparison of performance between microwave-free measurement scheme and CW-ODMR scheme

      SchemeSensitivityBandwidthPower consumption
      CW-ODMR method

      As low as the femtotesla level:

      (195±60) fT/Hz32

      0‒10 kHz

      Tens to hundreds

      of watts

      Microwave-free measurement scheme

      As low as picotesla level: 26 pT/Hz

      (laboratory environment)85

      >300 kHz (up to MHz

      level)84

      ~1.5 W (minimum

      0.1 mW)85

    • Table 3. Performance comparison of different current measurement technologies at present[95]

      View table

      Table 3. Performance comparison of different current measurement technologies at present[95]

      Current sensor namePrincipleAbility to measure DCCostMeasurement rangeLinearity
      Rogowski coilFaraday’s law of electromagnetic inductionNoModerateA‒MA0.05%‒1%
      Hall effect sensorAmpere’s circuital lawYesExtremely lowA‒kA0.05%‒1%
      Magnetic resistive sensorAmpere’s circuital lawYesHighmA‒kA0.001%‒0.05%
      Optical fiber sensorFaraday magneto-optical effectYesExtremely highkA0.2%
      Diamond NV centers sensorZeeman splittingYesLow~μA0.0033%
    • Table 4. Performance comparison of different current sensors[96]

      View table

      Table 4. Performance comparison of different current sensors[96]

      TypeRange /kABandwidth /kHzAccuracy /%Temperature drift
      Standard current transformer11000.2‒1Yes
      Hall effect0.510.5‒5Yes
      Fluxgate0.110.001‒0.5Yes
      Fiber-optic1001000.2‒1Yes
      QCT11.40.05‒1No
    • Table 5. Performance comparison of domestic and international QCTs[86]

      View table

      Table 5. Performance comparison of domestic and international QCTs[86]

      YearMeasurement rangeAccuracy (non-linearity error)Real-timeCurrent response rateDiamond crystal orientation
      2022102-1000 to+1000 A0.3%Yes70 A/s(111)
      202221500 A0.3%Yes(100)
      202310440 A0.0033%No(100)
      2023100400 A0.46%Yes15 A/s(100)
      202486-1000 to+1000 A0.06%Yes107 kA/s(100)
      2025961000 A0.05%Yes(100)
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    Wenbo Luo, Qiuming Fu, Geming Wang, Qirui Wu, Zhibin Ma, Hongyang Zhao, Tingting Jia, Shiao Wang, Wenshu Liu, Minghe Wang, Ziyun Zhu, Zhenxiang Cheng. Fabrication of Diamond NV Centers Quantum Sensors and Their Applications in Power Systems (Invited)[J]. Chinese Journal of Lasers, 2025, 52(18): 1803012

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    Paper Information

    Category: Materials

    Received: May. 30, 2025

    Accepted: Jul. 14, 2025

    Published Online: Sep. 17, 2025

    The Author Email: Hongyang Zhao (zhaohy@wit.edu.cn), Tingting Jia (jia.tingting@hotmail.com), Zhenxiang Cheng (zhenxiang_cheng@uow.edu.au)

    DOI:10.3788/CJL250884

    CSTR:32183.14.CJL250884

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