Chinese Journal of Lasers, Volume. 51, Issue 19, 1901009(2024)

Developments in Research on Mid‐Infrared Fiber Lasers Based on Fluoroaluminate Glass (Invited)

Hao Wu1, Changjun Xu1, Mo Liu1, ShunBin Wang2、*, and Pengfei Wang2
Author Affiliations
  • 1College of Physics and Optoelectronic Engineering, Harbin Engineering University, Harbin 150001, Heilongjiang , China
  • 2Qingdao Innovation and Development Center, Harbin Engineering University, Qingdao 266400, Shandong , China
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    Figures & Tables(20)
    Glass-forming region in AlF3-BaF2-CaF2-YF3 system[26]
    Glass-forming region in AlF3-SrF2-MgF2-YF3 system[27]
    Glass-forming region in AlF3-RF2-YF3 system[28]
    Glass-forming region in AlF3-YF3-PbF2 system[39]
    Optical micrographs of neck surfaces of fiber preformed rods drawn in different atmospheres[57]. (a) In dry nitrogen; (b) in air
    Scanning electron micrographs of surfaces of fibers drawn in different atmospheres[57]. (a) In air; (b) in dry nitrogen
    Schematic of experimental setup for ~2.868 μm fiber laser[68]
    Experimental results of ~2.868 μm fiber laser[68]. (a) Output spectrum; (b) slope efficiency
    Energy level diagram and energy transfer mechanism of Ho3+/Pr3+ co-doped AZF glass[60]
    Schematic of experimental setup for ~2.9 μm fiber laser[60]
    Experimental results of ~2.866 μm fiber laser[60]. (a) Output spectrum; (b) slope efficiency
    Schematic of experimental setup for ~2.9 μm fiber laser[62]
    Experimental results of ~2.9 μm fiber laser[62]. (a) Output power versus pump power; (b) laser wavelength versus output power with laser spectrum at 969 mW output power shown in inset
    Experimental results of ~2.9 μm tunable fiber laser[62]. (a) Time stability; (b) tunable spectrum
    Experimental results of cascade fiber lasers[15]. (a) Output power versus pump power ; (b) output laser spectrum at highest pump power of ~20 W; (c) temporal dependence of ~3 μm laser maximum output power within 50 min
    Experimental setup and output power of ~2. 86 μm fiber laser[77]. (a) Schematic of experimental setup for ~2.86 μm fiber laser; (b) output power versus pump power
    Experimental results of ~2.86 μm fiber laser[77]. (a) Laser spectra under different output powers with laser spectrum shown in inset when output power is 977 mW; (b) temporal stability of output power
    • Table 1. Comparison of main properties of classic fluoride glasses

      View table

      Table 1. Comparison of main properties of classic fluoride glasses

      Type of glassesFluoroaluminate glassFluorozirconate glassFluoroindate glass
      ABCYSMABCYSMTABCYSMLZZBYAZBLANIZBGSPLYN
      v0.310.270.230.220.310.295
      α /(10-6/K)15.6615.417.4519.417.220.93
      E /GPa72.7472.526155.958.357.07
      σF /(MPa·m1/20.5740.510.440.450.320.219
      Rs /(W/ m1/20.3670.2630.2960.1970.1380.219
      Tg /°C425440376331262260
      ΔT/°C7812076716686
      Ref.15161517171819
    • Table 2. Nominal components of representative fluoroaluminate glasses and temperature parameters for measuring thermal stability of glasses

      View table

      Table 2. Nominal components of representative fluoroaluminate glasses and temperature parameters for measuring thermal stability of glasses

      Glass systemMole fraction /%Temperature /℃Year
      AlF3BaF2CaF2SrF2MgF2PbF2YF3ZrF4NaFLiFTgTxΔT
      AlF3-RF240204043048050197925
      AlF3-RF2-YF340222216430535105198126
      3533161642948960198327
      3512.512.512.512.515425535110198528
      30.210.620.213.23.58.310.23.8393528135198736
      37121591215426552126199331
      301020133.510.510337345784202138
      35102010101542850981201447
      40101510101542751285201447
      37131510101543852082201447
      AlF3-YF3-PbF230202030194920
      40122424194920
      3015102520367505138199139
      30101552015365490125199139
    • Table 3. Representative research achievements of mid-infrared fluoroaluminate fiber lasers

      View table

      Table 3. Representative research achievements of mid-infrared fluoroaluminate fiber lasers

      Gain fiber

      Pump

      wavelength /

      nm

      Doped

      mole

      fraction /%

      Fiber loss /

      (dB∙m-1

      Fiber

      length /

      cm

      Output

      wavelength /

      μm

      Output

      power /

      mW

      Slope

      efficiency /

      %

      Threshold

      power /

      mW

      Year
      Er∶AZF80010

      0.1

      @2.7 μm

      202.7152.1810200972
      Ho∶ABYPM11201.5

      2

      @1.56 μm

      842.868575.157201868

      Ho/Pr∶

      ABYPM

      1120

      1.5(Ho)

      0.2(Pr)

      2

      @1.56 μm

      502.86818915.343202069

      Ho/Pr∶

      AZF

      1150

      2(Ho)

      0.2(Pr)

      2

      @0.793 μm

      192.86617310.4154202060

      1.8

      @0.793 μm

      8.62.865320711.4123.2202061

      1.9

      @0.793 μm

      28~2.87~113010.352202162

      1.6

      @0.793 μm

      16.52.8639100617.730.67202277

      0.5

      @0.793 μm

      20.53.009101411.8131202478

      Ho/Pr∶

      AYF

      1150

      1(Ho)

      0.6(Pr)

      <3

      @0.793 μm

      222.84229.3202476
      Ho∶AYF11500.5

      0.5

      @1.57 μm

      95

      ~3

      ~2

      ~5820

      ~5760

      29202415
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    Hao Wu, Changjun Xu, Mo Liu, ShunBin Wang, Pengfei Wang. Developments in Research on Mid‐Infrared Fiber Lasers Based on Fluoroaluminate Glass (Invited)[J]. Chinese Journal of Lasers, 2024, 51(19): 1901009

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    Paper Information

    Category: laser devices and laser physics

    Received: Jul. 10, 2024

    Accepted: Sep. 12, 2024

    Published Online: Oct. 12, 2024

    The Author Email: ShunBin Wang (shunbinwang@hrbeu.edu.cn)

    DOI:10.3788/CJL241046

    CSTR:32183.14.CJL241046

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